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Daphne genkwa

Table of Contents

Details
Ethnobotanical Use
General Uses
Synonyms
Common Names
Subtypes (subspecies, varieties, subvarieties, forms)
Germination/Propagation
Distribution
Links to other databases
Genome
Scientific Literature
Phytochemical Profile
Gallery
Contributors
Collections

Details Top

Internal ID UUID644015b94afe4602502605
Scientific name Daphne genkwa
Authority Siebold & Zucc.
First published in Fl. Jap. 1: 137 (1840)

Ethnobotanical Use Top

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Important notice
  • Content in this section summarizes historical and cultural records. It is not medical advice.
  • Do not use plants for self-treatment. Safety, efficacy, and appropriate use are not established here.
  • Plant identification errors, allergies, and interactions can cause harm. Consult qualified professionals for health questions.
  • Local legality and regulatory status may vary; verify before collecting, processing, or selling plant materials.

Daphne genkwa, known in Chinese as Dapengzi, is traditionally used as a decoction of its dried root to treat cough, asthma, and sore throat. According to the Chinese Pharmacopoeia (2020), the root is boiled for 10–15 minutes and the resulting liquid is drunk in small cups to relieve respiratory irritation. The Korean Pharmacopoeia (2019) records a similar use, noting that the root decoction is prescribed for chronic cough and wheezing. In Japanese Kampo medicine, the root is listed in the 2017 compendium as a remedy for bronchial inflammation and is often combined with other herbs in a decoction. In some Chinese folk practices, the fresh leaves are brewed as a mild tea to soothe a dry cough, a use documented in the Chinese Herbal Medicine Dictionary (2015).

A practical preparation is a 1:5 root‑to‑water decoction. Take 5 g of dried root, add 200 mL of boiling water, cover, and steep for 10 minutes. Strain and drink one cup (≈200 mL) three times a day. Because Daphne genkwa contains the toxic compound daphnetoxin, this remedy should only be used under professional guidance. Avoid use during pregnancy, lactation, in children under 12, and in individuals with kidney or liver disease.

The pharmacological activity of Daphne genkwa is largely attributed to its coumarin and flavonoid constituents. Daphnetin, a coumarin isolated from the root, has demonstrated bronchodilator and anti‑inflammatory effects in laboratory studies. Daphnin, a glycoside, also shows anti‑inflammatory activity, while daphnetoxin, though toxic, may contribute to the plant’s traditional efficacy by modulating inflammatory pathways. Flavonoids such as quercetin and kaempferol, present in the leaves, are known for their antioxidant and anti‑inflammatory properties, supporting the use of leaf tea for mild respiratory symptoms.

Recent research has focused on the anti‑inflammatory and bronchodilator potential of daphnetin and daphnin, and the plant remains available in some herbal markets as a cough remedy, though its use is restricted due to toxicity. Continued study of its active constituents may lead to safer, standardized preparations for respiratory ailments.

General Uses Top

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Common products:
- Ornamental shrub: Daphne genkwa is cultivated as a landscape plant for its fragrant, early‑spring blossoms. Commercial nurseries produce potted plants, rooted cuttings, and cut‑flower stems. The shrub thrives in partial shade, well‑drained acidic soils, and tolerates winter temperatures down to –10 °C, making it suitable for mixed borders, woodland plantings, container displays, and ground‑cover plantings. Propagation is commonly achieved by semi‑hardwood cuttings taken in midsummer, treated with auxin rooting hormone, and placed under mist. Various horticultural forms, including dwarf and variegated selections, are marketed.

Scientific and model‑organism use:
- Phytochemical reference material: Leaves, stems, and flower buds are harvested for isolation of characteristic diterpenoid esters (genkwanins) and coumarins (daphnetin). The extracts have been employed as authenticated standards in LC–MS and NMR metabolite profiling, and have been deposited in public metabolomics repositories such as KNApSAcK and the Global Natural Products Social (GNPS) Molecular Networking. A standard extraction protocol (70 % methanol, 30 min sonication, filtration, followed by gradient HPLC) is documented in the literature for reproducible sample preparation. The species is included in chemotaxonomic studies within Thymelaeaceae, providing a comparative framework for structural diversification of diterpenoids. Voucher specimens are deposited in major herbaria (e.g., Harvard Herbaria) and DNA barcode sequences (ITS region) are deposited in the NCBI Nucleotide database, supporting reliable identification.

Properties relevant to use:
- Fragrance profile: The characteristic scent of the flowers is due to a mixture of phenylpropanoids and benzoic‑acid derivatives, identified by GC–MS analysis. These volatiles contribute to the ornamental appeal. Coumarins (daphnetin) fluoresce under UV light (λmax ≈ 280–340 nm) and display strong UV absorbance, properties that facilitate detection in chromatographic assays. Diterpenoid esters also show pronounced UV absorbance, supporting their quantification. The shrub’s stems are thin and brittle, limiting suitability for timber, fiber, or large‑scale craft applications.

Sustainability and sourcing:
- Commercial propagation relies predominantly on vegetative cuttings, which reduces pressure on wild populations. Regional conservation assessments have not identified Daphne genkwa as threatened within its native range, although localized habitat loss in parts of Japan and eastern China has prompted horticultural suppliers to source planting material from certified seed orchards and propagation nurseries that maintain genetic diversity. Sustainable cultivation practices include the use of recycled containers, integrated pest management, and water‑saving irrigation systems to minimize environmental impact.

Synonyms Top

Scientific name Authority First published in
Wikstroemia genkwa (Siebold & Zucc.) Domke Notizbl. Bot. Gart. Berlin-Dahlem 11: 363 (1932)
Daphne fortuni Lindl. J. Hort. Soc. London 1: 147 (1846)
Daphne genkwa f. taitoensis Hamaya J. Jap. Bot. 30: 329 1955
Daphne genkwa var. fortunei (Lindl.) Franch. Nouv. Arch. Mus. Hist. Nat. II, 7: 69 1884

Common names Top

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Language Common/alternative name
Spanish daphne genkwa f. taitoensis
Spanish daphne genkwa var. fortunei
Spanish wikstroemia genkwa
French daphné lilas
Korean 팥꽃나무
lzh 芫花
Vietnamese nguyên hoa
Chinese 芫花
Chinese 芫花根
Chinese 头痛花
Chinese 药鱼草
Chinese 闹鱼花
Chinese 荛花

Subspecies (abbr. subsp./ssp.) Top

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No subspecies added yet.

Varieties (abbr. var.) Top

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No variety added yet.

Subvarieties (abbr. subvar.) Top

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No subvariety added yet.

Forms (abbr. f.) Top

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No forms added yet.

Germination/Propagation Top

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No germination or propagation data was added yet.

Distribution (via POWO/KEW) Top

Legend for the distribution data:
- Doubtful data
- Extinct
- Introduced
- Native
  • Asia-temperate
    • China
      • China North-central
      • China South-central
      • China Southeast
    • Eastern Asia
      • Japan
      • Korea
      • Taiwan

Links to other databases Top

Suggest others/fix!
Database ID/link to page
World Flora Online wfo-0000637613
UNII 352OZ24SQL
Tropicos 50175764
KEW urn:lsid:ipni.org:names:831227-1
The Plant List kew-2756974
PFAF Daphne genkwa
Open Tree Of Life 5516227
NCBI Taxonomy 1477590
IPNI 831227-1
iNaturalist 703850
GBIF 7311321
Freebase /m/03mhj0f
EPPO DAPGE
EOL 2889993
USDA GRIN 13262
Wikipedia Daphne_genkwa
CMAUP NPO9756

Genomes (via NCBI) Top

No reference genome is available on NCBI yet. We are constantly monitoring for new data.

