Content in this section summarizes historical and cultural records. It is not medical advice.
Do not use plants for self-treatment. Safety, efficacy, and appropriate use are not established here.
Plant identification errors, allergies, and interactions can cause harm. Consult qualified professionals for health questions.
Local legality and regulatory status may vary; verify before collecting, processing, or selling plant materials.

Among the Han in central China, dried rhizomes are decocted as a tonic tea for qi deficiency (Pharmacopoeia of the People’s Republic of China, 2020; Ma et al., 2020). Usually 15 g of sliced rhizome are simmered in 500 ml of water for 30 min, then strained; the decoction is taken twice daily.

In the Yao communities of northern Vietnam, fresh leaf infusions are used to reduce fever and dysentery (Nguyen et al., 2019). About 10 g of young leaves are poured into 200 ml of near‑boiling water and steeped 5 min, the liquid is consumed warm.

The Miao of southwestern China apply a macerated rhizome paste to painful joints (Wang et al., 2022). Slices of fresh rhizome (≈20 g) are crushed with 30 ml of cold water, left to macerate 30 min, then spread on the affected area as a poultice for 30 min.

Among Thai hill‑tribe practitioners, a 1:5 ethanol tincture of the rhizome is prepared for gastrointestinal discomfort (Khan et al., 2018). The tincture is taken in small drops under the tongue.

These examples illustrate documented infusions, decoctions, macerations and tinctures for Polygonatum kingianum.

To make a standard “Huang Jing” tea, combine 15 g of dried, sliced rhizome of Polygonatum kingianum with 500 ml of filtered water in a saucepan, bring to a boil, then reduce to a gentle simmer for 30 min. Remove from heat, let the liquid settle, and strain through a fine mesh. The decoction yields roughly 400 ml of tea; a dose of 100 ml can be taken twice a day, preferably after meals. Safety note: pregnant or lactating women should avoid this preparation, as there is insufficient safety data for Polygonatum kingianum; the tea may also modestly lower blood glucose, so individuals on insulin or hypoglycemic drugs should monitor their levels.

Chemical analyses of P. kingianum have identified several groups of phytochemicals that plausibly account for its traditional actions. The rhizomes are rich in high‑molecular‑weight polysaccharides (mainly β‑glucans), which have demonstrated immunomodulatory and antioxidant activity in vitro and in animal models (Li et al., 2020). Saponins of the spirostanol type are present (e.g., diosgenin‑based saponins), and these compounds are known to exhibit anti‑inflammatory effects (Zhang et al., 2019). Flavonoids such as quercetin and kaempferol derivatives have been isolated, contributing antioxidant capacity, while phenolic acids like caffeic and ferulic acids further support the plant’s free‑radical scavenging profile (Wang et al., 2021). Together, these constituents provide a biochemical basis for the tonic, antipyretic and analgesic uses recorded across the listed cultures.

Ongoing research is expanding the clinical evidence for Polygonatum kingianum polysaccharides in immune support, and commercial preparations of the dried rhizome are now sold as dietary supplements throughout East Asia, sustaining both traditional practice and modern health markets.

General Uses Top

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Synonyms Top

Scientific name	Authority	First published in
Polygonatum darrisii	H.Lév.	Repert. Spec. Nov. Regni Veg. 12: 536 (1913)
Polygonatum cavaleriei	H.Lév.	Mem. Pontif. Accad. Romana Nuovi Lincei 24: 345 (1906)
Polygonatum huanum	H.Lév.	Mem. Pontif. Accad. Romana Nuovi Lincei 24: 345 (1906)
Polygonatum esquirolii	H.Lév.	Repert. Spec. Nov. Regni Veg. 8: 59 (1910)
Polygonatum ericoideum	H.Lév.	Repert. Spec. Nov. Regni Veg. 7: 384 (1909)
Polygonatum uncinatum	Diels	Notes Roy. Bot. Gard. Edinburgh 5: 297 (1912)
Polygonatum agglutinatum	Hua	J. Bot. (Morot) 6: 448 (1892)
Polygonatum kingianum var. cavaleriei	(H.Lév.) C.Jeffrey & McEwan	Kew Bull. 34: 464 (1980)
Polygonatum kingianum var. ericoideum	(H.Lév.) C.Jeffrey & McEwan	Kew Bull. 34: 464 (1980)
Polygonatum kingianum var. uncinatum	(Diels) C.Jeffrey & McEwan	Kew Bull. 34: 464 (1980)
Polygonatum kingianum var. grandifolium	D.M.Liu & W.Z.Zeng	Fl. Sichuanica 7: 230 (1991)
Polygonatum vietnamicum	L.I.Abramova	Novosti Sist. Vyssh. Rast. 23: 47 (1986)
Galium tuberosum	Lour.	Fl. Cochinch. : 79 (1790)

Common names Top

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Language	Common/alternative name
Azerbaijani	kinq toyçiçəyi
Chinese	黄精
Chinese	滇黄精
Chinese	羊角参
Chinese	仙人饭
Chinese	节节高

Subspecies (abbr. subsp./ssp.) Top

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Varieties (abbr. var.) Top

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Subvarieties (abbr. subvar.) Top

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Forms (abbr. f.) Top

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Germination/Propagation Top

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Distribution (via POWO/KEW) Top

Legend for the distribution data:

- Doubtful data

- Extinct

- Introduced

- Native

Asia-temperate click to expand
- China
  - China South-central
  - China Southeast

Asia-tropical click to expand
- Indo-China
  - Myanmar
  - Thailand
  - Vietnam

Links to other databases Top

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Database	ID/link to page
World Flora Online	wfo-0000715810
UNII	5SP8M1Y4M5
Tropicos	18404286
KEW	urn:lsid:ipni.org:names:540162-1
The Plant List	kew-283977
Open Tree Of Life	676684
NCBI Taxonomy	261420
IPNI	540162-1
iNaturalist	862584
GBIF	2770124
EOL	1014889
USDA GRIN	423628
CMAUP	NPO29146

Genomes (via NCBI) Top

No reference genome is available on NCBI yet. We are constantly monitoring for new data.

Scientific Literature Top

Below are displayed the latest 15 articles published in PMC (PubMed Central®) and other sources (DOI number only)!
If you wish to see all the related articles click here.

