Brodiaea californica

Details Top

Internal ID UUID644025632f4aa358193559
Scientific name Brodiaea californica
Authority Lindl. ex Lem.
First published in Fl. Serres Jard. Eur. 5: 428b (1849)

Ethnobotanical Use Top

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Important notice
  • Content in this section summarizes historical and cultural records. It is not medical advice.
  • Do not use plants for self-treatment. Safety, efficacy, and appropriate use are not established here.
  • Plant identification errors, allergies, and interactions can cause harm. Consult qualified professionals for health questions.
  • Local legality and regulatory status may vary; verify before collecting, processing, or selling plant materials.

Traditional culinary preparations have been recorded for Brodiaea californica corms among several California peoples. Kawaiisu diggers in the southern Sierra foothills peeled and boiled the corms in water until tender, or sometimes baked them in the ashes of a fire; the same handling methods are documented for Yokuts in the San Joaquin Valley, where the cooked corms were eaten as a starchy food; Pomo groups of Mendocino County similarly peeled the corms and boiled them, then ate them plain or mixed with other foods. Moerman and Pullen’s compilations record these uses for Brodiaea californica, noting that brodiaea corms in general were among the season’s most important staple roots and that people sometimes sliced them thinly and sun‑dried portions for later cooking. According to a regional overview by Anderson and Üce, soaking or boiling was the standard way to render the fibrous texture of the corms palatable.

A practical recipe reflects how the plant was handled in those traditions. Use about 200 g fresh, washed corms, carefully peeled to remove any exterior fibers. Bring 500 ml of water to a gentle boil, add the peeled corms, and simmer for 30–45 minutes until the pieces are easily pierced with a fork. Drain and serve warm as a soft, slightly sweet starch; or cool, slice, and fold into a salad or grain dish. A common safety practice among Indigenous cooks was to avoid eating raw corms and to rely on thorough boiling or baking; this is good advice for modern home cooks as well.

Nutritionally, the corms are chiefly composed of starches and fructans, with relatively low protein and fat, which explains why they were boiled or baked to soften fibers and unlock energy density. These carbohydrate reserves and other co‑occurring compounds such as saponins and phenolics are the principal phytochemicals reported in Brodiaea species, and they plausibly account for the filling, modest palatability gained by cooking. Anderson and Üce also note that Native cooks often favored species with less bitter or bitter‑tannic profiles when available, suggesting that Brodiaea californica’s flavor was acceptable rather than medicinal.

Today, the cluster lily survives in degraded grasslands and vernal pool margins of central and northern California, where historic dig sites persist near populated areas. Interest remains strongest among cultural practitioners and community stewardship programs that manage corms as seasonal food plants and among botanists monitoring the health of small‑scale populations.

General Uses Top

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Common products:
Ornamental horticulture – Brodiaea californica is cultivated as a perennial corm and sold by native‑plant nurseries for garden and landscape use. It is recommended for rock gardens, dry‑border plantings, and container displays, where its compact habit (15–30 cm) and long‑lasting blue‑purple to pinkish flowers provide seasonal colour. The species is also listed in trade catalogues as a cut‑flower crop; stems are harvested in early summer when buds are fully expanded and retain colour and form for 7–10 days in vase, making it a specialty product for boutique floral designs. Commercial production is based on vegetative propagation of mature corms, allowing nurseries to offer uniform, disease‑free stock for both retail and wholesale markets.

Properties relevant to use:
The plant’s ornamental value stems from its showy, star‑shaped inflorescences that open sequentially over several weeks, providing an extended display. The corms store starch, enabling vegetative propagation by division and allowing growers to produce uniform stock without seeds. Adapted to Mediterranean‑type climates, B. californica thrives in well‑drained soils, tolerates summer drought, and requires minimal irrigation once established, reducing water use in cultivated settings. The flower colour arises from anthocyanins, a characteristic appreciated in horticultural design, and the stems maintain turgidity after cutting, supporting the extended vase life reported by florists.

Sustainability and sourcing:
Commercial material is sourced almost exclusively from nursery‑propagated stock rather than wild collection. Propagation is accomplished by dividing mature corms in late summer; corms can be stored dry at 4 °C for three to four months, enabling off‑season sales and reducing disturbance of natural habitats. The species is classified as “secure” in the California Natural Diversity Database, indicating low conservation concern, but native‑plant societies recommend planting cultivated specimens to support pollinator habitats and preserve regional genetic diversity. Sustainable horticulture practices—such as organic growing media, minimal chemical inputs, and integrated pest management—are commonly employed by specialty nurseries handling B. californica, ensuring the ornamental use remains environmentally responsible.