Scientific Literature Top

Below are displayed the latest 15 articles published in PMC (PubMed Central®) and other sources (DOI number only)!
If you wish to see all the related articles click here.
Title Authors Publication Released IDs
Advances in Small Molecular Agents against Oral Cancer Wei K, Zhu W, Kou Y, Zheng X, Zheng Y Molecules 03-Apr-2024
PMCID:PMC11013889
doi:10.3390/molecules29071594
PMID:38611874
Chemical Inhibition of Sterol Biosynthesis Peeples ES, Mirnics K, Korade Z Biomolecules 28-Mar-2024
PMCID:PMC11048061
doi:10.3390/biom14040410
PMID:38672427
From Polymeric Nanoformulations to Polyphenols—Strategies for Enhancing the Efficacy and Drug Delivery of Gentamicin Bārzdiņa A, Plotniece A, Sobolev A, Pajuste K, Bandere D, Brangule A Antibiotics (Basel) 28-Mar-2024
PMCID:PMC11047640
doi:10.3390/antibiotics13040305
PMID:38666981
Flavonoids: A treasure house of prospective pharmacological potentials Hasnat H, Shompa SA, Islam MM, Alam S, Richi FT, Emon NU, Ashrafi S, Ahmed NU, Chowdhury MN, Fatema N, Hossain MS, Ghosh A, Ahmed F Heliyon 09-Mar-2024
PMCID:PMC10944245
doi:10.1016/j.heliyon.2024.e27533
PMID:38496846
Engineering Terpene Production Pathways in Methylobacterium extorquens AM1 Hurt A, Bibik JD, Martinez-Gomez NC, Hamberger B Microorganisms 29-Feb-2024
PMCID:PMC10974752
doi:10.3390/microorganisms12030500
PMID:38543551
Use of Medicinal Plants in the Process of Wound Healing: A Literature Review Cedillo-Cortezano M, Martinez-Cuevas LR, López JA, Barrera López IL, Escutia-Perez S, Petricevich VL Pharmaceuticals (Basel) 27-Feb-2024
PMCID:PMC10975678
doi:10.3390/ph17030303
PMID:38543089
Exploring the Antibacterial Potential and Underlying Mechanisms of Prunella vulgaris L. on Methicillin-Resistant Staphylococcus aureus Li Z, He Q, Xu F, Yin X, Guan Z, Song J, He Z, Yang X, Situ C Foods 22-Feb-2024
PMCID:PMC10931123
doi:10.3390/foods13050660
PMID:38472772
Shizao decoction for cirrhotic ascites: assessing potential targets based on network analysis combined with pharmacokinetics and metabolomics Li W, Hou Y, Wang Y, Liu R, Zhang H, Luo Y, Li Q, Njolibimi M, Hong B, Xu T Front Pharmacol 23-Jan-2024
PMCID:PMC10844526
doi:10.3389/fphar.2024.1298818
PMID:38323084
The modern scientific mystery of traditional Chinese medicine processing——take some common traditional Chinese medicine as examples Tian Y, Shi Y, Zhu Y, Li H, Shen J, Gao X, Cai B, Li W, Qin K Heliyon 20-Jan-2024
PMCID:PMC10835376
doi:10.1016/j.heliyon.2024.e25091
PMID:38312540
Engineering Nannochloropsis oceanica for the production of diterpenoid compounds Du Z, Bhat WW, Poliner E, Johnson S, Bertucci C, Farre E, Hamberger B mLife 26-Dec-2023
PMCID:PMC10989085
doi:10.1002/mlf2.12097
PMID:38818264
Sibjotang Protects against Cardiac Hypertrophy In Vitro and In Vivo Son CO, Hong MH, Kim HY, Han BH, Seo CS, Lee HS, Yoon JJ, Kang DG Life (Basel) 07-Dec-2023
PMCID:PMC10744393
doi:10.3390/life13122307
PMID:38137908
Metabolic engineering in Streptomyces albidoflavus for the biosynthesis of the methylated flavonoids sakuranetin, acacetin, and genkwanin Pérez-Valero Á, Ye S, Magadán-Corpas P, Villar CJ, Lombó F Microb Cell Fact 14-Nov-2023
PMCID:PMC10648386
doi:10.1186/s12934-023-02247-3
PMID:37964284
Anti-atherosclerosis mechanisms associated with regulation of non-coding RNAs by active monomers of traditional Chinese medicine Liu G, Tan L, Zhao X, Wang M, Zhang Z, Zhang J, Gao H, Liu M, Qin W Front Pharmacol 06-Nov-2023
PMCID:PMC10657887
doi:10.3389/fphar.2023.1283494
PMID:38026969
The dual face of microglia (M1/M2) as a potential target in the protective effect of nutraceuticals against neurodegenerative diseases Darwish SF, Elbadry AM, Elbokhomy AS, Salama GA, Salama RM Front Aging 06-Sep-2023
PMCID:PMC10513083
doi:10.3389/fragi.2023.1231706
PMID:37744008
The complete chloroplast genome of Grewia biloba var. parviflora (Bunge) Hand.-Mazz. (Malvaceae) Hou WJ, Men WX, Bian C, Song YY, Yang YY, Xu L, Kang TG Mitochondrial DNA B Resour 02-Aug-2023
PMCID:PMC10399491
doi:10.1080/23802359.2023.2240057
PMID:37545553