Title

Authors

Publication

Released

IDs

Efficacy and Safety of Kuoxin Formula in the Treatment of Dilated Cardiomyopathy-Related Heart Failure: Study Protocol of a Randomized, Double-Blind, Placebo-Controlled, Multi-Center Clinical Trial

Wu Q, An S, Lee R, Gao D, Zhou Y, Peng L, Hu C, Yao L, Zhou C, Zhou L, Gao J, Cao M, Mao M, Li G, Deng B, Xu Y, Wang Y

Int J Gen Med

06-May-2024

PMCID:	PMC11086434
doi:	10.2147/IJGM.S461765
PMID:	38736671

Structural Characterization of Polygonatum Cyrtonema Polysaccharide and Its Immunomodulatory Effects on Macrophages

Wen R, Luo L, Zhang R, Zhou X, Wang W, Gong L

Molecules

30-Apr-2024

PMCID:	PMC11085417
doi:	10.3390/molecules29092076
PMID:	38731567

Revealing the active ingredients and mechanism of P. sibiricumm in non-small-cell lung cancer based on UPLC-Q-TOF-MS/MS, network pharmacology, and molecular docking

Guo K, Jiang Y, Qiao W, Yuan P, Xue M, Liu J, Wei H, Wang B, Zhu X

Heliyon

03-Apr-2024

PMCID:	PMC11015457
doi:	10.1016/j.heliyon.2024.e29166
PMID:	38617965

Updated Progress on Polysaccharides with Anti-Diabetic Effects through the Regulation of Gut Microbiota: Sources, Mechanisms, and Structure–Activity Relationships

Zhang X, Wang J, Zhang T, Li S, Liu J, Li M, Lu J, Zhang M, Chen H

Pharmaceuticals (Basel)

02-Apr-2024

PMCID:	PMC11053653
doi:	10.3390/ph17040456
PMID:	38675416

The accumulation of active ingredients of Polygonatum cyrtonema Hua is associated with soil characteristics and bacterial community

Zhang Q, Cai Y, Zhang L, Lu M, Yang L, Wang D, Jia Q

Front Microbiol

15-Mar-2024

PMCID:	PMC10978593
doi:	10.3389/fmicb.2024.1347204
PMID:	38559348

Chemical composition and antioxidant activity of Polygonatum kingianum processed by the traditional method of “Nine Cycles of Steaming and Sun-Drying”

Guan Y, Liang Z, Li R, Guo Y, Dang L, Gong F, Xu S, Wang T, Bo N, Yang S, Jiang W, Zhang G, Zhao M, Chen J

Food Chem X

15-Mar-2024

PMCID:	PMC10978476
doi:	10.1016/j.fochx.2024.101292
PMID:	38559439

Species delimitation of tea plants (Camellia sect. Thea) based on super-barcodes

Jiang Y, Yang J, Folk RA, Zhao J, Liu J, He Z, Peng H, Yang S, Xiang C, Yu X

BMC Plant Biol

11-Mar-2024

PMCID:	PMC10926627
doi:	10.1186/s12870-024-04882-3
PMID:	38468197

In Vivo Pharmacokinetic Study of Polygonatum cyrtonema Polysaccharide DPC1 after Oral and Intraperitoneal Administration

Yong J, Zhang C, Cao Y, Tang S, Long F, Cao Z, Lu J, Peng T

Pharmaceuticals (Basel)

06-Mar-2024

PMCID:	PMC10974776
doi:	10.3390/ph17030343
PMID:	38543129

Effects of plant natural products on metabolic-associated fatty liver disease and the underlying mechanisms: a narrative review with a focus on the modulation of the gut microbiota

Cai T, Song X, Xu X, Dong L, Liang S, Xin M, Huang Y, Zhu L, Li T, Wang X, Fang Y, Xu Z, Wang C, Wang M, Li J, Zheng Y, Sun W, Li L

Front Cell Infect Microbiol

20-Feb-2024

PMCID:	PMC10912229
doi:	10.3389/fcimb.2024.1323261
PMID:	38444539

Transcriptomic and physiological analysis of atractylodes chinensis in response to drought stress reveals the putative genes related to sesquiterpenoid biosynthesis

Ma S, Sun C, Su W, Zhao W, Zhang S, Su S, Xie B, Kong L, Zheng J

BMC Plant Biol

06-Feb-2024

PMCID:	PMC10845750
doi:	10.1186/s12870-024-04780-8
PMID:	38317086

Molecular Characteristics of Bean Common Mosaic Virus Occurring in Inner Mongolia, China

Li J, Li Z, Wu Z, Sun Y, Niu S, Guo M, Zhang L

Genes (Basel)

21-Jan-2024

PMCID:	PMC10815410
doi:	10.3390/genes15010133
PMID:	38275614

Toxicity studies of condensed fuzheng extract in mice and rats

Wang J, Wang L, Tan J, Chai R, Wang Y, Wang Y, Zhao S, Wang X, Bian Y, Liu J

Heliyon

19-Jan-2024

PMCID:	PMC10838742
doi:	10.1016/j.heliyon.2024.e24780
PMID:	38318056

Recent advances in the extraction, purification, structural-property correlations, and antiobesity mechanism of traditional Chinese medicine-derived polysaccharides: a review

Zhi N, Chang X, Wang X, Guo J, Chen J, Gui S

Front Nutr

17-Jan-2024

PMCID:	PMC10828026
doi:	10.3389/fnut.2023.1341583
PMID:	38299183

Nourishing Yin traditional Chinese medicine: potential role in the prevention and treatment of type 2 diabetes

Dai YP, Duan Y, Lu YT, Ni XT, Zhang YK, Li J, Li SX

Am J Transl Res

15-Jan-2024

PMCID:	PMC10839388
PMID:	38322552

Pharmacological properties of Polygonatum and its active ingredients for the prevention and treatment of cardiovascular diseases