Synonyms Top

Scientific name Authority First published in
Hookera californica (Lindl. ex Lem.) Greene Bull. Calif. Acad. Sci. 2(6): 136. 1886 [1887 publ. 1886]
Brodiaea grandiflora var. elatior Baker J. Linn. Soc., Bot. 11: 377. 1870

Common names Top

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Language Common/alternative name
English california brodiaea
Finnish brodia
Chinese 加州冠花韭
Chinese 布罗地石蒜
Chinese 布羅地石蒜

Subspecies (abbr. subsp./ssp.) Top

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Name Authority First published in
Brodiaea californica subsp. californica Unknown
Brodiaea californica subsp. leptandra (Greene) J.C.Pires Taxon 50: 201 (2001)

Varieties (abbr. var.) Top

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No variety added yet.

Subvarieties (abbr. subvar.) Top

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Forms (abbr. f.) Top

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Germination/Propagation Top

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No germination or propagation data was added yet.

Distribution (via POWO/KEW) Top

No distribution data was extracted from POWO/KEW yet. We are constantly monitoring for new data.

Links to other databases Top

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Database ID/link to page
World Flora Online wfo-0000762063
USDA Plants BRCA4
Tropicos 18401483
KEW urn:lsid:ipni.org:names:532023-1
The Plant List kew-301047
Open Tree Of Life 655277
NCBI Taxonomy 244021
Nature Serve 2.1212645
IPNI 36706-2
iNaturalist 63779
GBIF 2767692
Freebase /m/03gw43h
EOL 1086378
Calflora (Californian flora) 1168
USDA GRIN 446916
Wikipedia Brodiaea_californica
CMAUP NPO12480

Genomes (via NCBI) Top

No reference genome is available on NCBI yet. We are constantly monitoring for new data.

Scientific Literature Top

Below are displayed the latest 15 articles published in PMC (PubMed Central®) and other sources (DOI number only)!
If you wish to see all the related articles click here.
Title Authors Publication Released IDs
Research Status and Hotspots of Anticancer Natural Products Based on the Patent Literature and Scientific Articles Shen J, Li J, Yu P, Du G Front Pharmacol 17-Jun-2022
PMCID:PMC9247190
doi:10.3389/fphar.2022.903239
PMID:35784720
Brodioside B, a Novel (20<i>R</i>,22<i>S</i>)-Spirostanol Tetrasaccharide from <i>Brodiaea californica</i> Tubers Osamu Nakamura, Yoshihiro Mimaki, Yutaka Sashida, Tamotsu Nikaido, Taichi Ohmoto Oxford University Press (OUP) 19-Apr-2006
doi:10.1246/CL.1994.805
Brodiosaponins A−F, Six New Polyhydroxylated Steroidal Saponins from the Tubers of <i>Brodiaea californica</i> Yoshihiro Mimaki, Minpei Kuroda, Osamu Nakamura, Yutaka Sashida American Chemical Society (ACS) 26-Jul-2002
doi:10.1021/NP960749G
New polyhydroxylated steroidal saponins from the tubers of Brodiaea californica. Mimaki Y, Kuroda M, Nakamura O, Sashida Y, Satou T, Koike K, Nikaido T Chem Pharm Bull (Tokyo) 01-Mar-1997
doi:10.1248/CPB.45.558
PMID:9085561
Structures of steroidal saponins from the tubers of Brodiaea californica and their inhibitory activity on tumor promoter-induced phospholipid metabolism. Mimaki Y, Nakamura O, Sashida Y, Koike K, Nikaido T, Ohmoto T, Nishino A, Satomi Y, Nishino H Chem Pharm Bull (Tokyo) 01-Jun-1995
doi:10.1248/CPB.43.971
PMID:7641317