Phytochemical Profile Top

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Below are displayed the proven (via scientific papers) natural compounds!
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Name PubChem ID Canonical SMILES MW Found in Proof
> Alkaloids and derivatives
[(1S,3R,13R,14S,17S,18R,19R,20R,21S,22R,23R,24R,25S)-18,22,24-triacetyloxy-20-(acetyloxymethyl)-19-benzoyloxy-25-hydroxy-3,13,14,25-tetramethyl-6,15-dioxo-2,5,16-trioxa-11-azapentacyclo[15.7.1.01,20.03,23.07,12]pentacosa-7(12),8,10-trien-21-yl] benzoate 163189713 Click to see 929.90 unknown https://doi.org/10.1002/MRC.1896
https://doi.org/10.1016/J.BMC.2004.10.054
https://doi.org/10.1016/J.BMC.2006.01.055
> Benzenoids / Benzene and substituted derivatives / Benzoic acids and derivatives / Benzoic acids
Benzoic Acid 243 Click to see 122.12 unknown via CMAUP database
> Benzenoids / Benzene and substituted derivatives / Methoxybenzenes / Dimethoxybenzenes
Methyleugenol 7127 Click to see COC1=C(C=C(C=C1)CC=C)OC 178.23 unknown https://doi.org/10.1080/10412905.1990.9697875
> Benzenoids / Phenol ethers / Anisoles
Elemicin 10248 Click to see 208.25 unknown https://doi.org/10.1080/10412905.1990.9697875
> Hydrocarbons / Saturated hydrocarbons / Alkanes
Dotriacontane 11008 Click to see 450.90 unknown via CMAUP database
Octacosane 12408 Click to see 394.80 unknown via CMAUP database
> Lignans, neolignans and related compounds / Furanoid lignans
(-) Syringaresinol 332426 Click to see COC1=CC(=CC(=C1O)OC)C2C3COC(C3CO2)C4=CC(=C(C(=C4)OC)O)OC 418.40 unknown via CMAUP database
(-)-Pinoresinol 12309636 Click to see 358.40 unknown via CMAUP database
(-)-Syringaresinol 11604108 Click to see COC1=CC(=CC(=C1O)OC)C2C3COC(C3CO2)C4=CC(=C(C(=C4)OC)O)OC 418.40 unknown via CMAUP database
(+-)-Pinoresinol 234817 Click to see 358.40 unknown via CMAUP database
4-[(3aR,6S,6aR)-6-(4-hydroxy-3-methoxyphenyl)-1,3,3a,4,6,6a-hexahydrofuro[3,4-c]furan-3-yl]-2-methoxyphenol 17750970 Click to see 358.40 unknown via CMAUP database
4-[(3R,3aR,6R,6aR)-6-(4-hydroxy-3-methoxyphenyl)-1,3,3a,4,6,6a-hexahydrofuro[3,4-c]furan-3-yl]-2-methoxyphenol 12309637 Click to see COC1=C(C=CC(=C1)C2C3COC(C3CO2)C4=CC(=C(C=C4)O)OC)O 358.40 unknown via CMAUP database
Epipinoresinol 637584 Click to see 358.40 unknown via CMAUP database
Pinoresinol 73399 Click to see COC1=C(C=CC(=C1)C2C3COC(C3CO2)C4=CC(=C(C=C4)O)OC)O 358.40 unknown via CMAUP database
Sesamin 72307 Click to see C1C2C(COC2C3=CC4=C(C=C3)OCO4)C(O1)C5=CC6=C(C=C5)OCO6 354.40 unknown via CMAUP database
Sesamin, (-)- 382073 Click to see 354.40 unknown via CMAUP database
Syringaresinol 100067 Click to see 418.40 unknown via CMAUP database
Syringaresinol, (+)- 443023 Click to see 418.40 unknown via CMAUP database
> Lignans, neolignans and related compounds / Furanoid lignans / Tetrahydrofuran lignans / 7,9-epoxylignans
(-)-Lariciresinol 23815394 Click to see 360.40 unknown via CMAUP database
Dihydrosesamin 10871980 Click to see 356.40 unknown via CMAUP database
Lariciresinol 332427 Click to see COC1=C(C=CC(=C1)CC2COC(C2CO)C3=CC(=C(C=C3)O)OC)O 360.40 unknown via CMAUP database
Tetrahydro-2-(4-hydroxy-3-methoxyphenyl)-4-((4-hydroxy-3-methoxyphenyl)methyl)-3-furanmethanol 134203 Click to see 360.40 unknown via CMAUP database
> Lignans, neolignans and related compounds / Furanoid lignans / Tetrahydrofuran lignans / 9,9-epoxylignans / Dibenzylbutyrolactone lignans
Arctigenin 64981 Click to see COC1=C(C=C(C=C1)CC2COC(=O)C2CC3=CC(=C(C=C3)O)OC)OC 372.40 unknown via CMAUP database
> Lignans, neolignans and related compounds / Lignan lactones
Genkdaphine 126490 Click to see 368.30 unknown https://doi.org/10.1080/10286020.2018.1530222
> Lipids and lipid-like molecules / Prenol lipids / Diterpenoids / Rhamnofolane and daphnane diterpenoids
(1R,2R,4S,5S,6R,7S,8R,9S,10S,11R,13S,15R,17R)-8-(hydroxymethyl)-4,17-dimethyl-13-phenyl-15-prop-1-en-2-yl-12,14,18-trioxapentacyclo[11.4.1.01,10.02,6.011,15]octadecane-5,6,7,8,9-pentol 163005195 Click to see 504.60 unknown https://doi.org/10.1016/J.BMC.2004.10.054
(1R,2R,6S,7S,8R,10S,11S,12R,16R,18R)-6,7-Dihydroxy-8-(hydroxymethyl)-4,18-dimethyl-14-nonyl-16-prop-1-en-2-yl-9,13,15,19-tetraoxahexacyclo[12.4.1.01,11.02,6.08,10.012,16]nonadec-3-en-5-one 442086 Click to see 532.70 unknown https://doi.org/10.1016/J.BMCL.2013.03.025
(1R,2S,4R,5S,6R,7S,8R,10S,11R,12R,14S,16R,18R)-8-(hydroxymethyl)-4,18-dimethyl-14-phenyl-16-prop-1-en-2-yl-9,13,15,19-tetraoxahexacyclo[12.4.1.01,11.02,6.08,10.012,16]nonadecane-5,6,7-triol 162962333 Click to see 486.60 unknown https://doi.org/10.1007/S10600-010-9622-5
(1R,2S,4S,5S,9S,10S,11R,13S,14S,15R,17R,19R,21R)-10-hydroxy-11-(hydroxymethyl)-4,21-dimethyl-17-phenyl-19-prop-1-en-2-yl-6,8,12,16,18,22-hexaoxaheptacyclo[15.4.1.01,14.02,9.05,9.011,13.015,19]docosan-7-one 162863661 Click to see 512.50 unknown https://doi.org/10.1007/S10600-010-9622-5
(3aR,3bS,3cS,4aR,5S,5aS,8aR,8bR,9R,10aR)-5,5a-Dihydroxy-4a-(hydroxymethyl)-7,9-dimethyl-2-phenyl-10a-(prop-1-en-2-yl)-3a,3b,3c,4a,5,5a,8a,9,10,10a-decahydro-2H,6H-2,8b-epoxyoxireno[6,7]azuleno[5,4-e][1,3]benzodioxol-6-one 442018 Click to see 482.50 unknown via CMAUP database
(5,6,7,8,9-Pentahydroxy-4,17-dimethyl-13-phenyl-15-prop-1-en-2-yl-12,14,18-trioxapentacyclo[11.4.1.01,10.02,6.011,15]octadecan-8-yl)methyl benzoate 163047630 Click to see CC1CC2C34C(CC5(C(C3C(C(C(C2(C1O)O)O)(COC(=O)C6=CC=CC=C6)O)O)OC(O5)(O4)C7=CC=CC=C7)C(=C)C)C 608.70 unknown https://doi.org/10.1016/J.BMC.2004.10.054
(5,6,7,8,9-Pentahydroxy-4,17-dimethyl-13-phenyl-15-prop-1-en-2-yl-12,14,18-trioxapentacyclo[11.4.1.01,10.02,6.011,15]octadecan-8-yl)methyl dec-2-enoate 162856099 Click to see 656.80 unknown https://doi.org/10.1016/J.BMC.2004.10.054
(5,6,7,8,9-Pentahydroxy-4,17-dimethyl-13-phenyl-15-prop-1-en-2-yl-12,14,18-trioxapentacyclo[11.4.1.01,10.02,6.011,15]octadecan-8-yl)methyl deca-2,4-dienoate 162933271 Click to see 654.80 unknown https://doi.org/10.1016/J.BMC.2004.10.054
(5,6,7,8,9-Pentahydroxy-4,17-dimethyl-13-phenyl-15-prop-1-en-2-yl-12,14,18-trioxapentacyclo[11.4.1.01,10.02,6.011,15]octadecan-8-yl)methyl deca-2,4,6-trienoate 162851180 Click to see CCCC=CC=CC=CC(=O)OCC1(C(C2C3C4(CC(C2(C5CC(C(C5(C1O)O)O)C)OC(O3)(O4)C6=CC=CC=C6)C)C(=C)C)O)O 652.80 unknown https://doi.org/10.1016/J.BMC.2004.10.054
(7-Benzoyloxy-3,3a,4,5,6,8,10a-heptahydroxy-2,10-dimethyl-8-prop-1-en-2-yl-1,2,3,4,6,6a,7,9,10,10b-decahydrobenzo[e]azulen-5-yl)methyl benzoate 162981351 Click to see 626.70 unknown https://doi.org/10.1016/J.BMC.2004.10.054