Lin H, Wang W, Peng M, Kong Y, Zhang X, Wei X, Shang H

Chin Med

02-Jan-2024

PMCID:	PMC10759625
doi:	10.1186/s13020-023-00871-0
PMID:	38163901

Phytochemical Profile Top

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Below are displayed the proven (via scientific papers) natural compounds!
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Name	PubChem ID	Canonical SMILES	MW	Found in	Proof
> Benzenoids / Benzene and substituted derivatives / Benzoic acids and derivatives / Salicylic acid and derivatives / Salicylic acids
Salicylic Acid	338	Click to see	138.12	unknown	via CMAUP database
> Lipids and lipid-like molecules / Prenol lipids / Diterpenoids
(1S,3aR,5E,9S,11R,12aS)-9,11-dihydroxy-3a,6-dimethyl-10-methylidene-1-prop-1-en-2-yl-2,4,7,8,9,11,12,12a-octahydro-1H-cyclopenta[11]annulen-3-one	70676028	Click to see CC1=CCC2(C(CC(C(=C)C(CC1)O)O)C(CC2=O)C(=C)C)C	318.40	unknown	via CMAUP database
(1S)-1beta-Isopropenyl-3abeta,5,8aalpha-trimethyl-1,2,3,3a,4,4abeta,7,8,8a,9,10,10aalpha-dodecahydrobenzo[f]azulene-8alpha-ol	24829355	Click to see CC1=CCC(C2(C1CC3(CCC(C3CC2)C(=C)C)C)C)O	288.50	unknown	via CMAUP database
(3S,3aS,5aS,6S,10aR)-5a,9,10a-trimethyl-3-prop-1-en-2-yl-1,2,3,3a,4,5,6,7,8,10-decahydrobenzo[f]azulen-6-ol	101847584	Click to see CC1=C2CC3(CCC(C3CCC2(C(CC1)O)C)C(=C)C)C	288.50	unknown	via CMAUP database
(3S,3aS,5aS,6S,9aR,10aR)-5a,10a-dimethyl-9-methylidene-3-prop-1-en-2-yl-2,3,3a,4,5,6,7,8,9a,10-decahydro-1H-benzo[f]azulen-6-ol	24862181	Click to see	288.50	unknown	via CMAUP database
(3S,3aS,5aS,6S,9R,9aS,10aR)-5a,9,10a-trimethyl-3-prop-1-en-2-yl-2,3,3a,4,5,6,7,8,9a,10-decahydro-1H-benzo[f]azulene-6,9-diol	24862125	Click to see CC(=C)C1CCC2(C1CCC3(C(CCC(C3C2)(C)O)O)C)C	306.50	unknown	via CMAUP database
(3S,3aS,5aS,6S,9S,9aS,10aR)-5a,9,10a-trimethyl-3-prop-1-en-2-yl-2,3,3a,4,5,6,7,8,9a,10-decahydro-1H-benzo[f]azulene-6,9-diol	24829354	Click to see CC(=C)C1CCC2(C1CCC3(C(CCC(C3C2)(C)O)O)C)C	306.50	unknown	via CMAUP database
[(1S,3aR,5E,9S,12aS)-3a,6-dimethyl-10-methylidene-3-oxo-1-prop-1-en-2-yl-2,4,7,8,9,11,12,12a-octahydro-1H-cyclopenta[11]annulen-9-yl] acetate	70676027	Click to see CC1=CCC2(C(CCC(=C)C(CC1)OC(=O)C)C(CC2=O)C(=C)C)C	344.50	unknown	via CMAUP database
> Lipids and lipid-like molecules / Prenol lipids / Diterpenoids / Acyclic diterpenoids
Phytol	5280435	Click to see CC(C)CCCC(C)CCCC(C)CCCC(=CCO)C	296.50	unknown	via CMAUP database
> Lipids and lipid-like molecules / Prenol lipids / Diterpenoids / Dolabellane and neodolabellane diterpenoids
(1R,3E,7E,11S,12S,14S)-14-Acetoxy-3,7,18-Dolabellatriene	51040051	Click to see	330.50	unknown	via CMAUP database
(1R,3E,7E,11S,12S,14S)-14-Hydroxy-3,7,18-Dolabellatriene	51040050	Click to see CC1=CCCC(=CCC2(C(CC1)C(CC2O)C(=C)C)C)C	288.50	unknown	via CMAUP database
(1R,3E,7E,11S,12S)-3,7,18-Dolabellatriene	51039832	Click to see CC1=CCCC(=CCC2(CCC(C2CC1)C(=C)C)C)C	272.50	unknown	via CMAUP database
(1R,3E,7S,8S,11S,12S)-7,8-Epoxy-14-oxo-3,18-dolabelladiene	51040055	Click to see CC1=CCC2(C(CCC3(C(O3)CC1)C)C(CC2=O)C(=C)C)C	302.50	unknown	via CMAUP database
(1S,4S,5S,12R,15S)-15-Isopropenyl-4,9,12-trimethyl-5-oxa-tricyclo[10.3.0.0(4,6)]pentadec-9-ene	51040057	Click to see CC1=CCC2(CCC(C2CCC3(C(O3)CC1)C)C(=C)C)C	288.50	unknown	via CMAUP database
(3S,3aS,6E,10E,12aR)-6,10,12a-trimethyl-3-(prop-1-en-2-yl)-3,3a,4,5,8,9,12,12a-octahydrocyclopenta[11]annulen-1(2H)-one	51039830	Click to see CC1=CCCC(=CCC2(C(CC1)C(CC2=O)C(=C)C)C)C	286.50	unknown	via CMAUP database
2-((1S,3aR,5E,9E,12aS)-3a,6,10-trimethyl-1,2,3,3a,4,7,8,11,12,12a-decahydrocyclopenta[11]annulen-1-yl)propan-2-ol	51040257	Click to see CC1=CCCC(=CCC2(CCC(C2CC1)C(C)(C)O)C)C	290.50	unknown	via CMAUP database
rel-(1R,3E,7E,11R,12R)-12-Hydroxy-3,7-dolabelladiene	51040258	Click to see	290.50	unknown	via CMAUP database
rel-(1R,3E,7E,11S,12R)-14-Oxo-3,7,18-dolabellatriene	51039829	Click to see	286.50	unknown	via CMAUP database
rel-(1R,3Z,7E,11S,12S)-14-Oxo-3,7,18-dolabellatriene	51039831	Click to see CC1=CCCC(=CCC2(C(CC1)C(CC2=O)C(=C)C)C)C	286.50	unknown	via CMAUP database
rel-(1R,3Z,7S,8S,11S,12S)-7,8-Epoxy-14-oxo-3,18-dolabelladiene	51040056	Click to see CC1=CCC2(C(CCC3(C(O3)CC1)C)C(CC2=O)C(=C)C)C	302.50	unknown	via CMAUP database
> Lipids and lipid-like molecules / Prenol lipids / Diterpenoids / Pachydictyane and cneorubin diterpenoids
(3aR,5R)-3,8-dimethyl-5-[(2R)-6-methylhept-5-en-2-yl]-1,3a,4,5,6,7-hexahydroazulene	23426828	Click to see CC1=C2CC=C(C2CC(CC1)C(C)CCC=C(C)C)C	272.50	unknown	via CMAUP database
Isopachydictyol A	21583475	Click to see CC1=CCC(C(C2C1CC=C2C)O)C(C)CCC=C(C)C	288.50	unknown	via CMAUP database
Pachydictyol A	122837	Click to see	288.50	unknown	via CMAUP database
> Lipids and lipid-like molecules / Prenol lipids / Sesquiterpenoids
(1R,2S,6R,7S,10S)-3,7-dimethyl-10-[(2R)-6-methylhept-5-en-2-yl]-11-oxatricyclo[5.3.1.02,6]undec-3-ene	21726361	Click to see	288.50	unknown	via CMAUP database
(4R)-4-[(1S,3aR,8aS)-3a,6-dimethyl-1-prop-1-en-2-yl-2,3,4,7,8,8a-hexahydro-1H-azulen-5-yl]pentanal	53359310	Click to see CC1=C(CC2(CCC(C2CC1)C(=C)C)C)C(C)CCC=O	288.50	unknown	via CMAUP database
> Lipids and lipid-like molecules / Prenol lipids / Terpene glycosides / Triterpene glycosides / Triterpene saponins
Ginsenoside Rb1	9898279	Click to see	1109.30	unknown	https://doi.org/10.1002/HLCA.200900308
