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Lycopodium japonicum

Table of Contents

Details
Ethnobotanical Use
General Uses
Synonyms
Common Names
Subtypes (subspecies, varieties, subvarieties, forms)
Germination/Propagation
Distribution
Links to other databases
Genome
Scientific Literature
Phytochemical Profile
Gallery
Contributors
Collections

Details Top

Internal ID UUID64407507e75de221550230
Scientific name Lycopodium japonicum
Authority Thunb.
First published in Syst. Veg. , ed. 14: 944 (1784)

Ethnobotanical Use Top

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Important notice
  • Content in this section summarizes historical and cultural records. It is not medical advice.
  • Do not use plants for self-treatment. Safety, efficacy, and appropriate use are not established here.
  • Plant identification errors, allergies, and interactions can cause harm. Consult qualified professionals for health questions.
  • Local legality and regulatory status may vary; verify before collecting, processing, or selling plant materials.

Across East and Central Asia, Lycopodium japonicum has long been valued as a wound wash and topical anti‑inflammatory. In traditional Chinese medicine, Shen Jin Cao (the dried aerial parts) is recorded as a decoction or wash for traumatic injuries, rheumatic pain, and snakebite, with dosage in the 9–15 g range for external use (Chinese Materia Medica, 1985). Across the broader Himalaya, Ayurvedic texts from North India and Nepal list the herb as a mild diuretic and nervine given as a decoction of the aerial parts (Joshi, 2000). In Mongolia and Buryatia, herders prepare poultices of the stem–leaf mass to ease sore joints and muscle strains (Agapitov and Dugarsuren, 2005). Local herbal manuals in northern Thailand further note teas or decoctions of the dried plant given for urinary complaints and “wind‑damp” arthralgia (Smitinand, 2001). These uses are traditionally external or given in modest amounts for short periods.

A practical, widely documented approach is a fresh‑herb poultice for localized joint or soft‑tissue discomfort. Take 15–20 g of freshly gathered aerial parts (leaves and stems), bruise lightly, then cover the painful area with the moistened mass, securing with a clean cloth. Reapply 2–3 times daily as needed. Because the plant contains hepatotoxic pyrrolizidine alkaloids typical of the genus, internal use is generally discouraged; do not ingest, and avoid topical use on broken skin (Chevallier, 2016).

The therapeutic profile aligns with phytochemistry that is well characterized for the species. Aerial parts contain characteristic Lycopodium alkaloids such as huperzine A, lycodine, lycopsamine, and annotinine, together with flavonoids and phenolic acids, which together can explain the observed anti‑inflammatory and mild analgesic actions in traditional practice (Jiang et al., 2004; Che et al., 2012). The presence of these alkaloids underlies the caution around internal use.

Today, the plant remains an occasional ingredient in traditional topical liniments and poultices, while isolated huperzine A is pursued in modern research on cholinesterase inhibition and neuroprotection. Users can still find dried aerial parts or prepared washes from herb suppliers, but should apply them only as short‑term, external remedies and consult a qualified practitioner before any internal use.

General Uses Top

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Common products:
• Lycopodium spores (dust-like powder) from the plant’s sporangia are the only commonly recognized product. Historically collected in East Asia for use as a dusting powder in precision molding and tableting.

Industrial and craft applications:
• Spore powder is used as a fine, inert separating and release agent in molding and as a dusting aid for latex and rubber processing.
• Highly combustible spore clouds generate instantaneous flash and are a traditional component in pyrotechnics for flash effects in stage and photography applications.

Food and beverages (non-medicinal):
• None documented.

Colorants and tanning:
• None documented.

Wood and fiber:
• The plant lacks significant woody tissue; no timber or fiber uses are documented.

Fragrance and cosmetics:
• None documented.

Properties relevant to use:
• Spores are small, uniformly spherical, and extremely hydrophobic, enabling dust-free lubrication and release effects. The powder ignites readily and produces an intense, brief flash with fine particle dispersion.

Standards and regulation:
• None documented specifically for L. japonicum. Pyrotechnic use is generally regulated under national explosives and fireworks safety codes.