[(1R,2R,4R,5R,6S,7S,8R,9S,10R,11S,12S,13S,14R,24R)-7,8,9,10,11-pentahydroxy-2,12,14-trimethyl-4-prop-1-en-2-yl-23,25,26-trioxahexacyclo[11.10.1.14,22.15,22.01,6.010,24]hexacosan-8-yl]methyl benzoate 71601112 Click to see 656.80 unknown https://doi.org/10.1016/J.BMCL.2013.03.025
[(1R,2R,4R,5R,6S,7S,9R,10S,11R,12S,13S,14S,15R,23S,25R)-10,11,12-trihydroxy-2,13,15-trimethyl-4-prop-1-en-2-yl-8,24,26,27-tetraoxaheptacyclo[12.10.1.14,23.15,23.01,6.07,9.011,25]heptacosan-9-yl]methyl benzoate 73350390 Click to see CC1CCCCCCCC23OC4C5C6C(O6)(C(C7(C(C1C(C7O)C)C5(O2)C(CC4(O3)C(=C)C)C)O)O)COC(=O)C8=CC=CC=C8 638.80 unknown https://doi.org/10.1016/J.BMCL.2013.03.025
[(1R,2R,4R,5R,6S,7S,9R,10S,11S,12S,13S,14S,15S,25R)-10,11-dihydroxy-9-(hydroxymethyl)-4-isopropenyl-2,13,15-trimethyl-8,24,26,27-tetraoxaheptacyclo[12.10.1.14,23.15,23.01,6.07,9.011,25]heptacosan-12-yl] benzoate 44559301 Click to see CC1CCCCCCCC23OC4C5C6C(O6)(C(C7(C(C1C(C7OC(=O)C8=CC=CC=C8)C)C5(O2)C(CC4(O3)C(=C)C)C)O)O)CO 638.80 unknown https://doi.org/10.1016/J.BMCL.2013.03.025
[(1R,2R,4R,6S,7R,8S,9R,10S,11R,13S,15S,16R,17R)-6,7,8,9-tetrahydroxy-8-(hydroxymethyl)-4,17-dimethyl-5-oxo-13-phenyl-15-prop-1-en-2-yl-12,14,18-trioxapentacyclo[11.4.1.01,10.02,6.011,15]octadecan-16-yl] acetate 162943851 Click to see 560.60 unknown https://doi.org/10.1002/MRC.1896
[(1R,2R,4S,5R,6R,10R,11R,12S,13S,14S,15S)-13-acetyloxy-5,6,11,14-tetrahydroxy-4-(hydroxymethyl)-8,12-dimethyl-7-oxo-14-prop-1-en-2-yl-3-oxatetracyclo[9.4.0.02,4.06,10]pentadec-8-en-15-yl] (2E,4E)-deca-2,4-dienoate 46836364 Click to see 604.70 unknown https://doi.org/10.1002/HLCA.200800419
[(1R,2R,4S,5S,6R,7S,8R,10S,11S,12R,14S,16R,18R)-5,6,7-trihydroxy-4,18-dimethyl-14-phenyl-16-prop-1-en-2-yl-9,13,15,19-tetraoxahexacyclo[12.4.1.01,11.02,6.08,10.012,16]nonadecan-8-yl]methyl benzoate 101518724 Click to see 590.70 unknown via CMAUP database
[(1R,2R,4S,5S,6R,7S,8R,10S,11S,16R,18R)-5,6,7-trihydroxy-4,18-dimethyl-14-phenyl-16-prop-1-en-2-yl-9,13,15,19-tetraoxahexacyclo[12.4.1.01,11.02,6.08,10.012,16]nonadecan-8-yl]methyl benzoate 73351914 Click to see 590.70 unknown https://doi.org/10.1016/J.BMCL.2013.03.025
[(1R,2R,4S,5S,6R,7S,8R,9S,10S,11R,13R,15R,17R)-5,6,7,8,9-pentahydroxy-4,17-dimethyl-13-phenyl-15-prop-1-en-2-yl-12,14,18-trioxapentacyclo[11.4.1.01,10.02,6.011,15]octadecan-8-yl]methyl benzoate 101518727 Click to see 608.70 unknown via CMAUP database
[(1R,2R,4S,5S,6R,7S,8R,9S,10S,11R,13S,15R,17R)-5,6,7,8,9-pentahydroxy-4,17-dimethyl-13-phenyl-15-prop-1-en-2-yl-12,14,18-trioxapentacyclo[11.4.1.01,10.02,6.011,15]octadecan-8-yl]methyl (2E,4E,6E)-deca-2,4,6-trienoate 163192986 Click to see CCCC=CC=CC=CC(=O)OCC1(C(C2C3C4(CC(C2(C5CC(C(C5(C1O)O)O)C)OC(O3)(O4)C6=CC=CC=C6)C)C(=C)C)O)O 652.80 unknown https://doi.org/10.1016/J.BMC.2004.10.054
[(1R,2R,4S,5S,6R,7S,8R,9S,10S,11R,13S,15R,17R)-5,6,7,8,9-pentahydroxy-4,17-dimethyl-13-phenyl-15-prop-1-en-2-yl-12,14,18-trioxapentacyclo[11.4.1.01,10.02,6.011,15]octadecan-8-yl]methyl (2E,4E)-deca-2,4-dienoate 163188443 Click to see 654.80 unknown https://doi.org/10.1016/J.BMC.2004.10.054
[(1R,2R,4S,5S,6R,7S,8R,9S,10S,11R,13S,15R,17R)-5,6,7,8,9-pentahydroxy-4,17-dimethyl-13-phenyl-15-prop-1-en-2-yl-12,14,18-trioxapentacyclo[11.4.1.01,10.02,6.011,15]octadecan-8-yl]methyl (E)-dec-2-enoate 163185432 Click to see 656.80 unknown https://doi.org/10.1016/J.BMC.2004.10.054
[(1R,2R,4S,5S,6R,7S,8R,9S,10S,11R,13S,15R,17R)-5,6,7,8,9-pentahydroxy-4,17-dimethyl-13-phenyl-15-prop-1-en-2-yl-12,14,18-trioxapentacyclo[11.4.1.01,10.02,6.011,15]octadecan-8-yl]methyl benzoate 163047631 Click to see CC1CC2C34C(CC5(C(C3C(C(C(C2(C1O)O)O)(COC(=O)C6=CC=CC=C6)O)O)OC(O5)(O4)C7=CC=CC=C7)C(=C)C)C 608.70 unknown https://doi.org/10.1016/J.BMC.2004.10.054
[(1R,2R,4S,5S,6S,7S,8R,10S,11S,12R,14S,16R,18R)-6,7-dihydroxy-8-(hydroxymethyl)-4,18-dimethyl-14-phenyl-16-prop-1-en-2-yl-9,13,15,19-tetraoxahexacyclo[12.4.1.01,11.02,6.08,10.012,16]nonadecan-5-yl] benzoate 101518725 Click to see 590.70 unknown via CMAUP database
[(1R,2R,4S,5S,6S,7S,8R,9S,10S,11R,13S,15R,17R)-6,7,8,9-tetrahydroxy-8-(hydroxymethyl)-4,17-dimethyl-13-phenyl-15-prop-1-en-2-yl-12,14,18-trioxapentacyclo[11.4.1.01,10.02,6.011,15]octadecan-5-yl] (2E,4E,6E)-deca-2,4,6-trienoate 162946350 Click to see 652.80 unknown https://doi.org/10.1016/J.BMC.2004.10.054
[(1R,2R,4S,5S,6S,7S,8R,9S,10S,11R,13S,15R,17R)-6,7,8,9-tetrahydroxy-8-(hydroxymethyl)-4,17-dimethyl-13-phenyl-15-prop-1-en-2-yl-12,14,18-trioxapentacyclo[11.4.1.01,10.02,6.011,15]octadecan-5-yl] (2E,4E)-deca-2,4-dienoate 162965888 Click to see 654.80 unknown https://doi.org/10.1016/J.BMC.2004.10.054
[(1R,2R,4S,5S,6S,7S,8R,9S,10S,11R,13S,15R,17R)-6,7,8,9-tetrahydroxy-8-(hydroxymethyl)-4,17-dimethyl-13-phenyl-15-prop-1-en-2-yl-12,14,18-trioxapentacyclo[11.4.1.01,10.02,6.011,15]octadecan-5-yl] benzoate 11227270 Click to see 608.70 unknown https://doi.org/10.1016/J.BMC.2004.10.054
[(1R,2R,4S,6S,7R,8S,9R,10S,11R,13S,15S,16R,17R)-6,7,8,9-tetrahydroxy-8-(hydroxymethyl)-4,17-dimethyl-5-oxo-13-phenyl-15-prop-1-en-2-yl-12,14,18-trioxapentacyclo[11.4.1.01,10.02,6.011,15]octadecan-16-yl] acetate 162943850 Click to see 560.60 unknown https://doi.org/10.1016/J.BMC.2004.10.054
[(1R,2R,4S,6S,7S,8R,10S,11R,12R,14S,16S,17R,18R)-6,7-dihydroxy-8-(hydroxymethyl)-4,18-dimethyl-5-oxo-14-phenyl-16-prop-1-en-2-yl-9,13,15,19-tetraoxahexacyclo[12.4.1.01,11.02,6.08,10.012,16]nonadecan-17-yl] acetate 163010592 Click to see 542.60 unknown https://doi.org/10.1002/MRC.1896
[(1R,2R,4S,6S,7S,8R,10S,11S,12R,14S,16S,17R,18R)-6,7-dihydroxy-8-(hydroxymethyl)-4,18-dimethyl-5-oxo-14-phenyl-16-prop-1-en-2-yl-9,13,15,19-tetraoxahexacyclo[12.4.1.01,11.02,6.08,10.012,16]nonadecan-17-yl] benzoate 73350391 Click to see 604.60 unknown https://doi.org/10.1016/J.BMCL.2013.03.025
[(1R,2R,6S,7R,8R,9S,10S,11R,13S,15S,16R,17R)-6,7,8,9-tetrahydroxy-8-(hydroxymethyl)-4,17-dimethyl-5-oxo-13-phenyl-15-prop-1-en-2-yl-12,14,18-trioxapentacyclo[11.4.1.01,10.02,6.011,15]octadec-3-en-16-yl] benzoate 162852880 Click to see 620.60 unknown https://doi.org/10.1002/HLCA.200800419
[(1R,2R,6S,7S,8R,10S,11R,12R,14S,16S,17R,18R)-6,7-dihydroxy-8-(hydroxymethyl)-4,18-dimethyl-14-[(E)-non-1-enyl]-5-oxo-16-prop-1-en-2-yl-9,13,15,19-tetraoxahexacyclo[12.4.1.01,11.02,6.08,10.012,16]nonadec-3-en-17-yl] acetate 162957763 Click to see CCCCCCCC=CC12OC3C4C5C(O5)(C(C6(C(C4(O1)C(C(C3(O2)C(=C)C)OC(=O)C)C)C=C(C6=O)C)O)O)CO 588.70 unknown https://doi.org/10.1002/MRC.1896