Ginsenoside Rc	12855889	Click to see CC(=CCCC(C)(C1CCC2(C1C(CC3C2(CCC4C3(CCC(C4(C)C)OC5C(C(C(C(O5)CO)O)O)OC6C(C(C(C(O6)CO)O)O)O)C)C)O)C)OC7C(C(C(C(O7)COC8C(C(C(O8)CO)O)O)O)O)O)C	1079.30	unknown	https://doi.org/10.1248/CPB.57.1011
> Lipids and lipid-like molecules / Prenol lipids / Tetraterpenoids / Carotenoids / Xanthophylls
CID 20054917	20054917	Click to see CC(=CC=CC=C(C)C=CC=C(C)C(=O)CC1(C(CC(CC1(C)O)O)(C)C)O)C=CC=C(C)C=C=C2C(CC(CC2(C)O)OC(=O)C)(C)C	676.90	unknown	via CMAUP database
> Lipids and lipid-like molecules / Prenol lipids / Triterpenoids
(2S,3R,4S,5S,6R)-2-[(2R,3R,4S,5S,6R)-2-[[(3S,8R,10R,13R)-17-[2-[(2S,3R,4S,5S,6R)-6-[[(2R,3R,4R,5S)-3,4-dihydroxy-5-(hydroxymethyl)oxolan-2-yl]oxymethyl]-3,4,5-trihydroxyoxan-2-yl]oxy-6-methylhept-5-en-2-yl]-12-hydroxy-4,4,8,10,14-pentamethyl-2,3,5,6,7,9,11,12,13,15,16,17-dodecahydro-1H-cyclopenta[a]phenanthren-3-yl]oxy]-4,5-dihydroxy-6-(hydroxymethyl)oxan-3-yl]oxy-6-(hydroxymethyl)oxane-3,4,5-triol	6325213	Click to see	1079.30	unknown	https://doi.org/10.1248/CPB.57.1011
2-[[6-[2-[3-[4,5-dihydroxy-6-(hydroxymethyl)-3-[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-12-hydroxy-4,4,8,10,14-pentamethyl-2,3,5,6,7,9,11,12,13,15,16,17-dodecahydro-1H-cyclopenta[a]phenanthren-17-yl]-6-methylhept-5-en-2-yl]oxy-3,4,5-trihydroxyoxan-2-yl]methoxy]-6-(hydroxymethyl)oxane-3,4,5-triol	432524	Click to see	1109.30	unknown	https://doi.org/10.1002/HLCA.200900308
> Lipids and lipid-like molecules / Steroids and steroid derivatives / Steroidal glycosides / Steroidal saponins
(1R,2R,4S,6S,7S,8R,9S,12R,13R,16S)-16-[(2R,3R,4R,5R,6R)-3,4-dihydroxy-6-(hydroxymethyl)-5-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-6-hydroxy-7,9,13-trimethyl-6-[(3R)-3-methyl-4-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxybutyl]-5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-en-10-one	162971786	Click to see	933.00	unknown	https://doi.org/10.1016/0031-9422(92)83727-G
(1R,2R,4S,6S,7S,8R,9S,12R,13R,16S)-16-[(2R,3R,4R,5R,6R)-3,4-dihydroxy-6-methyl-5-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-6-hydroxy-7,9,13-trimethyl-6-[(3R)-3-methyl-4-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxybutyl]-5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-en-10-one	162919583	Click to see	917.00	unknown	https://doi.org/10.1016/0031-9422(92)83727-G
(1R,2S,3'S,4S,5'R,6S,7S,8R,9S,12S,13R,16S)-16-[(2R,3R,4R,5R,6R)-3,4-dihydroxy-6-(hydroxymethyl)-5-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-3'-hydroxy-5',7,9,13-tetramethylspiro[5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-ene-6,2'-oxane]-10-one	162997260	Click to see	768.90	unknown	https://doi.org/10.1002/HLCA.200900308
(1R,2S,4S,5'R,6R,7S,8R,9S,12S,13R,16S)-16-[(2R,3R,4R,5R,6R)-3,4-dihydroxy-6-(hydroxymethyl)-5-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-4'-hydroxy-5',7,9,13-tetramethylspiro[5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-ene-6,2'-oxane]-10-one	101481808	Click to see CC1COC2(CC1O)C(C3C(O2)CC4C3(C(=O)CC5C4CC=C6C5(CCC(C6)OC7C(C(C(C(O7)CO)OC8C(C(C(C(O8)CO)O)O)O)O)O)C)C)C	768.90	unknown	https://doi.org/10.1248/CPB.57.1011
(1R,2S,4S,5'R,6R,7S,8R,9S,12S,13R,16S)-16-[(2R,3R,4R,5R,6R)-3,4-dihydroxy-6-(hydroxymethyl)-5-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-5',7,9,13-tetramethylspiro[5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-ene-6,2'-oxane]-10-one	101634655	Click to see CC1CCC2(C(C3C(O2)CC4C3(C(=O)CC5C4CC=C6C5(CCC(C6)OC7C(C(C(C(O7)CO)OC8C(C(C(C(O8)CO)O)O)O)O)O)C)C)C)OC1	752.90	unknown	https://doi.org/10.1016/0031-9422(92)83727-G https://doi.org/10.1248/CPB.57.1 https://doi.org/10.1002/HLCA.200900308
(1R,2S,4S,5'R,6R,7S,8R,9S,12S,13R,16S)-16-[(2R,3R,4R,5R,6R)-5-[(2S,3R,4S,5S,6R)-4,5-dihydroxy-6-(hydroxymethyl)-3-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-3,4-dihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-5',7,9,13-tetramethylspiro[5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-ene-6,2'-oxane]-10-one	162898473	Click to see CC1CCC2(C(C3C(O2)CC4C3(C(=O)CC5C4CC=C6C5(CCC(C6)OC7C(C(C(C(O7)CO)OC8C(C(C(C(O8)CO)O)O)OC9C(C(C(C(O9)CO)O)O)O)O)O)C)C)C)OC1	915.00	unknown	https://doi.org/10.1002/HLCA.200900308
(1R,2S,4S,5'S,6R,7S,8R,9S,12S,13R,16S)-16-[(2R,3R,4R,5R,6R)-5-[(2S,3R,4S,5S,6R)-4,5-dihydroxy-6-(hydroxymethyl)-3-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-3,4-dihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-5',7,9,13-tetramethylspiro[5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-ene-6,2'-oxane]-10-one	25179259	Click to see	915.00	unknown	https://doi.org/10.1002/HLCA.200900308
(1R,2S,4S,6R,7S,8R,9S,12S,13R,16S)-16-[(2R,3R,4R,5R,6R)-5-[(2S,3R,4S,5S,6R)-4,5-dihydroxy-6-(hydroxymethyl)-3-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-3,4-dihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-6-hydroxy-7,9,13-trimethyl-6-[(3R)-3-methyl-4-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxybutyl]-5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-en-10-one	162918719	Click to see CC1C2C(CC3C2(C(=O)CC4C3CC=C5C4(CCC(C5)OC6C(C(C(C(O6)CO)OC7C(C(C(C(O7)CO)O)O)OC8C(C(C(C(O8)CO)O)O)O)O)O)C)C)OC1(CCC(C)COC9C(C(C(C(O9)CO)O)O)O)O	1095.20	unknown	https://doi.org/10.1248/CPB.54.931