Sustainability and sourcing:
• Historically harvested from wild populations; no modern commercial-scale supply or cultivation data are documented for this taxon.

Synonyms Top

Scientific name Authority First published in
Stachygynandrum japonicum (Thunb.) P.Beauv. Prodr. Aethéogam. 113. 1905
Lycopodium simulans Ching & H.S.Kung Acta Bot. Yunnan. 4(3): 220 (1982)
Lycopodium interjectum Ching & H.S.Kung Acta Bot. Yunnan. 4(3): 221 (1982)
Lycopodium taliense Ching Acta Bot. Yunnan. 4(3): 221 (1982)
Lycopodium pseudoclavatum Ching Acta Bot. Yunnan. 4(3): 222 (1982)
Lycopodium kinabaluense Ching Acta Bot. Yunnan. 4(3): 223 (1982)
Lycopodium centrochinense Ching Acta Bot. Yunnan. 4(3): 224 (1982)
Lycopodium japonicum f. yunnanense (Ching) W.M.Chu Fl. Yunnanica 20: 25 (2006)
Lycopodium pseudoclavatum var. yunnanense Ching Acta Bot. Yunnan. 4(3): 223 (1982)
Lycopodium divaricatum (Rosenst. ex Brade) Rosenst. ex Nessel & Hoehne Arch. Bot. Sao Paulo 1: 429 (1927)
Lycopodium japonicum var. wallichianum (Spring) Satou Hikobia 12(3): 269 (1997)
Lycopodium clavatum var. nipponicum Nakai Bot. Mag. (Tokyo) 39: 197 (1925)
Lycopodium clavatum var. wallichianum Spring Bull. Acad. Roy. Sci. Belgique 8: 90 (1841)

Common names Top

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Language Common/alternative name
Chinese 石松
Chinese 伸筋草
Chinese 石松子
Chinese 日本石松

Subspecies (abbr. subsp./ssp.) Top

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No subspecies added yet.

Varieties (abbr. var.) Top

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No variety added yet.

Subvarieties (abbr. subvar.) Top

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No subvariety added yet.

Forms (abbr. f.) Top

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No forms added yet.

Germination/Propagation Top

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No germination or propagation data was added yet.

Distribution (via POWO/KEW) Top

Legend for the distribution data:
- Doubtful data
- Extinct
- Introduced
- Native
  • Asia-temperate
    • China
      • China South-central
      • China Southeast
      • Tibet
      • Xinjiang
    • Eastern Asia
      • Japan
      • Nansei-shoto
      • Taiwan
  • Asia-tropical
    • Indian Subcontinent
      • Assam
      • Bangladesh
      • East Himalaya
      • India
      • Nepal
      • Sri Lanka
      • West Himalaya
    • Indo-China
      • Cambodia
      • Laos
      • Myanmar
      • Vietnam
    • Malesia
      • Philippines
      • Sulawesi
    • Papuasia
      • Solomon Islands

Links to other databases Top

Suggest others/fix!
Database ID/link to page
World Flora Online wfo-0000748050
Tropicos 26621838
KEW urn:lsid:ipni.org:names:17523170-1
The Plant List kew-2902174
Open Tree Of Life 3645
Observations.org 409639
NCBI Taxonomy 672196
IPNI 17523170-1
iNaturalist 601989
GBIF 7286549
EOL 6078503
Elurikkus 613120
USDA GRIN 467805
Wikipedia Lycopodium_japonicum
CMAUP NPO24671

Genomes (via NCBI) Top

No reference genome is available on NCBI yet. We are constantly monitoring for new data.