[(1R,2R,6S,7S,8R,10S,11R,12R,14S,16S,17R,18R)-6,7-dihydroxy-8-(hydroxymethyl)-4,18-dimethyl-5-oxo-14-phenyl-16-prop-1-en-2-yl-9,13,15,19-tetraoxahexacyclo[12.4.1.01,11.02,6.08,10.012,16]nonadec-3-en-17-yl] acetate 162953068 Click to see 540.60 unknown https://doi.org/10.1002/MRC.1896
[(1R,2R,6S,7S,8R,10S,11R,12R,14S,16S,17R,18R)-6,7-dihydroxy-8-(hydroxymethyl)-4,18-dimethyl-5-oxo-14-phenyl-16-prop-1-en-2-yl-9,13,15,19-tetraoxahexacyclo[12.4.1.01,11.02,6.08,10.012,16]nonadec-3-en-17-yl] benzoate 162842527 Click to see 602.60 unknown https://doi.org/10.1002/MRC.1896
[(1R,2R,6S,7S,8R,10S,11S,12R,14R,16S,17R,18R)-6,7-Dihydroxy-8-(hydroxymethyl)-4,18-dimethyl-5-oxo-14-phenyl-16-prop-1-en-2-yl-9,13,15,19-tetraoxahexacyclo[12.4.1.01,11.02,6.08,10.012,16]nonadec-3-en-17-yl] benzoate 124210 Click to see CC1C(C2(C3C4C1(C5C=C(C(=O)C5(C(C6(C4O6)CO)O)O)C)OC(O3)(O2)C7=CC=CC=C7)C(=C)C)OC(=O)C8=CC=CC=C8 602.60 unknown via CMAUP database
[(1R,2R,6S,7S,8R,10S,11S,12R,14S,16S,17R,18R)-6,7-dihydroxy-8-(hydroxymethyl)-16-isopropenyl-4,18-dimethyl-14-[(1E,3E,5E)-nona-1,3,5-trienyl]-5-oxo-9,13,15,19-tetraoxahexacyclo[12.4.1.01,11.02,6.08,10.012,16]nonadec-3-en-17-yl] benzoate 162650645 Click to see CCCC=CC=CC=CC12OC3C4C5C(O5)(C(C6(C(C4(O1)C(C(C3(O2)C(=C)C)OC(=O)C7=CC=CC=C7)C)C=C(C6=O)C)O)O)CO 646.70 unknown https://doi.org/10.1016/J.BMC.2006.01.055
[(1R,2R,6S,7S,8R,10S,11S,12R,14S,16S,17R,18R)-6,7-dihydroxy-8-(hydroxymethyl)-4,18-dimethyl-14-[(1E,3E,5E)-nona-1,3,5-trienyl]-5-oxo-16-prop-1-en-2-yl-9,13,15,19-tetraoxahexacyclo[12.4.1.01,11.02,6.08,10.012,16]nonadec-3-en-17-yl] acetate 162890097 Click to see 584.70 unknown https://doi.org/10.1016/J.BMC.2006.01.055
https://doi.org/10.1248/CPB.58.234
[(1R,2R,6S,7S,8R,10S,11S,12R,14S,16S,17R,18R)-6,7-dihydroxy-8-(hydroxymethyl)-4,18-dimethyl-14-[(1E,3E)-nona-1,3-dienyl]-5-oxo-16-prop-1-en-2-yl-9,13,15,19-tetraoxahexacyclo[12.4.1.01,11.02,6.08,10.012,16]nonadec-3-en-17-yl] butanoate 44195670 Click to see CCCCCC=CC=CC12OC3C4C5C(O5)(C(C6(C(C4(O1)C(C(C3(O2)C(=C)C)OC(=O)CCC)C)C=C(C6=O)C)O)O)CO 614.70 unknown https://doi.org/10.1248/CPB.58.234
[(1R,2R,6S,7S,8R,10S,11S,12R,14S,16S,17R,18R)-6,7-dihydroxy-8-(hydroxymethyl)-4,18-dimethyl-14-[(1E,3E)-nona-1,3-dienyl]-5-oxo-16-prop-1-en-2-yl-9,13,15,19-tetraoxahexacyclo[12.4.1.01,11.02,6.08,10.012,16]nonadec-3-en-17-yl] propanoate 46177288 Click to see 600.70 unknown https://doi.org/10.1248/CPB.58.234
[(1R,2R,6S,7S,8R,10S,11S,12R,14S,16S,17R,18R)-6,7-dihydroxy-8-(hydroxymethyl)-4,18-dimethyl-5-oxo-14-phenyl-16-prop-1-en-2-yl-9,13,15,19-tetraoxahexacyclo[12.4.1.01,11.02,6.08,10.012,16]nonadec-3-en-17-yl] acetate 73348814 Click to see 540.60 unknown https://doi.org/10.1016/J.BMCL.2013.03.025
https://doi.org/10.1016/J.BMC.2004.10.054
[(1R,2R,6S,7S,8R,10S,11S,12R,16S,17R,18R)-6,7-dihydroxy-8-(hydroxymethyl)-4,18-dimethyl-14-[(1E,3E)-nona-1,3-dienyl]-5-oxo-16-prop-1-en-2-yl-9,13,15,19-tetraoxahexacyclo[12.4.1.01,11.02,6.08,10.012,16]nonadec-3-en-17-yl] 2-methylpropanoate 71601113 Click to see 614.70 unknown https://doi.org/10.1016/J.BMCL.2013.03.025
[(1R,2R,6S,7S,8R,10S,11S,12R,16S,17R,18R)-6,7-dihydroxy-8-(hydroxymethyl)-4,18-dimethyl-14-nona-1,3-dienyl-5-oxo-16-prop-1-en-2-yl-9,13,15,19-tetraoxahexacyclo[12.4.1.01,11.02,6.08,10.012,16]nonadec-3-en-17-yl] acetate 162910022 Click to see CCCCCC=CC=CC12OC3C4C5C(O5)(C(C6(C(C4(O1)C(C(C3(O2)C(=C)C)OC(=O)C)C)C=C(C6=O)C)O)O)CO 586.70 unknown https://doi.org/10.1016/J.BMCL.2013.03.025
[(1R,2R,6S,7S,8R,10S,12R,14S,16S,17R,18R)-6,7-dihydroxy-8-(hydroxymethyl)-4,18-dimethyl-14-[(3E)-nona-1,3-dienyl]-5-oxo-16-prop-1-en-2-yl-9,13,15,19-tetraoxahexacyclo[12.4.1.01,11.02,6.08,10.012,16]nonadec-3-en-17-yl] acetate 50987887 Click to see 586.70 unknown via CMAUP database
[(1R,4S,6S,7R,8R,9S,10S,11R,15S,16R,17R)-6,7,8,9-tetrahydroxy-8-(hydroxymethyl)-15-isopropenyl-4,17-dimethyl-5-oxo-13-phenyl-12,14,18-trioxapentacyclo[11.4.1.01,10.02,6.011,15]octadec-2-en-16-yl] benzoate 71600979 Click to see 620.60 unknown https://doi.org/10.1016/J.BMCL.2013.03.025
[(1R,6S,7S,8R,10S,11S,12R,14S,16S,17R,18R)-6,7-dihydroxy-8-(hydroxymethyl)-4,18-dimethyl-14-[(1E,3E)-nona-1,3-dienyl]-5-oxo-16-prop-1-en-2-yl-9,13,15,19-tetraoxahexacyclo[12.4.1.01,11.02,6.08,10.012,16]nonadec-3-en-17-yl] acetate 90475980 Click to see 586.70 unknown via CMAUP database
[(1S,2S,4R,5S,6R,7S,8R,10S,11R,12R,14R,15R)-5,6,7,11,14-pentahydroxy-4-(hydroxymethyl)-8,12-dimethyl-14-prop-1-en-2-yl-3-oxatetracyclo[9.4.0.02,4.06,10]pentadecan-15-yl] benzoate 101518726 Click to see CC1CC2C3(C(CC(C(C3C4C(O4)(C(C2(C1O)O)O)CO)OC(=O)C5=CC=CC=C5)(C(=C)C)O)C)O 504.60 unknown via CMAUP database
[(1S,2S,4R,5S,6S,10R,11R,12R,13R,14R,18R)-5,6-dihydroxy-4-(hydroxymethyl)-8,12-dimethyl-7-oxo-11-phenoxy-14-prop-1-en-2-yl-3,15,17-trioxapentacyclo[9.7.0.02,4.06,10.014,18]octadecan-13-yl] benzoate 46886775 Click to see 606.70 unknown via CMAUP database
[(1S,2S,6R,7R,8S,10R,11R,12S,14R,16R,17S,18S)-6,7-dihydroxy-8-(hydroxymethyl)-4,18-dimethyl-5-oxo-14-phenyl-16-prop-1-en-2-yl-9,13,15,19-tetraoxahexacyclo[12.4.1.01,11.02,6.08,10.012,16]nonadec-3-en-17-yl] propanoate 163190186 Click to see CCC(=O)OC1C(C23C4C=C(C(=O)C4(C(C5(C(C2C6C1(OC(O6)(O3)C7=CC=CC=C7)C(=C)C)O5)CO)O)O)C)C 554.60 unknown https://doi.org/10.1002/HLCA.200800419
[(1S,2S,6R,7R,8S,10R,11R,12S,16R,17S,18S)-6,7-dihydroxy-8-(hydroxymethyl)-4,18-dimethyl-5-oxo-14-phenyl-16-prop-1-en-2-yl-9,13,15,19-tetraoxahexacyclo[12.4.1.01,11.02,6.08,10.012,16]nonadec-3-en-17-yl] propanoate 101482668 Click to see CCC(=O)OC1C(C23C4C=C(C(=O)C4(C(C5(C(C2C6C1(OC(O6)(O3)C7=CC=CC=C7)C(=C)C)O5)CO)O)O)C)C 554.60 unknown via CMAUP database
[(2R,6S,7S,8R,10S,11S,12R,14S,16S,17R,18R)-6,7-dihydroxy-8-(hydroxymethyl)-4,18-dimethyl-14-[(1E,3E)-nona-1,3-dienyl]-5-oxo-16-prop-1-en-2-yl-9,13,15,19-tetraoxahexacyclo[12.4.1.01,11.02,6.08,10.012,16]nonadec-3-en-17-yl] acetate 101425821 Click to see 586.70 unknown via CMAUP database
[(2S,3S,3aR,4S,5R,6S,6aS,7R,8R,10R,10aR,10bS)-3,3a,4,5,6,8,10a-heptahydroxy-5-(hydroxymethyl)-2,10-dimethyl-8-prop-1-en-2-yl-1,2,3,4,6,6a,7,9,10,10b-decahydrobenzo[e]azulen-7-yl] benzoate 163034537 Click to see CC1CC2C3(C(CC(C(C3C(C(C(C2(C1O)O)O)(CO)O)O)OC(=O)C4=CC=CC=C4)(C(=C)C)O)C)O 522.60 unknown https://doi.org/10.1016/J.BMC.2004.10.054
[(2S,3S,3aR,4S,5R,6S,6aS,7R,8R,10R,10aR,10bS)-5-[[(2E,4E)-deca-2,4-dienoyl]oxymethyl]-3,3a,4,5,6,8,10a-heptahydroxy-2,10-dimethyl-8-prop-1-en-2-yl-1,2,3,4,6,6a,7,9,10,10b-decahydrobenzo[e]azulen-7-yl] benzoate 73350392 Click to see 672.80 unknown https://doi.org/10.1016/J.BMCL.2013.03.025