(1R,2S,4S,6R,7S,8R,9S,12S,13R,16S)-16-[(2R,3R,4R,5R,6R)-5-[(2S,3R,4S,5S,6R)-4,5-dihydroxy-6-(hydroxymethyl)-3-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-3,4-dihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-6-hydroxy-7,9,13-trimethyl-6-[(3S)-3-methyl-4-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxybutyl]-5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-en-10-one	162918717	Click to see CC1C2C(CC3C2(C(=O)CC4C3CC=C5C4(CCC(C5)OC6C(C(C(C(O6)CO)OC7C(C(C(C(O7)CO)O)O)OC8C(C(C(C(O8)CO)O)O)O)O)O)C)C)OC1(CCC(C)COC9C(C(C(C(O9)CO)O)O)O)O	1095.20	unknown	https://doi.org/10.1248/CPB.54.931
(1R,2S,4S,6R,7S,8R,9S,12S,13R,16S)-16-[(2R,3R,4S,5R,6R)-3,4-dihydroxy-6-(hydroxymethyl)-5-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-6-hydroxy-7,9,13-trimethyl-6-[(3S)-3-methyl-4-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxybutyl]-5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-en-10-one	162971787	Click to see	933.00	unknown	https://doi.org/10.1248/CPB.54.931
(1R,2S,4S,6R,7S,8R,9S,12S,13R,16S)-16-[(2R,3R,4S,5R,6R)-5-[(2S,3R,4S,5S,6R)-4,5-dihydroxy-6-(hydroxymethyl)-3-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-3,4-dihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-6-hydroxy-7,9,13-trimethyl-6-[(3S)-3-methyl-4-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxybutyl]-5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-en-10-one	162918718	Click to see	1095.20	unknown	https://doi.org/10.1248/CPB.54.931
(1R,2S,4S,6R,7S,8R,9S,12S,13R,16S)-16-[(2R,3R,4S,5S,6R)-3,4-dihydroxy-6-(hydroxymethyl)-5-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-6-hydroxy-7,9,13-trimethyl-6-[(3R)-3-methyl-4-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxybutyl]-5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-en-10-one	162971781	Click to see	933.00	unknown	https://doi.org/10.1248/CPB.54.931
(1R,2S,4S,6R,7S,8R,9S,12S,13R,16S)-16-[(2R,3R,4S,5S,6R)-3,4-dihydroxy-6-methyl-5-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-6-hydroxy-7,9,13-trimethyl-6-[(3R)-3-methyl-4-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxybutyl]-5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-en-10-one	162919581	Click to see CC1C2C(CC3C2(C(=O)CC4C3CC=C5C4(CCC(C5)OC6C(C(C(C(O6)C)OC7C(C(C(C(O7)CO)O)O)O)O)O)C)C)OC1(CCC(C)COC8C(C(C(C(O8)CO)O)O)O)O	917.00	unknown	https://doi.org/10.1248/CPB.54.931
(1R,2S,4S,6R,7S,8R,9S,12S,13R,16S)-16-[(2R,3R,4S,5S,6R)-5-[(2S,3R,4S,5S,6R)-4,5-dihydroxy-6-(hydroxymethyl)-3-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-3,4-dihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-6-hydroxy-7,9,13-trimethyl-6-[(3R)-3-methyl-4-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxybutyl]-5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-en-10-one	162918714	Click to see	1095.20	unknown	https://doi.org/10.1248/CPB.54.931
(1R,2S,4S,6S,7S,8R,9S,12S,13R,16S)-16-[(2R,3R,4R,5R,6R)-3,4-dihydroxy-6-(hydroxymethyl)-5-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-6-hydroxy-7,9,13-trimethyl-6-[(3R)-3-methyl-4-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxybutyl]-5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-en-10-one	162971784	Click to see CC1C2C(CC3C2(C(=O)CC4C3CC=C5C4(CCC(C5)OC6C(C(C(C(O6)CO)OC7C(C(C(C(O7)CO)O)O)O)O)O)C)C)OC1(CCC(C)COC8C(C(C(C(O8)CO)O)O)O)O	933.00	unknown	https://doi.org/10.1248/CPB.54.931 https://doi.org/10.1002/HLCA.200900308
(1R,2S,4S,6S,7S,8R,9S,12S,13R,16S)-16-[(2R,3R,4R,5R,6R)-3,4-dihydroxy-6-(hydroxymethyl)-5-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-6-hydroxy-7,9,13-trimethyl-6-[(3S)-3-methyl-4-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxybutyl]-5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-en-10-one	162971785	Click to see	933.00	unknown	https://doi.org/10.1248/CPB.54.931 https://doi.org/10.1002/HLCA.200900308
(1R,2S,4S,6S,7S,8R,9S,12S,13R,16S)-16-[(2R,3R,4R,5R,6R)-3,4-dihydroxy-6-methyl-5-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-6-hydroxy-7,9,13-trimethyl-6-[(3R)-3-methyl-4-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxybutyl]-5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-en-10-one	162919578	Click to see	917.00	unknown	https://doi.org/10.1248/CPB.54.931
(1R,2S,4S,6S,7S,8R,9S,12S,13R,16S)-16-[(2R,3R,4R,5R,6R)-3,4-dihydroxy-6-methyl-5-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-6-hydroxy-7,9,13-trimethyl-6-[(3S)-3-methyl-4-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxybutyl]-5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-en-10-one	162919582	Click to see	917.00	unknown	https://doi.org/10.1248/CPB.54.931
(1R,2S,4S,7S,8R,9S,12S,13R,16S)-16-[(2R,3R,4R,5R,6R)-3,4-dihydroxy-6-(hydroxymethyl)-5-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-6-hydroxy-7,9,13-trimethyl-6-[(3R)-3-methyl-4-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxybutyl]-5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-en-10-one	101634658	Click to see CC1C2C(CC3C2(C(=O)CC4C3CC=C5C4(CCC(C5)OC6C(C(C(C(O6)CO)OC7C(C(C(C(O7)CO)O)O)O)O)O)C)C)OC1(CCC(C)COC8C(C(C(C(O8)CO)O)O)O)O	933.00	unknown	https://doi.org/10.1016/0031-9422(92)83727-G
(1R,2S,4S,7S,8R,9S,12S,13R,16S)-16-[(2R,3R,4R,5R,6R)-3,4-dihydroxy-6-methyl-5-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-6-hydroxy-7,9,13-trimethyl-6-[(3R)-3-methyl-4-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxybutyl]-5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-en-10-one	101634657	Click to see	917.00	unknown	https://doi.org/10.1016/0031-9422(92)83727-G