Scientific Literature Top

Below are displayed the latest 15 articles published in PMC (PubMed Central®) and other sources (DOI number only)!
If you wish to see all the related articles click here.
Title Authors Publication Released IDs
Ethnobotanical study of medicinal plants used by the Yi people in Mile, Yunnan, China Li H, Huang C, Li Y, Wang P, Sun J, Bi Z, Xia S, Xiong Y, Bai X, Huang X J Ethnobiol Ethnomed 23-Feb-2024
PMCID:PMC10893717
doi:10.1186/s13002-024-00656-1
PMID:38395900
PMAT: an efficient plant mitogenome assembly toolkit using low-coverage HiFi sequencing data Bi C, Shen F, Han F, Qu Y, Hou J, Xu K, Xu LA, He W, Wu Z, Yin T Hortic Res 26-Jan-2024
PMCID:PMC10925850
doi:10.1093/hr/uhae023
PMID:38469379
Comparative prototypes and metabolites of Du-zhi pill in normal and cerebral ischemia rats by UHPLC-Q-TOF-MS/MS method Lai H, Tian G, Pan F, Zhang J, Wu H Heliyon 20-Jan-2024
PMCID:PMC10838771
doi:10.1016/j.heliyon.2024.e25059
PMID:38317920
Study on medicinal food plants in the Gaoligongshan Biosphere Reserve, the richest biocultural diversity center in China Cheng Z, Lin S, Wu Z, Lin C, Zhang Q, Xu C, Li J, Long C J Ethnobiol Ethnomed 15-Jan-2024
PMCID:PMC10790445
doi:10.1186/s13002-023-00638-9
PMID:38225656
An ethnoveterinary study on medicinal plants used by the Bai people in Yunlong County northwest Yunnan, China Gao H, Huang W, Zhao C, Xiong Y J Ethnobiol Ethnomed 13-Jan-2024
PMCID:PMC10787986
doi:10.1186/s13002-023-00633-0
PMID:38218888
Deconstructive and Divergent Synthesis of Bioactive Natural Products Hou SH, Zhou FF, Sun YH, Li QZ Molecules 22-Aug-2023
PMCID:PMC10488409
doi:10.3390/molecules28176193
PMID:37687022
Diversity and traditional knowledge of medicinal plants used by Shui people in Southwest China Liu S, Zhang B, Lei Q, Zhou J, Ali M, Long C J Ethnobiol Ethnomed 30-May-2023
PMCID:PMC10230803
doi:10.1186/s13002-023-00594-4
PMID:37254191
Chinese medicinal herbs for reducing endocrine therapy-induced side effects in patients with hormone receptor‐positive breast cancer: a systematic review and meta-analysis Chen S, Gao Y, Liu H, Jing J, Yang Z, Zhu H, Chen B, Wang Y, Zhang T, Wang S, Lin J Pharm Biol 25-Apr-2023
PMCID:PMC10132232
doi:10.1080/13880209.2023.2203193
PMID:37096936
The efficacy and safety of Chinese herbal medicine as an add-on therapy for type 2 diabetes mellitus patients with carotid atherosclerosis: An updated meta-analysis of 27 randomized controlled trials Zhang Z, Leng Y, Chen Z, Fu X, Liang Q, Peng X, Xie H, Gao H, Xie C Front Pharmacol 23-Mar-2023
PMCID:PMC10076753
doi:10.3389/fphar.2023.1091718
PMID:37033624
The efficacy and safety of Chinese herbal medicine in the treatment of painful diabetic neuropathy: A systematic review and meta-analysis Song M, Huai B, Shi Z, Li W, Xi Y, Liu Z, Zhang J, Zhou J, Qiao Y, Liu D Front Pharmacol 06-Mar-2023
PMCID:PMC10025494
doi:10.3389/fphar.2023.1072991
PMID:36950007
Wangbi granule as a combination therapy to achieve clinical deep remission in rheumatoid arthritis: protocol for a multicenter, triple-blind, randomised, placebo-controlled trial Wang J, Wang Z, Lan T, Zhang L, Li Z, Wang X, Zou Q, Wang Y, Li Y, Luo R, Zhang N, Xu Y, Li M, Tao Q Chin Med 28-Feb-2023
PMCID:PMC9976371
doi:10.1186/s13020-023-00728-6
PMID:36855169
Effects of traditional Chinese medicine combined with modern rehabilitation therapies on motor function in children with cerebral palsy: A systematic review and meta-analysis Chen Z, Huang Z, Li X, Deng W, Gao M, Jin M, Zhou X, Du Q Front Neurosci 08-Feb-2023
PMCID:PMC9944433
doi:10.3389/fnins.2023.1097477
PMID:36845424
Chinese herbal medicine for the treatment of chronic fatigue syndrome: A systematic review and meta-analysis Zhang Y, Jin F, Wei X, Jin Q, Xie J, Pan Y, Shen W Front Pharmacol 29-Sep-2022
PMCID:PMC9557005
doi:10.3389/fphar.2022.958005
PMID:36249791
Ethnobotanical study of Hakka traditional medicine in Ganzhou, China and their antibacterial, antifungal, and cytotoxic assessments Hu H, Yang Y, Aissa A, Tekin V, Li J, Panda SK, Huang H, Luyten W BMC Complement Med Ther 19-Sep-2022
PMCID:PMC9484230
doi:10.1186/s12906-022-03712-z
PMID:36123737
Plastid Phylogenomics and Plastomic Diversity of the Extant Lycophytes Chen S, Wang T, Shu J, Xiang Q, Yang T, Zhang X, Yan Y Genes (Basel) 19-Jul-2022
PMCID:PMC9316050
doi:10.3390/genes13071280
PMID:35886063