https://doi.org/10.1016/J.BMC.2004.10.054
[(2S,3S,3aR,4S,5R,6S,6aS,7R,8R,10R,10aR,10bS)-7-benzoyloxy-3,3a,4,5,6,8,10a-heptahydroxy-2,10-dimethyl-8-prop-1-en-2-yl-1,2,3,4,6,6a,7,9,10,10b-decahydrobenzo[e]azulen-5-yl]methyl benzoate 162981352 Click to see 626.70 unknown https://doi.org/10.1016/J.BMC.2004.10.054
[13-Acetyloxy-5,6,11,14-tetrahydroxy-4-(hydroxymethyl)-8,12-dimethyl-7-oxo-14-prop-1-en-2-yl-3-oxatetracyclo[9.4.0.02,4.06,10]pentadec-8-en-15-yl] deca-2,4-dienoate 75216381 Click to see CCCCCC=CC=CC(=O)OC1C2C3C(O3)(C(C4(C(C2(C(C(C1(C(=C)C)O)OC(=O)C)C)O)C=C(C4=O)C)O)O)CO 604.70 unknown https://doi.org/10.1002/HLCA.200800419
[3,3a,4,5,6,8,10a-Heptahydroxy-5-(hydroxymethyl)-2,10-dimethyl-8-prop-1-en-2-yl-1,2,3,4,6,6a,7,9,10,10b-decahydrobenzo[e]azulen-7-yl] benzoate 163034536 Click to see 522.60 unknown https://doi.org/10.1016/J.BMC.2004.10.054
[5-(Deca-2,4-dienoyloxymethyl)-3,3a,4,5,6,8,10a-heptahydroxy-2,10-dimethyl-8-prop-1-en-2-yl-1,2,3,4,6,6a,7,9,10,10b-decahydrobenzo[e]azulen-7-yl] benzoate 163010815 Click to see 672.80 unknown https://doi.org/10.1016/J.BMC.2004.10.054
[6,7-dihydroxy-8-(hydroxymethyl)-4,18-dimethyl-14-[(1Z,3E)-nona-1,3-dienyl]-5-oxo-16-prop-1-en-2-yl-9,13,15,19-tetraoxahexacyclo[12.4.1.01,11.02,6.08,10.012,16]nonadec-3-en-17-yl] benzoate 10077983 Click to see CCCCCC=CC=CC12OC3C4C5C(O5)(C(C6(C(C4(O1)C(C(C3(O2)C(=C)C)OC(=O)C7=CC=CC=C7)C)C=C(C6=O)C)O)O)CO 648.70 unknown via CMAUP database
[6,7-Dihydroxy-8-(hydroxymethyl)-4,18-dimethyl-14-non-1-enyl-5-oxo-16-prop-1-en-2-yl-9,13,15,19-tetraoxahexacyclo[12.4.1.01,11.02,6.08,10.012,16]nonadec-3-en-17-yl] acetate 162957762 Click to see 588.70 unknown https://doi.org/10.1002/MRC.1896
[6,7-Dihydroxy-8-(hydroxymethyl)-4,18-dimethyl-14-nona-1,3-dienyl-5-oxo-16-prop-1-en-2-yl-9,13,15,19-tetraoxahexacyclo[12.4.1.01,11.02,6.08,10.012,16]nonadec-3-en-17-yl] acetate 73227522 Click to see CCCCCC=CC=CC12OC3C4C5C(O5)(C(C6(C(C4(O1)C(C(C3(O2)C(=C)C)OC(=O)C)C)C=C(C6=O)C)O)O)CO 586.70 unknown https://doi.org/10.1016/J.BMC.2006.01.055
https://doi.org/10.1248/CPB.58.234
https://doi.org/10.1016/J.BMC.2004.10.054
[6,7-Dihydroxy-8-(hydroxymethyl)-4,18-dimethyl-14-nona-1,3-dienyl-5-oxo-16-prop-1-en-2-yl-9,13,15,19-tetraoxahexacyclo[12.4.1.01,11.02,6.08,10.012,16]nonadec-3-en-17-yl] benzoate 429656 Click to see 648.70 unknown https://doi.org/10.1016/J.JEP.2006.12.023
https://doi.org/10.1016/J.BMC.2006.01.055
https://doi.org/10.1248/CPB.58.234
https://doi.org/10.1016/J.BMC.2004.10.054
[6,7-Dihydroxy-8-(hydroxymethyl)-4,18-dimethyl-14-nona-1,3-dienyl-5-oxo-16-prop-1-en-2-yl-9,13,15,19-tetraoxahexacyclo[12.4.1.01,11.02,6.08,10.012,16]nonadec-3-en-17-yl] butanoate 74943470 Click to see CCCCCC=CC=CC12OC3C4C5C(O5)(C(C6(C(C4(O1)C(C(C3(O2)C(=C)C)OC(=O)CCC)C)C=C(C6=O)C)O)O)CO 614.70 unknown https://doi.org/10.1248/CPB.58.234
[6,7-Dihydroxy-8-(hydroxymethyl)-4,18-dimethyl-14-nona-1,3-dienyl-5-oxo-16-prop-1-en-2-yl-9,13,15,19-tetraoxahexacyclo[12.4.1.01,11.02,6.08,10.012,16]nonadec-3-en-17-yl] propanoate 74943469 Click to see CCCCCC=CC=CC12OC3C4C5C(O5)(C(C6(C(C4(O1)C(C(C3(O2)C(=C)C)OC(=O)CC)C)C=C(C6=O)C)O)O)CO 600.70 unknown https://doi.org/10.1248/CPB.58.234
[6,7-Dihydroxy-8-(hydroxymethyl)-4,18-dimethyl-14-nona-1,3,5-trienyl-5-oxo-16-prop-1-en-2-yl-9,13,15,19-tetraoxahexacyclo[12.4.1.01,11.02,6.08,10.012,16]nonadec-3-en-17-yl] acetate 75069612 Click to see 584.70 unknown https://doi.org/10.1016/J.BMC.2006.01.055
https://doi.org/10.1248/CPB.58.234
[6,7-Dihydroxy-8-(hydroxymethyl)-4,18-dimethyl-14-nona-1,3,5-trienyl-5-oxo-16-prop-1-en-2-yl-9,13,15,19-tetraoxahexacyclo[12.4.1.01,11.02,6.08,10.012,16]nonadec-3-en-17-yl] benzoate 162861794 Click to see CCCC=CC=CC=CC12OC3C4C5C(O5)(C(C6(C(C4(O1)C(C(C3(O2)C(=C)C)OC(=O)C7=CC=CC=C7)C)C=C(C6=O)C)O)O)CO 646.70 unknown https://doi.org/10.1016/J.BMC.2006.01.055
[6,7-Dihydroxy-8-(hydroxymethyl)-4,18-dimethyl-5-oxo-14-phenyl-16-prop-1-en-2-yl-9,13,15,19-tetraoxahexacyclo[12.4.1.01,11.02,6.08,10.012,16]nonadec-3-en-17-yl] propanoate 75216359 Click to see CCC(=O)OC1C(C23C4C=C(C(=O)C4(C(C5(C(C2C6C1(OC(O6)(O3)C7=CC=CC=C7)C(=C)C)O5)CO)O)O)C)C 554.60 unknown https://doi.org/10.1002/HLCA.200800419
[6,7,8,9-Tetrahydroxy-8-(hydroxymethyl)-4,17-dimethyl-13-phenyl-15-prop-1-en-2-yl-12,14,18-trioxapentacyclo[11.4.1.01,10.02,6.011,15]octadecan-5-yl] benzoate 72759445 Click to see 608.70 unknown https://doi.org/10.1016/J.BMC.2004.10.054
[6,7,8,9-Tetrahydroxy-8-(hydroxymethyl)-4,17-dimethyl-13-phenyl-15-prop-1-en-2-yl-12,14,18-trioxapentacyclo[11.4.1.01,10.02,6.011,15]octadecan-5-yl] deca-2,4-dienoate 162965886 Click to see 654.80 unknown https://doi.org/10.1016/J.BMC.2004.10.054
[6,7,8,9-Tetrahydroxy-8-(hydroxymethyl)-4,17-dimethyl-13-phenyl-15-prop-1-en-2-yl-12,14,18-trioxapentacyclo[11.4.1.01,10.02,6.011,15]octadecan-5-yl] deca-2,4,6-trienoate 162946349 Click to see CCCC=CC=CC=CC(=O)OC1C(CC2C1(C(C(C(C3C24C(CC5(C3OC(O5)(O4)C6=CC=CC=C6)C(=C)C)C)O)(CO)O)O)O)C 652.80 unknown https://doi.org/10.1016/J.BMC.2004.10.054
[6,7,8,9-Tetrahydroxy-8-(hydroxymethyl)-4,17-dimethyl-5-oxo-13-phenyl-15-prop-1-en-2-yl-12,14,18-trioxapentacyclo[11.4.1.01,10.02,6.011,15]octadec-3-en-16-yl] benzoate 75216380 Click to see 620.60 unknown https://doi.org/10.1002/HLCA.200800419
[6,7,8,9-Tetrahydroxy-8-(hydroxymethyl)-4,17-dimethyl-5-oxo-13-phenyl-15-prop-1-en-2-yl-12,14,18-trioxapentacyclo[11.4.1.01,10.02,6.011,15]octadecan-16-yl] acetate 162943849 Click to see 560.60 unknown https://doi.org/10.1002/MRC.1896
https://doi.org/10.1016/J.BMC.2004.10.054
10-Hydroxy-11-(hydroxymethyl)-4,21-dimethyl-17-phenyl-19-prop-1-en-2-yl-6,8,12,16,18,22-hexaoxaheptacyclo[15.4.1.01,14.02,9.05,9.011,13.015,19]docosan-7-one 75239076 Click to see CC1CC2C34C(CC5(C(C3C6C(O6)(C(C27C1OC(=O)O7)O)CO)OC(O5)(O4)C8=CC=CC=C8)C(=C)C)C 512.50 unknown https://doi.org/10.1007/S10600-010-9622-5
12-Acetoxydaphnetoxin 571308 Click to see 540.60 unknown https://doi.org/10.1002/MRC.1896
https://doi.org/10.1016/J.BMC.2004.10.054
12-Benzoyldaphnetoxin 428494 Click to see 602.60 unknown https://doi.org/10.1002/MRC.1896
https://doi.org/10.1016/J.JEP.2006.12.023
8-(Hydroxymethyl)-4,17-dimethyl-13-phenyl-15-prop-1-en-2-yl-12,14,18-trioxapentacyclo[11.4.1.01,10.02,6.011,15]octadecane-5,6,7,8,9-pentol 163005193 Click to see CC1CC2C34C(CC5(C(C3C(C(C(C2(C1O)O)O)(CO)O)O)OC(O5)(O4)C6=CC=CC=C6)C(=C)C)C 504.60 unknown https://doi.org/10.1016/J.BMC.2004.10.054
8-(Hydroxymethyl)-4,18-dimethyl-14-phenyl-16-prop-1-en-2-yl-9,13,15,19-tetraoxahexacyclo[12.4.1.01,11.02,6.08,10.012,16]nonadecane-5,6,7-triol 162962331 Click to see 486.60 unknown https://doi.org/10.1007/S10600-010-9622-5