Phytochemical Profile Top

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Below are displayed the proven (via scientific papers) natural compounds!
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Name PubChem ID Canonical SMILES MW Found in Proof
> Benzenoids / Benzene and substituted derivatives / Benzoic acids and derivatives / Hydroxybenzoic acid derivatives
4-Hydroxybenzoic acid 135 Click to see C1=CC(=CC=C1C(=O)O)O 138.12 unknown via CMAUP database
> Benzenoids / Benzene and substituted derivatives / Benzoic acids and derivatives / Methoxybenzoic acids and derivatives / M-methoxybenzoic acids and derivatives
Vanillic Acid 8468 Click to see COC1=C(C=CC(=C1)C(=O)O)O 168.15 unknown via CMAUP database
> Hydrocarbons / Saturated hydrocarbons / Alkanes
Hentriacontane 12410 Click to see 436.80 unknown via CMAUP database
> Lipids and lipid-like molecules / Prenol lipids / Terpene glycosides / Iridoid O-glycosides
Aucubin 91458 Click to see C1=COC(C2C1C(C=C2CO)O)OC3C(C(C(C(O3)CO)O)O)O 346.33 unknown via CMAUP database
> Lipids and lipid-like molecules / Prenol lipids / Triterpenoids
(+)-Ursolic Acid 64945 Click to see 456.70 unknown via CMAUP database
(1S,2R,4aS,6aR,6aS,6bR,8aR,10S,12aR,14bR)-10-hydroxy-1,2,6a,6b,9,9,12a-heptamethyl-2,3,4,5,6,6a,7,8,8a,10,11,12,13,14b-tetradecahydro-1H-picene-4a-carboxylic acid 7163172 Click to see 456.70 unknown via CMAUP database
> Lipids and lipid-like molecules / Steroids and steroid derivatives / Steroidal glycosides / Steroidal saponins
(1R,2S,3'S,4S,4'S,5'R,6S,7S,8R,9S,10R,12S,13R,14R,16R)-14-[(2R,3R,4S,5R,6R)-5-hydroxy-6-(hydroxymethyl)-3-[(2S,3R,4R,5R,6S)-3,4,5-trihydroxy-6-methyloxan-2-yl]oxy-4-[(2S,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxyoxan-2-yl]oxy-5',7,9,13-tetramethyl-4'-[(2S,3R,4R,5R,6R)-3,4,5-trihydroxy-6-methyloxan-2-yl]oxyspiro[5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-ene-6,2'-oxane]-3',10,16-triol 163093997 Click to see 1065.20 unknown https://doi.org/10.1021/NP960749G
(1R,2S,3'S,4S,4'S,5'R,6S,7S,8R,9S,10R,12S,13R,14R,16R)-14-[(2R,3R,4S,5R,6R)-5-hydroxy-6-(hydroxymethyl)-3-[(2S,3R,4R,5R,6S)-3,4,5-trihydroxy-6-methyloxan-2-yl]oxy-4-[(2S,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxyoxan-2-yl]oxy-5',7,9,13-tetramethyl-4'-[(2S,3R,4S,5R,6R)-3,4,5-trihydroxy-6-methyloxan-2-yl]oxyspiro[5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-ene-6,2'-oxane]-3',10,16-triol 163093996 Click to see 1065.20 unknown https://doi.org/10.1021/NP960749G
(1R,2S,3'S,4S,4'S,5'R,6S,7S,8R,9S,10R,12S,13R,14R,16R)-14-[(2R,3R,4S,5R,6R)-5-hydroxy-6-(hydroxymethyl)-3-[(2S,3R,4R,5R,6S)-3,4,5-trihydroxy-6-methyloxan-2-yl]oxy-4-[(2S,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxyoxan-2-yl]oxy-5',7,9,13-tetramethylspiro[5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-ene-6,2'-oxane]-3',4',10,16-tetrol 162873901 Click to see 919.00 unknown https://doi.org/10.1021/NP960749G
(1R,2S,3'S,4S,4'S,5'R,6S,7S,8R,9S,10R,12S,13R,14R,16R)-14-[(2R,3R,4S,5S,6R)-3-[(2S,3R,4R,5S,6S)-3,5-dihydroxy-6-methyl-4-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-4,5-dihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-5',7,9,13-tetramethyl-4'-[(2S,3R,4R,5R,6R)-3,4,5-trihydroxy-6-methyloxan-2-yl]oxyspiro[5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-ene-6,2'-oxane]-3',10,16-triol 162944991 Click to see 1095.20 unknown https://doi.org/10.1021/NP960749G