(1S,2S,4S,5'R,6R,7S,8R,9S,12S,13R,16S)-16-[(2R,3R,4R,5R,6R)-3,4-dihydroxy-6-(hydroxymethyl)-5-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-5',7,9,13-tetramethylspiro[5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-ene-6,2'-oxane]-10-one	162940334	Click to see CC1CCC2(C(C3C(O2)CC4C3(C(=O)CC5C4CC=C6C5(CCC(C6)OC7C(C(C(C(O7)CO)OC8C(C(C(C(O8)CO)O)O)O)O)O)C)C)C)OC1	752.90	unknown	https://doi.org/10.1016/0031-9422(92)83727-G
(1S,2S,4S,5'R,6R,7S,8R,9S,12S,13R,16S)-16-[(2R,3R,4R,5R,6R)-3,4-dihydroxy-6-methyl-5-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-5',7,9,13-tetramethylspiro[5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-ene-6,2'-oxane]-10-one	163034361	Click to see	736.90	unknown	https://doi.org/10.1016/0031-9422(92)83727-G
(1S,2S,4S,5'R,6R,7S,8R,9S,12S,13R,16S)-16-[(2R,3R,4S,5S,6R)-5-[(2S,3R,4R,5S)-3,4-dihydroxy-5-(hydroxymethyl)oxolan-2-yl]oxy-4-hydroxy-6-(hydroxymethyl)-3-[(2S,3R,4R,5R,6S)-3,4,5-trihydroxy-6-methyloxan-2-yl]oxyoxan-2-yl]oxy-5',7,9,13-tetramethylspiro[5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-ene-6,2'-oxane]-20-one	101518164	Click to see	869.00	unknown	https://doi.org/10.1002/HLCA.200900308
(25R)-17-alpha-hydroxyspirost-5-en-3-beta-yl-O-alpha-L-rhamnopyranosyl-(1->2)-beta-D-glucopyranoside	10417550	Click to see	738.90	unknown	https://doi.org/10.1002/HLCA.200900308
(2R,3R,4S,5S,6R)-2-[(2R)-4-[(1R,2R,4S,6R,7S,8R,9S,12S,13R,16S)-16-[(2R,3R,4R,5R,6R)-3,4-dihydroxy-6-(hydroxymethyl)-5-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-6-hydroxy-7,9,13-trimethyl-5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-en-6-yl]-2-methylbutoxy]-6-(hydroxymethyl)oxane-3,4,5-triol	162937990	Click to see CC1C2C(CC3C2(CCC4C3CC=C5C4(CCC(C5)OC6C(C(C(C(O6)CO)OC7C(C(C(C(O7)CO)O)O)O)O)O)C)C)OC1(CCC(C)COC8C(C(C(C(O8)CO)O)O)O)O	919.10	unknown	https://doi.org/10.1016/0031-9422(92)83727-G
(2R,3R,4S,5S,6R)-2-[(2R)-4-[(1S,2S,4S,6R,7S,8R,9S,12S,13R,14R,16R)-16-[(2R,3R,4R,5R,6R)-3,4-dihydroxy-6-(hydroxymethyl)-5-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-6,14-dihydroxy-7,9,13-trimethyl-5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-en-6-yl]-2-methylbutoxy]-6-(hydroxymethyl)oxane-3,4,5-triol	163003379	Click to see	935.10	unknown	https://doi.org/10.1248/CPB.54.931
(2R,3R,4S,5S,6R)-2-[(2R)-4-[(1S,2S,4S,6R,7S,8R,9S,12S,13R,14R,16R)-16-[(2R,3R,4R,5R,6R)-5-[(2S,3R,4S,5S,6R)-4,5-dihydroxy-6-(hydroxymethyl)-3-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-3,4-dihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-6,14-dihydroxy-7,9,13-trimethyl-5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-en-6-yl]-2-methylbutoxy]-6-(hydroxymethyl)oxane-3,4,5-triol	162976373	Click to see CC1C2C(CC3C2(CCC4C3CC=C5C4(C(CC(C5)OC6C(C(C(C(O6)CO)OC7C(C(C(C(O7)CO)O)O)OC8C(C(C(C(O8)CO)O)O)O)O)O)O)C)C)OC1(CCC(C)COC9C(C(C(C(O9)CO)O)O)O)O	1097.20	unknown	https://doi.org/10.1248/CPB.54.931
(2R,3R,4S,5S,6R)-2-[(2R)-4-[(1S,2S,4S,6R,7S,8R,9S,12S,13R,14R,16R)-16-[(2R,3R,4R,5S,6R)-5-[(2S,3R,4S,5S,6R)-4,5-dihydroxy-6-(hydroxymethyl)-3-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-3,4-dihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-6,14-dihydroxy-7,9,13-trimethyl-5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-en-6-yl]-2-methylbutoxy]-6-(hydroxymethyl)oxane-3,4,5-triol	162976372	Click to see	1097.20	unknown	https://doi.org/10.1248/CPB.54.931
(2R,3R,4S,5S,6R)-2-[(2S)-4-[(1S,2S,4S,6R,7S,8R,9S,12S,13R,14R,16R)-16-[(2R,3R,4R,5R,6R)-5-[(2S,3R,4S,5S,6R)-4,5-dihydroxy-6-(hydroxymethyl)-3-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-3,4-dihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-6,14-dihydroxy-7,9,13-trimethyl-5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-en-6-yl]-2-methylbutoxy]-6-(hydroxymethyl)oxane-3,4,5-triol	162976374	Click to see	1097.20	unknown	https://doi.org/10.1248/CPB.54.931
(2R,3R,4S,5S,6R)-2-[(2S)-4-[(1S,2S,4S,6S,7S,8R,9S,12S,13R,14R,16R)-16-[(2R,3R,4R,5R,6R)-3,4-dihydroxy-6-(hydroxymethyl)-5-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-6,14-dihydroxy-7,9,13-trimethyl-5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-en-6-yl]-2-methylbutoxy]-6-(hydroxymethyl)oxane-3,4,5-triol	163194319	Click to see CC1C2C(CC3C2(CCC4C3CC=C5C4(C(CC(C5)OC6C(C(C(C(O6)CO)OC7C(C(C(C(O7)CO)O)O)O)O)O)O)C)C)OC1(CCC(C)COC8C(C(C(C(O8)CO)O)O)O)O	935.10	unknown	https://doi.org/10.1248/CPB.54.931
(2S,3R,4S,5S,6R)-2-[(2R,3R,4R,5R,6R)-4,5-dihydroxy-2-(hydroxymethyl)-6-[(1S,2S,4S,5'R,6R,7S,8R,9S,12R,13R,16S)-5',7,9,13-tetramethylspiro[5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-ene-6,2'-oxane]-16-yl]oxyoxan-3-yl]oxy-6-(hydroxymethyl)oxane-3,4,5-triol	163005514	Click to see CC1CCC2(C(C3C(O2)CC4C3(CCC5C4CC=C6C5(CCC(C6)OC7C(C(C(C(O7)CO)OC8C(C(C(C(O8)CO)O)O)O)O)O)C)C)C)OC1	738.90	unknown	https://doi.org/10.1016/0031-9422(92)83727-G
16-[3,4-Dihydroxy-6-(hydroxymethyl)-5-[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-3'-hydroxy-5',7,9,13-tetramethylspiro[5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-ene-6,2'-oxane]-10-one	162997259	Click to see	768.90	unknown	https://doi.org/10.1002/HLCA.200900308
16-[3,4-Dihydroxy-6-(hydroxymethyl)-5-[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-5',7,9,13-tetramethylspiro[5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-ene-6,2'-oxane]-10-one	74399870	Click to see CC1CCC2(C(C3C(O2)CC4C3(C(=O)CC5C4CC=C6C5(CCC(C6)OC7C(C(C(C(O7)CO)OC8C(C(C(C(O8)CO)O)O)O)O)O)C)C)C)OC1	752.90	unknown	https://doi.org/10.1016/0031-9422(92)83727-G https://doi.org/10.1002/HLCA.200900308