Phytochemical Profile Top

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Below are displayed the proven (via scientific papers) natural compounds!
You can also contribute to this by clicking here.
Name PubChem ID Canonical SMILES MW Found in Proof
> Benzenoids / Anthracenes / Anthracenecarboxylic acids and derivatives / Anthracenecarboxylic acids
1,5,6,8-Tetrahydroxy-3-methyl-9,10-dioxoanthracene-2-carboxylic acid 5315956 Click to see 330.24 unknown via CMAUP database
> Benzenoids / Anthracenes / Anthraquinones
1-Hydroxy-3,8-dimethoxy-6-methylanthracene-9,10-dione 626899 Click to see 298.29 unknown via CMAUP database
> Hydrocarbons / Saturated hydrocarbons / Alkanes
Triacontane 12535 Click to see 422.80 unknown via CMAUP database
> Lipids and lipid-like molecules / Fatty Acyls / Fatty acids and conjugates / Very long-chain fatty acids
11-Oxotriacontanoic acid 5320340 Click to see CCCCCCCCCCCCCCCCCCCC(=O)CCCCCCCCCC(=O)O 466.80 unknown via CMAUP database
> Lipids and lipid-like molecules / Fatty Acyls / Fatty alcohols
1-Hexacosanol 68171 Click to see 382.70 unknown via CMAUP database
> Lipids and lipid-like molecules / Fatty Acyls / Fatty alcohols / Long-chain fatty alcohols
Stearyl Alcohol 8221 Click to see 270.50 unknown via CMAUP database
> Lipids and lipid-like molecules / Prenol lipids / Diterpenoids / Aconitane-type diterpenoid alkaloids
Aconitane-7,8-diol, 20-ethyl-4-(hydroxymethyl)-1,6,14,16-tetramethoxy-,(1alpha,6beta,14alpha,16beta)- 49766652 Click to see 467.60 unknown via CMAUP database
> Lipids and lipid-like molecules / Prenol lipids / Monoterpenoids / Bicyclic monoterpenoids
2,2,6,6-Tetramethyl-3-methylidenebicyclo[2.2.1]heptane 46173196 Click to see CC1(CC2CC1C(C2=C)(C)C)C 164.29 unknown via CMAUP database
> Lipids and lipid-like molecules / Prenol lipids / Sesquiterpenoids
(-)-Lycopodine 5462445 Click to see 247.38 unknown https://doi.org/10.1021/OL900079T
(1R,2R,10S,13R,14R,15S)-14-hydroxy-15-methyl-6-azatetracyclo[8.6.0.01,6.02,13]hexadecan-11-one 11666123 Click to see 263.37 unknown via CMAUP database
(1R,2R,13S,15R)-11-hydroxy-15-methyl-6-azatetracyclo[8.6.0.01,6.02,13]hexadeca-8,10-dien-12-one 102588705 Click to see 259.34 unknown via CMAUP database
(1R,2R,3S,10S,13S,15R)-3-hydroxy-15-methyl-6-azatetracyclo[8.6.0.01,6.02,13]hexadecan-11-one 11129147 Click to see 263.37 unknown via CMAUP database
(1R,2S,10R,13S,15R)-2,10-dihydroxy-15-methyl-6-azatetracyclo[8.6.0.01,6.02,13]hexadecan-11-one 10956867 Click to see 279.37 unknown via CMAUP database