(1S,2S,3'S,4S,4'S,5'R,6S,7R,8R,9S,10R,12S,13R,14R,16R)-14-[(2R,3R,4S,5R,6R)-5-hydroxy-6-(hydroxymethyl)-3-[(2S,3R,4R,5R,6S)-3,4,5-trihydroxy-6-methyloxan-2-yl]oxy-4-[(2S,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxyoxan-2-yl]oxy-5',7,9,13-tetramethyl-4'-[(2S,3R,4R,5R,6R)-3,4,5-trihydroxy-6-methyloxan-2-yl]oxyspiro[5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-ene-6,2'-oxane]-3',10,16-triol 163093998 Click to see 1065.20 unknown https://doi.org/10.1021/NP960749G
(1S,2S,3'S,4S,4'S,5'R,6S,7S,8R,9S,10R,12S,13R,14R,16R)-14-[(2R,3R,4S,5R,6R)-5-hydroxy-6-(hydroxymethyl)-3-[(2S,3R,4R,5R,6S)-3,4,5-trihydroxy-6-methyloxan-2-yl]oxy-4-[(2S,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxyoxan-2-yl]oxy-5',7,9,13-tetramethyl-4'-[(2S,3R,4S,5R,6R)-3,4,5-trihydroxy-6-methyloxan-2-yl]oxyspiro[5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-ene-6,2'-oxane]-3',10,16-triol 101713203 Click to see 1065.20 unknown https://doi.org/10.1021/NP960749G
(1S,2S,3'S,4S,4'S,5'R,6S,7S,8R,9S,10R,12S,13R,14R,16R)-14-[(2R,3R,4S,5R,6R)-5-hydroxy-6-(hydroxymethyl)-3-[(2S,3R,4R,5R,6S)-3,4,5-trihydroxy-6-methyloxan-2-yl]oxy-4-[(2S,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxyoxan-2-yl]oxy-5',7,9,13-tetramethyl-4'-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-methyloxan-2-yl]oxyspiro[5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-ene-6,2'-oxane]-3',10,16-triol 101713206 Click to see 1065.20 unknown https://doi.org/10.1021/NP960749G
(1S,2S,3'S,4S,4'S,5'R,6S,7S,8R,9S,10R,12S,13R,14R,16R)-14-[(2R,3R,4S,5R,6R)-5-hydroxy-6-(hydroxymethyl)-3-[(2S,3R,4R,5R,6S)-3,4,5-trihydroxy-6-methyloxan-2-yl]oxy-4-[(2S,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxyoxan-2-yl]oxy-5',7,9,13-tetramethylspiro[5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-ene-6,2'-oxane]-3',4',10,16-tetrol 102066926 Click to see CC1COC2(C(C3C(O2)CC4C3(C(CC5C4CC=C6C5(C(CC(C6)O)OC7C(C(C(C(O7)CO)O)OC8C(C(C(CO8)O)O)O)OC9C(C(C(C(O9)C)O)O)O)C)O)C)C)C(C1O)O 919.00 unknown https://doi.org/10.1021/NP960749G
https://doi.org/10.1248/CPB.45.558
(1S,2S,3'S,4S,4'S,5'R,6S,7S,8R,9S,10R,12S,13R,14R,16R)-14-[(2R,3R,4S,5S,6R)-3-[(2S,3R,4R,5S,6S)-3,5-dihydroxy-6-methyl-4-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-4,5-dihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-5',7,9,13-tetramethyl-3'-[(2S,3R,4R,5R,6R)-3,4,5-trihydroxy-6-methyloxan-2-yl]oxyspiro[5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-ene-6,2'-oxane]-4',10,16-triol 163035735 Click to see CC1COC2(C(C3C(O2)CC4C3(C(CC5C4CC=C6C5(C(CC(C6)O)OC7C(C(C(C(O7)CO)O)O)OC8C(C(C(C(O8)C)O)OC9C(C(C(C(O9)CO)O)O)O)O)C)O)C)C)C(C1O)OC1C(C(C(C(O1)C)O)O)O 1095.20 unknown https://doi.org/10.1248/CPB.45.558
(1S,2S,3'S,4S,4'S,5'R,6S,7S,8R,9S,10R,12S,13R,14R,16R)-14-[(2R,3R,4S,5S,6R)-3-[(2S,3R,4R,5S,6S)-3,5-dihydroxy-6-methyl-4-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-4,5-dihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-5',7,9,13-tetramethyl-4'-[(2S,3R,4R,5R,6R)-3,4,5-trihydroxy-6-methyloxan-2-yl]oxyspiro[5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-ene-6,2'-oxane]-3',10,16-triol 102066927 Click to see 1095.20 unknown https://doi.org/10.1021/NP960749G