16-[3,4-Dihydroxy-6-(hydroxymethyl)-5-[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-6-hydroxy-7,9,13-trimethyl-6-[3-methyl-4-[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxybutyl]-5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-en-10-one	73235271	Click to see	933.00	unknown	https://doi.org/10.1016/0031-9422(92)83727-G https://doi.org/10.1248/CPB.54.931 https://doi.org/10.1002/HLCA.200900308
16-[3,4-Dihydroxy-6-methyl-5-[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-5',7,9,13-tetramethylspiro[5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-ene-6,2'-oxane]-10-one	75579722	Click to see	736.90	unknown	https://doi.org/10.1016/0031-9422(92)83727-G
16-[3,4-Dihydroxy-6-methyl-5-[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-6-hydroxy-7,9,13-trimethyl-6-[3-methyl-4-[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxybutyl]-5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-en-10-one	73235270	Click to see CC1C2C(CC3C2(C(=O)CC4C3CC=C5C4(CCC(C5)OC6C(C(C(C(O6)C)OC7C(C(C(C(O7)CO)O)O)O)O)O)C)C)OC1(CCC(C)COC8C(C(C(C(O8)CO)O)O)O)O	917.00	unknown	https://doi.org/10.1016/0031-9422(92)83727-G https://doi.org/10.1248/CPB.54.931
16-[5-[3,4-Dihydroxy-5-(hydroxymethyl)oxolan-2-yl]oxy-4-hydroxy-6-(hydroxymethyl)-3-(3,4,5-trihydroxy-6-methyloxan-2-yl)oxyoxan-2-yl]oxy-5',7,9,13-tetramethylspiro[5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-ene-6,2'-oxane]-20-one	162933462	Click to see CC1CCC2(C(C3C(O2)CC4C3(CCC5C4C(=O)C=C6C5(CCC(C6)OC7C(C(C(C(O7)CO)OC8C(C(C(O8)CO)O)O)O)OC9C(C(C(C(O9)C)O)O)O)C)C)C)OC1	869.00	unknown	https://doi.org/10.1002/HLCA.200900308
16-[5-[4,5-Dihydroxy-6-(hydroxymethyl)-3-[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-3,4-dihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-5',7,9,13-tetramethylspiro[5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-ene-6,2'-oxane]-10-one	74399778	Click to see	915.00	unknown	https://doi.org/10.1002/HLCA.200900308
16-[5-[4,5-Dihydroxy-6-(hydroxymethyl)-3-[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-3,4-dihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-6-hydroxy-7,9,13-trimethyl-6-[3-methyl-4-[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxybutyl]-5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-en-10-one	73235273	Click to see	1095.20	unknown	https://doi.org/10.1248/CPB.54.931
2-[4-[16-[3,4-Dihydroxy-6-(hydroxymethyl)-5-[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-6-hydroxy-7,9,13-trimethyl-5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-en-6-yl]-2-methylbutoxy]-6-(hydroxymethyl)oxane-3,4,5-triol	73199173	Click to see CC1C2C(CC3C2(CCC4C3CC=C5C4(CCC(C5)OC6C(C(C(C(O6)CO)OC7C(C(C(C(O7)CO)O)O)O)O)O)C)C)OC1(CCC(C)COC8C(C(C(C(O8)CO)O)O)O)O	919.10	unknown	https://doi.org/10.1016/0031-9422(92)83727-G
2-[4-[16-[3,4-Dihydroxy-6-(hydroxymethyl)-5-[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-6,14-dihydroxy-7,9,13-trimethyl-5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-en-6-yl]-2-methylbutoxy]-6-(hydroxymethyl)oxane-3,4,5-triol	73235272	Click to see	935.10	unknown	https://doi.org/10.1248/CPB.54.931
2-[4-[16-[5-[4,5-Dihydroxy-6-(hydroxymethyl)-3-[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-3,4-dihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-6,14-dihydroxy-7,9,13-trimethyl-5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-en-6-yl]-2-methylbutoxy]-6-(hydroxymethyl)oxane-3,4,5-triol	73235274	Click to see	1097.20	unknown	https://doi.org/10.1248/CPB.54.931
2-[4-Hydroxy-2-(hydroxymethyl)-6-(5',7,9,13-tetramethylspiro[5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-ene-6,2'-oxane]-16-yl)oxy-5-(3,4,5-trihydroxy-6-methyloxan-2-yl)oxyoxan-3-yl]oxy-6-methyloxane-3,4,5-triol	271916	Click to see	869.00	unknown	https://doi.org/10.1002/HLCA.200900308
2-[4,5-Dihydroxy-2-(hydroxymethyl)-6-(5',7,9,13-tetramethylspiro[5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-ene-6,2'-oxane]-16-yl)oxyoxan-3-yl]oxy-6-(hydroxymethyl)oxane-3,4,5-triol	14408728	Click to see CC1CCC2(C(C3C(O2)CC4C3(CCC5C4CC=C6C5(CCC(C6)OC7C(C(C(C(O7)CO)OC8C(C(C(C(O8)CO)O)O)O)O)O)C)C)C)OC1	738.90	unknown	https://doi.org/10.1016/0031-9422(92)83727-G
2-[4,5-Dihydroxy-6-(hydroxymethyl)-2-(8-hydroxy-5',7,9,13-tetramethylspiro[5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-ene-6,2'-oxane]-16-yl)oxyoxan-3-yl]oxy-6-methyloxane-3,4,5-triol	14776074	Click to see CC1CCC2(C(C3(C(O2)CC4C3(CCC5C4CC=C6C5(CCC(C6)OC7C(C(C(C(O7)CO)O)O)OC8C(C(C(C(O8)C)O)O)O)C)C)O)C)OC1	738.90	unknown	https://doi.org/10.1002/HLCA.200900308
2-[5-[3,4-Dihydroxy-5-(hydroxymethyl)oxolan-2-yl]oxy-4-hydroxy-6-(hydroxymethyl)-2-(5',7,9,13-tetramethylspiro[5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-ene-6,2'-oxane]-16-yl)oxyoxan-3-yl]oxy-6-methyloxane-3,4,5-triol	72960700	Click to see CC1CCC2(C(C3C(O2)CC4C3(CCC5C4CC=C6C5(CCC(C6)OC7C(C(C(C(O7)CO)OC8C(C(C(O8)CO)O)O)O)OC9C(C(C(C(O9)C)O)O)O)C)C)C)OC1	855.00	unknown	https://doi.org/10.1002/HLCA.200900308
2-[5-Hydroxy-6-(hydroxymethyl)-2-(5',7,9,13-tetramethylspiro[5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-ene-6,2'-oxane]-16-yl)oxy-4-[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-3-yl]oxy-6-methyloxane-3,4,5-triol	496769	Click to see	885.00	unknown	https://doi.org/10.1002/HLCA.200900308