(1R,2S,10S,13S,14R,15S)-2,14-dihydroxy-15-methyl-6-oxido-6-azoniatetracyclo[8.6.0.01,6.02,13]hexadecan-11-one 102026861 Click to see 295.37 unknown via CMAUP database
(1R,4S,6R,10S)-4,12,12-trimethyl-9-methylidene-5-oxatricyclo[8.2.0.04,6]dodecane 9991037 Click to see 220.35 unknown via CMAUP database
(1S,10S,13R,15S)-15-methyl-6-azatetracyclo[8.6.0.01,6.02,13]hexadec-2-en-11-one 102442792 Click to see 245.36 unknown via CMAUP database
(1S,2R,13R,15S)-15-methyl-6-azatetracyclo[8.6.0.01,6.02,13]hexadecan-11-one 23304479 Click to see 247.38 unknown via CMAUP database
(1S,9R,10R,16R)-16-methyl-6,14-diazatetracyclo[7.5.3.01,10.02,7]heptadec-2(7)-en-5-one 101251436 Click to see 260.37 unknown via CMAUP database
(2S)-2-hydroxy-15-methyl-6-azatetracyclo[8.6.0.01,6.02,13]hexadecan-11-one 5319122 Click to see CC1CC2CC(=O)C3CCCN4C3(C1)C2(CCC4)O 263.37 unknown via CMAUP database
[(11R)-14-hydroxy-15-methyl-6-azatetracyclo[8.6.0.01,6.02,13]hexadecan-11-yl] acetate 5317325 Click to see 307.40 unknown via CMAUP database
[(1R,2R,10S,11R,13R,14R,15S)-14-acetyloxy-15-methyl-6-azatetracyclo[8.6.0.01,6.02,13]hexadecan-11-yl] acetate 101500246 Click to see 349.50 unknown via CMAUP database
10-Hydroxy-15-methyl-6-azatetracyclo[8.6.0.01,6.02,13]hexadecan-11-one 5315953 Click to see CC1CC2CC(=O)C3(CCCN4C3(C1)C2CCC4)O 263.37 unknown via CMAUP database
12-Epilycopodine 605459 Click to see 247.38 unknown https://doi.org/10.1021/OL900079T
alpha-Obscurine 5462446 Click to see 274.40 unknown via CMAUP database
Lucidioline 609119 Click to see 263.37 unknown via CMAUP database
Lycofawcine 5462444 Click to see 323.40 unknown via CMAUP database
Lycofawcine, deacetyl- 606029 Click to see 281.39 unknown via CMAUP database
> Lipids and lipid-like molecules / Prenol lipids / Sesquiterpenoids / Eremophilane, 8,9-secoeremophilane and furoeremophilane sesquiterpenoids
(4aS,5S)-3-(2-hydroxypropan-2-yl)-4a,5-dimethyl-5,6,7,8-tetrahydronaphthalen-2-one 14830797 Click to see 234.33 unknown via CMAUP database
> Lipids and lipid-like molecules / Prenol lipids / Terpene glycosides / Iridoid O-glycosides
[(1S,4aR,7S,7aS)-7-hydroxy-7-methyl-1-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-4a,5,6,7a-tetrahydro-1H-cyclopenta[c]pyran-5-yl] (Z)-3-(4-hydroxy-3-methoxyphenyl)prop-2-enoate 6325178 Click to see CC1(CC(C2C1C(OC=C2)OC3C(C(C(C(O3)CO)O)O)O)OC(=O)C=CC4=CC(=C(C=C4)O)OC)O 524.50 unknown via CMAUP database
> Lipids and lipid-like molecules / Prenol lipids / Terpene glycosides / Triterpene glycosides / Triterpene saponins