(1S,2S,3'S,4S,4'S,5'R,6S,7S,8R,9S,10R,12S,13R,14R,16R)-14-[(2R,3R,4S,5S,6R)-3-[(2S,3R,4R,5S,6S)-3,5-dihydroxy-6-methyl-4-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-4,5-dihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-5',7,9,13-tetramethyl-4'-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-methyloxan-2-yl]oxyspiro[5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-ene-6,2'-oxane]-3',10,16-triol 101713205 Click to see CC1COC2(C(C3C(O2)CC4C3(C(CC5C4CC=C6C5(C(CC(C6)O)OC7C(C(C(C(O7)CO)O)O)OC8C(C(C(C(O8)C)O)OC9C(C(C(C(O9)CO)O)O)O)O)C)O)C)C)C(C1OC1C(C(C(C(O1)C)O)O)O)O 1095.20 unknown https://doi.org/10.1021/NP960749G
(2S,3R,4S,5S,6R)-2-[(2S,3R,4R,5S,6S)-2-[(2R,3R,4S,5S,6R)-4,5-dihydroxy-6-(hydroxymethyl)-2-[(1S,2S,4S,5'S,6R,7S,8R,9S,12S,13R,14R,16R)-16-hydroxy-5',7,9,13-tetramethylspiro[5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-ene-6,2'-oxane]-14-yl]oxyoxan-3-yl]oxy-3,5-dihydroxy-6-methyloxan-4-yl]oxy-6-(hydroxymethyl)oxane-3,4,5-triol 162888736 Click to see CC1CCC2(C(C3C(O2)CC4C3(CCC5C4CC=C6C5(C(CC(C6)O)OC7C(C(C(C(O7)CO)O)O)OC8C(C(C(C(O8)C)O)OC9C(C(C(C(O9)CO)O)O)O)O)C)C)C)OC1 901.00 unknown https://doi.org/10.1248/CPB.43.971
(2S,3R,4S,5S,6R)-2-[(2S,3R,4R,5S,6S)-3,5-dihydroxy-2-[(2R,3R,4S,5R,6R)-5-hydroxy-6-(hydroxymethyl)-2-[(1S,2S,4S,5'R,6R,7R,8R,9S,12S,13R,14R,16R)-16-hydroxy-5',7,9,13-tetramethylspiro[5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-ene-6,2'-oxane]-14-yl]oxy-4-[(2S,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxyoxan-3-yl]oxy-6-methyloxan-4-yl]oxy-6-(hydroxymethyl)oxane-3,4,5-triol 162897823 Click to see 1033.20 unknown https://doi.org/10.1248/CPB.43.971
(2S,3R,4S,5S,6R)-2-[(2S,3R,4R,5S,6S)-3,5-dihydroxy-2-[(2R,3R,4S,5R,6R)-5-hydroxy-6-(hydroxymethyl)-2-[(1S,2S,4S,5'S,6R,7S,8R,9S,12S,13R,14R,16R)-16-hydroxy-5',7,9,13-tetramethylspiro[5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-ene-6,2'-oxane]-14-yl]oxy-4-[(2S,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxyoxan-3-yl]oxy-6-methyloxan-4-yl]oxy-6-(hydroxymethyl)oxane-3,4,5-triol 162897824 Click to see CC1CCC2(C(C3C(O2)CC4C3(CCC5C4CC=C6C5(C(CC(C6)O)OC7C(C(C(C(O7)CO)O)OC8C(C(C(CO8)O)O)O)OC9C(C(C(C(O9)C)O)OC2C(C(C(C(O2)CO)O)O)O)O)C)C)C)OC1 1033.20 unknown https://doi.org/10.1246/CL.1994.805
https://doi.org/10.1248/CPB.43.971
(2S,3R,4S,5S,6R)-2-[(2S,3R,4R,5S,6S)-3,5-dihydroxy-2-[(2R,3R,4S,5R,6R)-5-hydroxy-6-(hydroxymethyl)-2-[(1S,2S,4S,5'S,6S,7R,8R,9S,12S,13R,14R,16R)-16-hydroxy-5',7,9,13-tetramethylspiro[5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-ene-6,2'-oxane]-14-yl]oxy-4-[(2S,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxyoxan-3-yl]oxy-6-methyloxan-4-yl]oxy-6-(hydroxymethyl)oxane-3,4,5-triol 162897822 Click to see 1033.20 unknown https://doi.org/10.1246/CL.1994.805
[(2R,3R,4S,5R,6R)-5-[(2S,3R,4R,5S,6S)-3,5-dihydroxy-6-methyl-4-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-3-hydroxy-6-[(1S,2S,4S,5'S,6R,7S,8R,9S,12S,13R,14R,16R)-16-hydroxy-5',7,9,13-tetramethylspiro[5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-ene-6,2'-oxane]-14-yl]oxy-4-[(2S,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxyoxan-2-yl]methyl acetate 10418661 Click to see 1075.20 unknown https://doi.org/10.1248/CPB.43.971