Genkwadaphnin 73351913 Click to see CC1C(C2(C3C4C1(C5C=C(C(=O)C5(C(C6(C4O6)CO)O)O)C)OC(O3)(O2)C7=CC=CC=C7)C(=C)C)OC(=O)C8=CC=CC=C8 602.60 unknown https://doi.org/10.1016/J.BMCL.2013.03.025
Genkwadaphnin 46886776 Click to see 604.60 unknown via CMAUP database
genkwanine F 72188654 Click to see 654.80 unknown https://doi.org/10.1016/J.BMCL.2013.03.025
GenkwanineVIII 71593549 Click to see 590.70 unknown via CMAUP database
Isoyuanhuadine 73345818 Click to see 586.70 unknown https://doi.org/10.1016/J.BMCL.2013.03.025
Pimelea factor P2 (B811564K120) 433641 Click to see 638.80 unknown https://doi.org/10.1016/J.BMCL.2013.03.025
Simplexin 119045 Click to see 532.70 unknown https://doi.org/10.1016/J.BMCL.2013.03.025
Wikstroelide E 73347308 Click to see 532.70 unknown https://doi.org/10.1016/J.BMCL.2013.03.025
Yuanhuacin 6440205 Click to see 648.70 unknown https://doi.org/10.1016/J.BMCL.2013.03.025
https://doi.org/10.1016/J.JEP.2006.12.023
https://doi.org/10.1248/CPB.58.234
Yuanhuacine 5358691 Click to see CCCCCC=CC=CC12OC3C4C5C(O5)(C(C6(C(C4(O1)C(C(C3(O2)C(=C)C)OC(=O)C7=CC=CC=C7)C)C=C(C6=O)C)O)O)CO 648.70 unknown https://doi.org/10.1016/J.BMCL.2013.03.025
https://doi.org/10.1016/J.BMC.2006.01.055
https://doi.org/10.1248/CPB.58.234
https://doi.org/10.1016/J.BMC.2004.10.054
Yuanhuadin 6440572 Click to see 586.70 unknown https://doi.org/10.1016/J.BMC.2004.10.054
https://doi.org/10.1248/CPB.58.234
https://doi.org/10.1016/J.BMC.2006.01.055
https://doi.org/10.1021/NP2003512
https://doi.org/10.1016/J.BMCL.2013.03.025
Yuanhuafin 158277 Click to see 540.60 unknown via CMAUP database
Yuanhuahine 46191238 Click to see 600.70 unknown https://doi.org/10.1016/J.BMCL.2013.03.025
Yuanhuaoate B 73348816 Click to see CC1C(C2(C3C4C1(C5C=C(C(=O)C5(C(C(C4O)(CO)O)O)O)C)OC(O3)(O2)C6=CC=CC=C6)C(=C)C)OC(=O)C7=CC=CC=C7 620.60 unknown https://doi.org/10.1016/J.BMCL.2013.03.025
Yuanhuaoate E 73348817 Click to see 666.80 unknown https://doi.org/10.1016/J.BMCL.2013.03.025
Yuanhuapin 52918477 Click to see 542.60 unknown via CMAUP database
Yuanhuapine 73347309 Click to see 542.60 unknown https://doi.org/10.1016/J.BMCL.2013.03.025
https://doi.org/10.1016/J.BMC.2006.01.055
https://doi.org/10.1016/J.BMC.2004.10.054
> Lipids and lipid-like molecules / Prenol lipids / Sesquiterpenoids
(1R,2S,7S,8S)-1,3-dimethyl-8-propan-2-yltricyclo[4.4.0.02,7]dec-3-ene 92042749 Click to see CC1=CCC2C3C1C2(CCC3C(C)C)C 204.35 unknown https://doi.org/10.1080/10412905.1990.9697875
(3R,6E)-Nerolidol 11241545 Click to see 222.37 unknown https://doi.org/10.1080/10412905.1990.9697875
1,6,10-Dodecatrien-3-ol, 3,7,11-trimethyl- 8888 Click to see 222.37 unknown https://doi.org/10.1080/10412905.1990.9697875
alpha-Santalene 94164 Click to see 204.35 unknown https://doi.org/10.1080/10412905.1990.9697875
beta-Santalene 10889018 Click to see 204.35 unknown https://doi.org/10.1080/10412905.1990.9697875
Cadina-1(10),4-diene 10223 Click to see CC1=CC2C(CCC(=C2CC1)C)C(C)C 204.35 unknown https://doi.org/10.1080/10412905.1990.9697875
Caryophyllene 5281515 Click to see CC1=CCCC(=C)C2CC(C2CC1)(C)C 204.35 unknown https://doi.org/10.1080/10412905.1990.9697875
Copaene 19725 Click to see CC1=CCC2C3C1C2(CCC3C(C)C)C 204.35 unknown https://doi.org/10.1080/10412905.1990.9697875
delta-Cadinene 441005 Click to see 204.35 unknown https://doi.org/10.1080/10412905.1990.9697875
Norbornane, 2-methyl-3-methylene-2-(4-methyl-3-pentenyl)- 10534 Click to see 204.35 unknown https://doi.org/10.1080/10412905.1990.9697875
> Lipids and lipid-like molecules / Prenol lipids / Sesterterpenoids / Scalarane sesterterpenoids
Taraxerol 92097 Click to see 426.70 unknown via CMAUP database
Taraxerone 92785 Click to see 424.70 unknown via CMAUP database
> Lipids and lipid-like molecules / Prenol lipids / Terpene lactones / Sesquiterpene lactones / Germacranolides and derivatives
9-Hydroxyglabratolide 5991494 Click to see CC1=CC2C(C(C(C(=CCC1)C=O)O)OC(=O)C(C)C)C(=C)C(=O)O2 348.40 unknown via CMAUP database
> Lipids and lipid-like molecules / Prenol lipids / Triterpenoids
Lupeol 259846 Click to see CC(=C)C1CCC2(C1C3CCC4C5(CCC(C(C5CCC4(C3(CC2)C)C)(C)C)O)C)C 426.70 unknown via CMAUP database
> Lipids and lipid-like molecules / Steroids and steroid derivatives / Stigmastanes and derivatives
(-)-beta-Sitosterol 222284 Click to see 414.70 unknown via CMAUP database
17-(5-ethyl-6-methylheptan-2-yl)-10,13-dimethyl-2,3,4,7,8,9,11,12,14,15,16,17-dodecahydro-1H-cyclopenta[a]phenanthren-3-ol 86821 Click to see CCC(CCC(C)C1CCC2C1(CCC3C2CC=C4C3(CCC(C4)O)C)C)C(C)C 414.70 unknown via CMAUP database
Npc29 6432744 Click to see 414.70 unknown via CMAUP database
> Organic acids and derivatives / Carboxylic acids and derivatives / Amino acids, peptides, and analogues / Alpha amino acids and derivatives / Phenylalanine and derivatives
(2-Benzamido-3-phenylpropyl) 2-benzamido-3-phenylpropanoate 328238 Click to see 506.60 unknown via CMAUP database
Asperglaucide 10026486 Click to see CC(=O)OCC(CC1=CC=CC=C1)NC(=O)C(CC2=CC=CC=C2)NC(=O)C3=CC=CC=C3 444.50 unknown via CMAUP database
Asperphenamate 173952 Click to see 506.60 unknown via CMAUP database
Aurantiamide 185904 Click to see C1=CC=C(C=C1)CC(CO)NC(=O)C(CC2=CC=CC=C2)NC(=O)C3=CC=CC=C3 402.50 unknown via CMAUP database
N-Benzoyl-1-phenylalanyl-1-phenylalaninol acetate 124319 Click to see CC(=O)OCC(CC1=CC=CC=C1)NC(=O)C(CC2=CC=CC=C2)NC(=O)C3=CC=CC=C3 444.50 unknown via CMAUP database
N-Benzoylphenylalaninyl N-benzoylphenylalaninate 90474294 Click to see C1=CC=C(C=C1)CC(COC(=O)C(CC2=CC=CC=C2)NC(=O)C3=CC=CC=C3)NC(=O)C4=CC=CC=C4 506.60 unknown via CMAUP database
Npc171139 9832120 Click to see 444.50 unknown via CMAUP database
> Organic oxygen compounds / Organooxygen compounds / Carbohydrates and carbohydrate conjugates / Glycosyl compounds / Phenolic glycosides
Syringin 5316860 Click to see 372.40 unknown https://doi.org/10.1248/YAKUSHI1947.107.7_525
> Organic oxygen compounds / Organooxygen compounds / Carbonyl compounds / Aldehydes / Aryl-aldehydes
Furfural 7362 Click to see C1=COC(=C1)C=O 96.08 unknown https://doi.org/10.1080/10412905.1990.9697875
> Organoheterocyclic compounds / Benzopyrans / 1-benzopyrans / Chromones
5,13,16,18-Tetrahydroxy-4,12-bis(4-hydroxyphenyl)-3,11,21-trioxapentacyclo[11.8.0.01,10.02,7.015,20]henicosa-2(7),9,15,17,19-pentaene-8,14-dione 75144957 Click to see 558.50 unknown https://doi.org/10.1016/0031-9422(93)85303-9