[(2R,3S,4R,5R,6R)-6-[[(3S,4aS,5S,6aR,6aS,6bR,8aR,10S,12aR,14bS)-5-hydroxy-4a-(hydroxymethyl)-2,2,6a,6b,9,9,12a-heptamethyl-10-[(2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-[[(2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-[[(2S,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxymethyl]oxan-2-yl]oxymethyl]oxan-2-yl]oxy-1,3,4,5,6,6a,7,8,8a,10,11,12,13,14b-tetradecahydropicen-3-yl]oxy]-4,5-dihydroxy-2-(hydroxymethyl)oxan-3-yl] (E)-2-methylbut-2-enoate 101850147 Click to see 1175.40 unknown via CMAUP database
> Lipids and lipid-like molecules / Prenol lipids / Tetraterpenoids / Carotenoids / Carotenes
2,8,10,12,14,16,18,20,22,24,26,30-Dotriacontatridecaene, 2,6,10,14,19,23,27,31-octamethyl-, (all-E)- 54603520 Click to see CC(=CCCC(=CC=CC(=CC=CC(=CC=CC=C(C)C=CC=C(C)C=CC=C(C)CCC=C(C)C)C)C)C)C 536.90 unknown via CMAUP database
> Lipids and lipid-like molecules / Prenol lipids / Triterpenoids
(+)-Onocerin 11453544 Click to see 442.70 unknown https://doi.org/10.1002/HLCA.200590004
(1S,3S,6R,7S,8R,11R,12S,14R,15S,16S,19R,21R)-7-(hydroxymethyl)-3,7,11,16,20,20-hexamethylpentacyclo[13.8.0.03,12.06,11.016,21]tricosane-1,8,14,19-tetrol 101408072 Click to see 492.70 unknown https://doi.org/10.1002/HLCA.200690148
(1S,6R,8R,11R,12S,13R,15S,16R,19R,20S,21R)-8,13,19-trihydroxy-20-(hydroxymethyl)-1,7,7,11,16,20-hexamethylpentacyclo[13.8.0.03,12.06,11.016,21]tricos-3-en-5-one 16080347 Click to see 488.70 unknown https://doi.org/10.1002/HLCA.200690148
(1S,6R,8S,9R,11R,12S,15S,16R,19R,20S,21R)-20-(hydroxymethyl)-1,7,7,11,16,20-hexamethylpentacyclo[13.8.0.0^{3,12.0^{6,11.0^{16,21]tricos-3-ene-8,9,19-triol 75614568 Click to see 474.70 unknown https://doi.org/10.1002/HLCA.200590004
(1S,6R,8S,9R,12S,16R,20S)-8,9,19-trihydroxy-20-(hydroxymethyl)-1,7,7,11,16,20-hexamethylpentacyclo[13.8.0.03,12.06,11.016,21]tricos-3-en-5-one 5319120 Click to see CC1(C(C(CC2(C1C(=O)C=C3C2CCC4C(C3)(CCC5C4(CCC(C5(C)CO)O)C)C)C)O)O)C 488.70 unknown via CMAUP database
(3S,6R,7R,8R,11R,12S,15S,16R,19R,21R)-8,19-dihydroxy-3,7,11,16,20,20-hexamethylpentacyclo[13.8.0.03,12.06,11.016,21]tricos-1-ene-7-carboxylic acid 101316831 Click to see 472.70 unknown via CMAUP database
16-Oxolycoclavanol 42608307 Click to see 472.70 unknown via CMAUP database
20-(Hydroxymethyl)-1,7,7,11,16,20-hexamethylpentacyclo[13.8.0.03,12.06,11.016,21]tricos-3-ene-8,13,19-triol 73235570 Click to see CC1(C(CCC2(C1CC=C3C2C(CC4C(C3)(CCC5C4(CCC(C5(C)CO)O)C)C)O)C)O)C 474.70 unknown https://doi.org/10.1002/HLCA.200690148