[(2S,3R,4R,5R,6S)-4,5-dihydroxy-6-[(2R,3R,4S,5R,6R)-5-hydroxy-6-(hydroxymethyl)-4-[(2S,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxy-2-[(1R,2S,3'S,4S,4'S,5'R,6S,7S,8R,9S,10R,12S,13R,14R,16R)-3',10,16-trihydroxy-5',7,9,13-tetramethyl-4'-[(2S,3R,4R,5R,6R)-3,4,5-trihydroxy-6-methyloxan-2-yl]oxyspiro[5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-ene-6,2'-oxane]-14-yl]oxyoxan-3-yl]oxy-2-methyloxan-3-yl] acetate 162965259 Click to see 1107.20 unknown https://doi.org/10.1021/NP960749G
[(2S,3R,4R,5R,6S)-4,5-dihydroxy-6-[(2R,3R,4S,5R,6R)-5-hydroxy-6-(hydroxymethyl)-4-[(2S,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxy-2-[(1R,2S,3'S,4S,4'S,5'R,6S,7S,8R,9S,10R,12S,13R,14R,16R)-3',10,16-trihydroxy-5',7,9,13-tetramethyl-4'-[(2S,3R,4S,5R,6R)-3,4,5-trihydroxy-6-methyloxan-2-yl]oxyspiro[5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-ene-6,2'-oxane]-14-yl]oxyoxan-3-yl]oxy-2-methyloxan-3-yl] acetate 162965258 Click to see 1107.20 unknown https://doi.org/10.1021/NP960749G
[(2S,3R,4S,5R,6S)-4,5-dihydroxy-6-[(2R,3R,4S,5R,6R)-5-hydroxy-6-(hydroxymethyl)-4-[(2S,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxy-2-[(1S,2S,3'S,4S,4'S,5'R,6S,7S,8R,9S,10R,12S,13R,14R,16R)-3',10,16-trihydroxy-5',7,9,13-tetramethyl-4'-[(2S,3R,4R,5R,6R)-3,4,5-trihydroxy-6-methyloxan-2-yl]oxyspiro[5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-ene-6,2'-oxane]-14-yl]oxyoxan-3-yl]oxy-2-methyloxan-3-yl] acetate 162965260 Click to see 1107.20 unknown https://doi.org/10.1021/NP960749G
[(2S,3R,4S,5R,6S)-4,5-dihydroxy-6-[(2R,3R,4S,5R,6R)-5-hydroxy-6-(hydroxymethyl)-4-[(2S,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxy-2-[(1S,2S,3'S,4S,4'S,5'R,6S,7S,8R,9S,10R,12S,13R,14R,16R)-3',10,16-trihydroxy-5',7,9,13-tetramethyl-4'-[(2S,3R,4S,5R,6R)-3,4,5-trihydroxy-6-methyloxan-2-yl]oxyspiro[5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-ene-6,2'-oxane]-14-yl]oxyoxan-3-yl]oxy-2-methyloxan-3-yl] acetate 101713204 Click to see CC1COC2(C(C3C(O2)CC4C3(C(CC5C4CC=C6C5(C(CC(C6)O)OC7C(C(C(C(O7)CO)O)OC8C(C(C(CO8)O)O)O)OC9C(C(C(C(O9)C)OC(=O)C)O)O)C)O)C)C)C(C1OC1C(C(C(C(O1)C)O)O)O)O 1107.20 unknown https://doi.org/10.1021/NP960749G
[(2S,3R,4S,5R,6S)-4,5-dihydroxy-6-[(2R,3R,4S,5R,6R)-5-hydroxy-6-(hydroxymethyl)-4-[(2S,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxy-2-[(1S,2S,3'S,4S,4'S,5'R,6S,7S,8R,9S,10R,12S,13R,14R,16R)-3',10,16-trihydroxy-5',7,9,13-tetramethyl-4'-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-methyloxan-2-yl]oxyspiro[5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-ene-6,2'-oxane]-14-yl]oxyoxan-3-yl]oxy-2-methyloxan-3-yl] acetate 101713207 Click to see 1107.20 unknown https://doi.org/10.1021/NP960749G
[4,5-Dihydroxy-6-[5-hydroxy-6-(hydroxymethyl)-4-(3,4,5-trihydroxyoxan-2-yl)oxy-2-[3',10,16-trihydroxy-5',7,9,13-tetramethyl-4'-(3,4,5-trihydroxy-6-methyloxan-2-yl)oxyspiro[5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-ene-6,2'-oxane]-14-yl]oxyoxan-3-yl]oxy-2-methyloxan-3-yl] acetate 75094367 Click to see CC1COC2(C(C3C(O2)CC4C3(C(CC5C4CC=C6C5(C(CC(C6)O)OC7C(C(C(C(O7)CO)O)OC8C(C(C(CO8)O)O)O)OC9C(C(C(C(O9)C)OC(=O)C)O)O)C)O)C)C)C(C1OC1C(C(C(C(O1)C)O)O)O)O 1107.20 unknown https://doi.org/10.1021/NP960749G