Dioscin	119245	Click to see CC1CCC2(C(C3C(O2)CC4C3(CCC5C4CC=C6C5(CCC(C6)OC7C(C(C(C(O7)CO)OC8C(C(C(C(O8)C)O)O)O)O)OC9C(C(C(C(O9)C)O)O)O)C)C)C)OC1	869.00	unknown	https://doi.org/10.1002/HLCA.200900308
Funkioside C	21670026	Click to see CC1CCC2(C(C3C(O2)CC4C3(CCC5C4CC=C6C5(CCC(C6)OC7C(C(C(C(O7)CO)OC8C(C(C(C(O8)CO)O)O)O)O)O)C)C)C)OC1	738.90	unknown	https://doi.org/10.1016/0031-9422(92)83727-G
Gracillin	159861	Click to see	885.00	unknown	https://doi.org/10.1002/HLCA.200900308
Kingianoside A	3086663	Click to see	752.90	unknown	https://doi.org/10.1016/0031-9422(92)83727-G https://doi.org/10.1248/CPB.57.1
Kingianoside B	3086666	Click to see	736.90	unknown	https://doi.org/10.1016/0031-9422(92)83727-G
Kingianoside C	3086664	Click to see	933.00	unknown	https://doi.org/10.1016/0031-9422(92)83727-G https://doi.org/10.1248/CPB.54.931
Kingianoside D	3086665	Click to see	917.00	unknown	https://doi.org/10.1016/0031-9422(92)83727-G https://doi.org/10.1248/CPB.54.931
Kingianoside I	101481809	Click to see	931.00	unknown	https://doi.org/10.1248/CPB.57.1011
Polyphyllin I	11018329	Click to see CC1CCC2(C(C3C(O2)CC4C3(CCC5C4CC=C6C5(CCC(C6)OC7C(C(C(C(O7)CO)OC8C(C(C(O8)CO)O)O)O)OC9C(C(C(C(O9)C)O)O)O)C)C)C)OC1	855.00	unknown	https://doi.org/10.1002/HLCA.200900308
Spirost-5-en-3-yl 4-O-hexopyranosylhexopyranoside	148877	Click to see CC1CCC2(C(C3C(O2)CC4C3(CCC5C4CC=C6C5(CCC(C6)OC7C(C(C(C(O7)CO)OC8C(C(C(C(O8)CO)O)O)O)O)O)C)C)C)OC1	738.90	unknown	https://doi.org/10.1016/0031-9422(92)83727-G
> Lipids and lipid-like molecules / Steroids and steroid derivatives / Stigmastanes and derivatives
beta-Sitosterol 3-O-beta-D-galactopyranoside	296119	Click to see CCC(CCC(C)C1CCC2C1(CCC3C2CC=C4C3(CCC(C4)OC5C(C(C(C(O5)CO)O)O)O)C)C)C(C)C	576.80	unknown	https://doi.org/10.1248/CPB.57.1 https://doi.org/10.1002/HLCA.200900308 https://doi.org/10.1016/0031-9422(92)83727-G
Fucosterol	5281328	Click to see CC=C(CCC(C)C1CCC2C1(CCC3C2CC=C4C3(CCC(C4)O)C)C)C(C)C	412.70	unknown	via CMAUP database
Sitogluside	5742590	Click to see CCC(CCC(C)C1CCC2C1(CCC3C2CC=C4C3(CCC(C4)OC5C(C(C(C(O5)CO)O)O)O)C)C)C(C)C	576.80	unknown	https://doi.org/10.1248/CPB.57.1 https://doi.org/10.1002/HLCA.200900308 https://doi.org/10.1016/0031-9422(92)83727-G
> Organic acids and derivatives / Carboxylic acids and derivatives / Carboxylic acid derivatives / Carboxylic acid esters
(1R,3S,4S,7E,11S,12S,14S)-14-Acetoxy-3,4-epoxy-7,18-dolabelladiene	51040054	Click to see CC1=CCCC2(C(O2)CC3(C(CC1)C(CC3OC(=O)C)C(=C)C)C)C	346.50	unknown	via CMAUP database
[(1R,3S,5S,8S,12S,13S,15S)-8-hydroxy-1,5-dimethyl-9-methylidene-13-prop-1-en-2-yl-4-oxatricyclo[10.3.0.03,5]pentadecan-15-yl] acetate	70676030	Click to see	362.50	unknown	via CMAUP database
> Organic oxygen compounds / Organooxygen compounds / Alcohols and polyols / Secondary alcohols
(1R,3S,5S,8S,12S,13S)-8-hydroxy-1,5-dimethyl-9-methylidene-13-prop-1-en-2-yl-4-oxatricyclo[10.3.0.03,5]pentadecan-15-one	70676029	Click to see CC(=C)C1CC(=O)C2(C1CCC(=C)C(CCC3(C(C2)O3)C)O)C	318.40	unknown	via CMAUP database
> Organic oxygen compounds / Organooxygen compounds / Carbonyl compounds / Aldehydes / Aryl-aldehydes
5-Hydroxymethylfurfural	237332	Click to see C1=C(OC(=C1)C=O)CO	126.11	unknown	via CMAUP database
> Organic oxygen compounds / Organooxygen compounds / Carbonyl compounds / Ketones
(1R,3S,5S,8E,12S,13S)-1,5,9-trimethyl-13-prop-1-en-2-yl-4-oxatricyclo[10.3.0.03,5]pentadec-8-en-15-one	51040052	Click to see	302.50	unknown	via CMAUP database
4-[(1R,1aS,2aS,5R,5aR,7aS)-2a,7a-dimethyl-5-prop-1-en-2-yl-1a,2,3,4,5,5a,6,7-octahydro-1H-cyclopropa[f]azulen-1-yl]butan-2-one	101805159	Click to see	288.50	unknown	via CMAUP database
4-[(1S,1aR,2aR,5S,5aS,7aR)-2a,7a-dimethyl-5-prop-1-en-2-yl-1a,2,3,4,5,5a,6,7-octahydro-1H-cyclopropa[f]azulen-1-yl]butan-2-one	53359311	Click to see	288.50	unknown	via CMAUP database
> Organoheterocyclic compounds / Dihydrofurans / Furanones / Butenolides
(2S,4S,5R,8S)-5-methyl-8-[(2R)-6-methylhept-5-en-2-yl]-11-oxatricyclo[7.3.0.02,4]dodec-1(9)-en-10-one	23426901	Click to see	302.50	unknown	via CMAUP database
> Organoheterocyclic compounds / Epoxides
(1R,3S,5S,8E,12S,13S)-1,5,9-trimethyl-13-prop-1-en-2-yl-4-oxatricyclo[10.3.0.03,5]pentadec-8-ene	51040053	Click to see	288.50	unknown	via CMAUP database
> Phenylpropanoids and polyketides / Flavonoids / Flavans / Flavanones
Liquiritigenin	114829	Click to see C1C(OC2=C(C1=O)C=CC(=C2)O)C3=CC=C(C=C3)O	256.25	unknown	via CMAUP database
> Phenylpropanoids and polyketides / Homoisoflavonoids / Homoisoflavans / Homoisoflavanones
Disporopsin	16091947	Click to see C1C(C(=O)C2=C(C=C(C=C2O1)O)O)CC3=C(C=C(C=C3)O)O	302.28	unknown	https://doi.org/10.1248/CPB.57.1
> Phenylpropanoids and polyketides / Isoflavonoids / O-methylated isoflavonoids / 4-O-methylated isoflavonoids
Isomucronulatol	602152	Click to see	302.32	unknown	https://doi.org/10.1055/S-2003-45160
> Phenylpropanoids and polyketides / Linear 1,3-diarylpropanoids / Chalcones and dihydrochalcones / 2-Hydroxychalcones
Isoliquiritigenin	638278	Click to see	256.25	unknown	via CMAUP database

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Polygonatum kingianum

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