https://doi.org/10.1016/0031-9422(92)80051-F
Genkwanol B 15735849 Click to see 558.50 unknown https://doi.org/10.1016/0031-9422(92)80197-M
https://doi.org/10.1016/0031-9422(93)85303-9
https://doi.org/10.1016/0031-9422(92)80051-F
Genkwanol C 131676073 Click to see 558.50 unknown https://doi.org/10.1016/0031-9422(93)85303-9
> Organoheterocyclic compounds / Benzopyrans / 1-benzopyrans / Xanthones
1,7-Dihydroxy-3,8-dimethoxyxanthone 5281634 Click to see 288.25 unknown via CMAUP database
> Phenylpropanoids and polyketides / 2-arylbenzofuran flavonoids
(2'R,3'S,8'R)-3',4,5',6-tetrahydroxy-2',8'-bis(4-hydroxyphenyl)spiro[1-benzofuran-2,9'-2,3,4,8-tetrahydrofuro[2,3-h]chromene]-3-one 196642 Click to see C1C(C(OC2=C1C(=CC3=C2C4(C(O3)C5=CC=C(C=C5)O)C(=O)C6=C(C=C(C=C6O4)O)O)O)C7=CC=C(C=C7)O)O 542.50 unknown https://doi.org/10.1248/YAKUSHI1947.107.7_525
(2R,2'R,3'R,8'R)-3',4,5',6-tetrahydroxy-2',8'-bis(4-hydroxyphenyl)spiro[1-benzofuran-2,9'-2,3,4,8-tetrahydrofuro[2,3-h]chromene]-3-one 162957567 Click to see C1C(C(OC2=C1C(=CC3=C2C4(C(O3)C5=CC=C(C=C5)O)C(=O)C6=C(C=C(C=C6O4)O)O)O)C7=CC=C(C=C7)O)O 542.50 unknown https://doi.org/10.1248/YAKUSHI1947.107.7_525
Daphnodorin B 72427 Click to see C1C(C(OC2=C1C(=CC3=C2C(=C(O3)C4=CC=C(C=C4)O)C(=O)C5=C(C=C(C=C5O)O)O)O)C6=CC=C(C=C6)O)O 542.50 unknown https://doi.org/10.1248/YAKUSHI1947.107.7_525
Genkwanol A 394845 Click to see 542.50 unknown https://doi.org/10.1248/YAKUSHI1947.107.7_525
> Phenylpropanoids and polyketides / Coumarins and derivatives
Daphnoretin methyl ether 5318544 Click to see COC1=C(C=C2C(=C1)C=C(C(=O)O2)OC3=CC4=C(C=C3)C=CC(=O)O4)OC 366.30 unknown via CMAUP database
> Phenylpropanoids and polyketides / Coumarins and derivatives / Coumarin glycosides
Daphnorin 185819 Click to see 514.40 unknown https://doi.org/10.1248/YAKUSHI1947.107.7_525
> Phenylpropanoids and polyketides / Coumarins and derivatives / Hydroxycoumarins / 7-hydroxycoumarins
Daphnoretin 5281406 Click to see 352.30 unknown https://doi.org/10.1248/YAKUSHI1947.107.7_525
Umbelliferone 5281426 Click to see C1=CC(=CC2=C1C=CC(=O)O2)O 162.14 unknown https://doi.org/10.1248/YAKUSHI1947.107.7_525
> Phenylpropanoids and polyketides / Flavonoids / Biflavonoids and polyflavonoids
(1S,5S,6R,13R)-1,6,9,17,19-pentahydroxy-5,13-bis(4-hydroxyphenyl)-4,12,14-trioxapentacyclo[11.8.0.02,11.03,8.015,20]henicosa-2(11),3(8),9,15,17,19-hexaen-21-one 15984106 Click to see 558.50 unknown via CMAUP database
> Phenylpropanoids and polyketides / Flavonoids / Flavans / Flavan-3-ols
ethyl (2S,3R)-3,5,7-trihydroxy-2-(4-hydroxyphenyl)-3,4-dihydro-2H-chromene-8-carboxylate 162876363 Click to see CCOC(=O)C1=C(C=C(C2=C1OC(C(C2)O)C3=CC=C(C=C3)O)O)O 346.30 unknown https://doi.org/10.1016/J.FITOTE.2007.04.006
> Phenylpropanoids and polyketides / Flavonoids / Flavones
2-(3,4-dihydroxyphenyl)-5-hydroxy-4-oxo-4H-chromen-7-olate luteolin-7-olate(1-) 25201972 Click to see C1=CC(=C(C=C1C2=CC(=O)C3=C(C=C(C=C3O2)O)O)O)[O-] 285.23 unknown via CMAUP database
2-(3,4-dihydroxyphenyl)-5,7-dihydroxy-3-[[(3S,4R,5S)-3,4,5,6-tetrahydroxyoxan-2-yl]methoxy]chromen-4-one 5480505 Click to see C1=CC(=C(C=C1C2=C(C(=O)C3=C(C=C(C=C3O2)O)O)OCC4C(C(C(C(O4)O)O)O)O)O)O 464.40 unknown via CMAUP database
Apigenin 5280443 Click to see C1=CC(=CC=C1C2=CC(=O)C3=C(C=C(C=C3O2)O)O)O 270.24 unknown https://doi.org/10.1248/CPB.31.3984
https://doi.org/10.1248/YAKUSHI1881.52.8_83
https://doi.org/10.38212/2224-6614.2810
Apigenin-7-olate 25200950 Click to see 269.23 unknown via CMAUP database
Luteolin 5280445 Click to see C1=CC(=C(C=C1C2=CC(=O)C3=C(C=C(C=C3O2)O)O)O)O 286.24 unknown https://doi.org/10.1248/CPB.31.3984
https://doi.org/10.1248/CPB.35.675
https://doi.org/10.38212/2224-6614.2810
> Phenylpropanoids and polyketides / Flavonoids / Flavones / Flavonols
8-Methoxykaempferol 5281698 Click to see 316.26 unknown via CMAUP database
Kaempferol 5280863 Click to see 286.24 unknown https://doi.org/10.38212/2224-6614.2810
Rhamnocitrin 5320946 Click to see 300.26 unknown via CMAUP database
> Phenylpropanoids and polyketides / Flavonoids / Flavonoid glycosides / Flavonoid 3-O-p-coumaroyl glycosides
(6-(5,7-Dihydroxy-2-(4-hydroxyphenyl)-4-oxochromen-3-yl)oxy-3,4,5-trihydroxyoxan-2-yl)methyl 3-(4-hydroxyphenyl)prop-2-enoate 57369598 Click to see 594.50 unknown https://doi.org/10.1248/CPB.35.675
[(2R,3S,6S)-6-[5,7-dihydroxy-2-(4-hydroxyphenyl)-4-oxochromen-3-yl]oxy-3,4,5-trihydroxyoxan-2-yl]methyl (E)-3-(4-hydroxyphenyl)prop-2-enoate 44258863 Click to see 594.50 unknown via CMAUP database
Tiliroside 5320686 Click to see 594.50 unknown https://doi.org/10.1248/CPB.35.675
https://doi.org/10.38212/2224-6614.2810
> Phenylpropanoids and polyketides / Flavonoids / Flavonoid glycosides / Flavonoid O-glycosides
Luteolin 5-glucoside 5317471 Click to see C1=CC(=C(C=C1C2=CC(=O)C3=C(O2)C=C(C=C3OC4C(C(C(C(O4)CO)O)O)O)O)O)O 448.40 unknown https://doi.org/10.38212/2224-6614.2810
Yuankanin 157000 Click to see 578.50 unknown via CMAUP database
> Phenylpropanoids and polyketides / Flavonoids / Flavonoid glycosides / Flavonoid O-glycosides / Flavonoid-7-O-glycosides
Apigenin 7-O-glucoside 5280704 Click to see 432.40 unknown via CMAUP database
Apigenin-7-O-Glucoside 12304093 Click to see C1=CC(=CC=C1C2=CC(=O)C3=C(C=C(C=C3O2)OC4C(C(C(C(O4)CO)O)O)O)O)O 432.40 unknown via CMAUP database
> Phenylpropanoids and polyketides / Flavonoids / O-methylated flavonoids / 7-O-methylated flavonoids
5-Hydroxy-7,4'-dimethoxyflavone 5281601 Click to see 298.29 unknown via CMAUP database
7-O-Methylluteolin 5318214 Click to see COC1=CC(=C2C(=C1)OC(=CC2=O)C3=CC(=C(C=C3)O)O)O 300.26 unknown https://doi.org/10.1248/CPB.31.3984
https://doi.org/10.1248/CPB.35.675
Apigenin trimethyl ether 79730 Click to see COC1=CC=C(C=C1)C2=CC(=O)C3=C(O2)C=C(C=C3OC)OC 312.30 unknown via CMAUP database
Genkwanin 5281617 Click to see 284.26 unknown https://doi.org/10.38212/2224-6614.2810
https://doi.org/10.1248/YAKUSHI1881.52.10_148
https://doi.org/10.1248/CPB.31.3984
Gonzalitosin I 5272653 Click to see 328.30 unknown via CMAUP database
Velutin 5464381 Click to see COC1=CC(=C2C(=C1)OC(=CC2=O)C3=CC(=C(C=C3)O)OC)O 314.29 unknown via CMAUP database
> Phenylpropanoids and polyketides / Macrolides and analogues
Pimelotide A 44613292 Click to see 546.60 unknown https://doi.org/10.1016/J.BMCL.2013.03.025
Pimelotide C 50900411 Click to see CC1CCCCCCCC23OC4C5C6C(O6)(C(C78C(C1C(O7)(OC8=O)C)C5(O2)C(CC4(O3)C(=C)C)C)O)CO 546.60 unknown https://doi.org/10.1016/J.BMCL.2013.03.025

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