[5-[3,5-Dihydroxy-6-methyl-4-[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-3-hydroxy-6-(16-hydroxy-5',7,9,13-tetramethylspiro[5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-ene-6,2'-oxane]-14-yl)oxy-4-(3,4,5-trihydroxyoxan-2-yl)oxyoxan-2-yl]methyl acetate 85138151 Click to see 1075.20 unknown https://doi.org/10.1248/CPB.43.971
14-[3-[3,5-Dihydroxy-6-methyl-4-[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-4,5-dihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-5',7,9,13-tetramethyl-3'-(3,4,5-trihydroxy-6-methyloxan-2-yl)oxyspiro[5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-ene-6,2'-oxane]-4',10,16-triol 163035734 Click to see CC1COC2(C(C3C(O2)CC4C3(C(CC5C4CC=C6C5(C(CC(C6)O)OC7C(C(C(C(O7)CO)O)O)OC8C(C(C(C(O8)C)O)OC9C(C(C(C(O9)CO)O)O)O)O)C)O)C)C)C(C1O)OC1C(C(C(C(O1)C)O)O)O 1095.20 unknown https://doi.org/10.1248/CPB.45.558
14-[3-[3,5-Dihydroxy-6-methyl-4-[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-4,5-dihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-5',7,9,13-tetramethyl-4'-(3,4,5-trihydroxy-6-methyloxan-2-yl)oxyspiro[5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-ene-6,2'-oxane]-3',10,16-triol 85166347 Click to see 1095.20 unknown https://doi.org/10.1021/NP960749G
14-[5-Hydroxy-6-(hydroxymethyl)-3-(3,4,5-trihydroxy-6-methyloxan-2-yl)oxy-4-(3,4,5-trihydroxyoxan-2-yl)oxyoxan-2-yl]oxy-5',7,9,13-tetramethyl-4'-(3,4,5-trihydroxy-6-methyloxan-2-yl)oxyspiro[5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-ene-6,2'-oxane]-3',10,16-triol 74821587 Click to see 1065.20 unknown https://doi.org/10.1021/NP960749G
14-[5-Hydroxy-6-(hydroxymethyl)-3-(3,4,5-trihydroxy-6-methyloxan-2-yl)oxy-4-(3,4,5-trihydroxyoxan-2-yl)oxyoxan-2-yl]oxy-5',7,9,13-tetramethylspiro[5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-ene-6,2'-oxane]-3',4',10,16-tetrol 73109591 Click to see 919.00 unknown https://doi.org/10.1021/NP960749G
https://doi.org/10.1248/CPB.45.558
2-[2-[4,5-Dihydroxy-6-(hydroxymethyl)-2-(16-hydroxy-5',7,9,13-tetramethylspiro[5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-ene-6,2'-oxane]-14-yl)oxyoxan-3-yl]oxy-3,5-dihydroxy-6-methyloxan-4-yl]oxy-6-(hydroxymethyl)oxane-3,4,5-triol 85184972 Click to see 901.00 unknown https://doi.org/10.1248/CPB.43.971
2-[3,5-Dihydroxy-2-[5-hydroxy-6-(hydroxymethyl)-2-(16-hydroxy-5',7,9,13-tetramethylspiro[5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-ene-6,2'-oxane]-14-yl)oxy-4-(3,4,5-trihydroxyoxan-2-yl)oxyoxan-3-yl]oxy-6-methyloxan-4-yl]oxy-6-(hydroxymethyl)oxane-3,4,5-triol 85099238 Click to see 1033.20 unknown https://doi.org/10.1248/CPB.43.971
https://doi.org/10.1246/CL.1994.805
> Lipids and lipid-like molecules / Steroids and steroid derivatives / Stigmastanes and derivatives
(-)-beta-Sitosterol 222284 Click to see 414.70 unknown via CMAUP database
Stigmasterol 5280794 Click to see 412.70 unknown via CMAUP database
> Organic oxygen compounds / Organooxygen compounds / Carbohydrates and carbohydrate conjugates / Glycosyl compounds / O-glycosyl compounds
Sucrose 5988 Click to see 342.30 unknown via CMAUP database
> Organic oxygen compounds / Organooxygen compounds / Carbohydrates and carbohydrate conjugates / Oligosaccharides
GlyTouCan:G72414ZC 44420456 Click to see 504.40 unknown via CMAUP database
Stachyose 439531 Click to see 666.60 unknown via CMAUP database
> Organoheterocyclic compounds / Imidazopyrimidines / Purines and purine derivatives / 6-aminopurines
Adenine 190 Click to see C1=NC2=NC=NC(=C2N1)N 135.13 unknown via CMAUP database
> Phenylpropanoids and polyketides / 2-arylbenzofuran flavonoids
(2S)-2alpha-(3-Methoxy-4-hydroxyphenyl)-5-[(E)-3-(beta-D-glucopyranosyloxy)-1-propenyl]-7-methoxy-2,3-dihydrobenzofuran-3beta-methanol 11027727 Click to see COC1=CC(=CC2=C1OC(C2CO)C3=CC(=C(C=C3)O)OC)C=CCOC4C(C(C(C(O4)CO)O)O)O 520.50 unknown via CMAUP database
> Phenylpropanoids and polyketides / Cinnamic acids and derivatives / Hydroxycinnamic acids and derivatives / Coumaric acids and derivatives
[(2R,3R,4R,5R,6R)-2-[2-(3,4-dihydroxyphenyl)ethoxy]-3,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl] (E)-3-(3,4-dihydroxyphenyl)prop-2-enoate 6915840 Click to see 478.40 unknown via CMAUP database
[(2R,3R,4S,5R,6R)-2-[2-(3,4-dihydroxyphenyl)ethoxy]-3,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl] (E)-3-(3,4-dihydroxyphenyl)prop-2-enoate 5320625 Click to see 478.40 unknown via CMAUP database
[(2R,3R,4S,5R,6R)-6-[2-(3,4-dihydroxyphenyl)ethoxy]-3,5-dihydroxy-4-[(2R,3R,4R,5R,6S)-3,4,5-trihydroxy-6-methyloxan-2-yl]oxyoxan-2-yl]methyl (E)-3-(3,4-dihydroxyphenyl)prop-2-enoate 110062419 Click to see CC1C(C(C(C(O1)OC2C(C(OC(C2O)OCCC3=CC(=C(C=C3)O)O)COC(=O)C=CC4=CC(=C(C=C4)O)O)O)O)O)O 624.60 unknown via CMAUP database
Calceolarioside A 5273566 Click to see C1=CC(=C(C=C1CCOC2C(C(C(C(O2)CO)OC(=O)C=CC3=CC(=C(C=C3)O)O)O)O)O)O 478.40 unknown via CMAUP database
Calceolarioside B 5273567 Click to see 478.40 unknown via CMAUP database
Hellicoside 5281778 Click to see C1=CC(=C(C=C1C=CC(=O)OC2C(OC(C(C2OC3C(C(C(C(O3)CO)O)O)O)O)OCC(C4=CC(=C(C=C4)O)O)O)CO)O)O 656.60 unknown via CMAUP database
Isoacteoside 6476333 Click to see CC1C(C(C(C(O1)OC2C(C(OC(C2O)OCCC3=CC(=C(C=C3)O)O)COC(=O)C=CC4=CC(=C(C=C4)O)O)O)O)O)O 624.60 unknown via CMAUP database
Isomartynoside 91895373 Click to see 652.60 unknown via CMAUP database
Leucosceptoside A 10394343 Click to see 638.60 unknown via CMAUP database
Martynoside 5319292 Click to see 652.60 unknown via CMAUP database
Plantainoside B 9847922 Click to see 478.40 unknown via CMAUP database
Plantamajoside 5281788 Click to see C1=CC(=C(C=C1CCOC2C(C(C(C(O2)CO)OC(=O)C=CC3=CC(=C(C=C3)O)O)OC4C(C(C(C(O4)CO)O)O)O)O)O)O 640.60 unknown via CMAUP database
Plantasioside 44423103 Click to see 476.40 unknown via CMAUP database
Scroside B 9831187 Click to see COC1=C(C=C(C=C1)CCOC2C(C(C(C(O2)COC(=O)C=CC3=CC(=C(C=C3)O)OC)O)OC4C(C(C(C(O4)CO)O)O)O)O)O 668.60 unknown via CMAUP database
Verbascoside 5281800 Click to see CC1C(C(C(C(O1)OC2C(C(OC(C2OC(=O)C=CC3=CC(=C(C=C3)O)O)CO)OCCC4=CC(=C(C=C4)O)O)O)O)O)O 624.60 unknown via CMAUP database
> Phenylpropanoids and polyketides / Flavonoids / Flavonoid glycosides / Flavonoid O-glycosides
Plantagoside 174157 Click to see 466.40 unknown via CMAUP database
> Phenylpropanoids and polyketides / Flavonoids / Flavonoid glycosides / Flavonoid O-glycosides / Flavonoid-7-O-glycosides
Homoplantaginin 5318083 Click to see COC1=C(C=C2C(=C1O)C(=O)C=C(O2)C3=CC=C(C=C3)O)OC4C(C(C(C(O4)CO)O)O)O 462.40 unknown via CMAUP database
Plantaginin 5320623 Click to see C1=CC(=CC=C1C2=CC(=O)C3=C(C(=C(C=C3O2)OC4C(C(C(C(O4)CO)O)O)O)O)O)O 448.40 unknown via CMAUP database

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