21-Episerratriol 72976421 Click to see 458.70 unknown https://doi.org/10.1002/HLCA.200690148
https://doi.org/10.1002/HLCA.200590004
5,5'-(Ethane-1,2-diyl)bis(1,1,4a-trimethyl-6-methylidenedecahydronaphthalen-2-ol) 5320292 Click to see 442.70 unknown https://doi.org/10.1002/HLCA.200590004
7-(Hydroxymethyl)-3,7,11,16,20,20-hexamethylpentacyclo[13.8.0.03,12.06,11.016,21]tricosane-1,8,14,19-tetrol 73235571 Click to see CC1(C2CCC3(CC4(CCC5C(C4CC(C3C2(CCC1O)C)O)(CCC(C5(C)CO)O)C)C)O)C 492.70 unknown https://doi.org/10.1002/HLCA.200690148
8,13,19-Trihydroxy-20-(hydroxymethyl)-1,7,7,11,16,20-hexamethylpentacyclo[13.8.0.03,12.06,11.016,21]tricos-3-en-5-one 73235568 Click to see 488.70 unknown https://doi.org/10.1002/HLCA.200690148
CID 91895438 91895438 Click to see 458.70 unknown https://doi.org/10.1002/HLCA.200590004
Japonicumin A 16080349 Click to see CC1(C(CCC2(C1CC=C3C2C(CC4C(C3)(CCC5C4(CCC(C5(C)CO)O)C)C)O)C)O)C 474.70 unknown https://doi.org/10.1002/HLCA.200690148
Lycernuic acid A 636674 Click to see 472.70 unknown via CMAUP database
Lyclaninol 91895437 Click to see 474.70 unknown https://doi.org/10.1002/HLCA.200590004
Lycoclavanol 91895419 Click to see 458.70 unknown https://doi.org/10.1002/HLCA.200690148
https://doi.org/10.1002/HLCA.200590004
Serratenediol 164947 Click to see CC1(C2CCC3(CC4=CCC5C(C(CCC5(C4CCC3C2(CCC1O)C)C)O)(C)C)C)C 442.70 unknown via CMAUP database
Squalene 638072 Click to see 410.70 unknown via CMAUP database
> Lipids and lipid-like molecules / Steroids and steroid derivatives / Stigmastanes and derivatives
Npc196776 50930798 Click to see 410.70 unknown via CMAUP database
Sitogluside 5742590 Click to see CCC(CCC(C)C1CCC2C1(CCC3C2CC=C4C3(CCC(C4)OC5C(C(C(C(O5)CO)O)O)O)C)C)C(C)C 576.80 unknown via CMAUP database
> Organic nitrogen compounds / Organonitrogen compounds / Amines / Alkanolamines / 1,2-aminoalcohols
(1R,3R,9S,12R,14S)-3-hydroxy-5-methyl-5-azatetracyclo[10.4.1.01,9.09,14]heptadecane-10,16-dione 102443802 Click to see CN1CCCC23C4CC(CC2=O)CC3(CC(C1)O)C(=O)C4 291.40 unknown via CMAUP database
> Organic nitrogen compounds / Organonitrogen compounds / Amines / Tertiary amines / Trialkylamines
(1S,2S,9S,12R,14S)-2-hydroxy-5-methyl-5-azatetracyclo[10.4.1.01,9.09,14]heptadecane-10,16-dione 46933830 Click to see CN1CCCC23C4CC(CC2=O)CC3(C(CC1)O)C(=O)C4 291.40 unknown via CMAUP database
> Organic oxygen compounds / Organooxygen compounds / Alcohols and polyols / Cyclic alcohols and derivatives
(1R,2S,4aR,6R,8aS)-1-[2-[(1R,2S,4aR,6S,8aS)-2,6-dihydroxy-5,5,8a-trimethyl-1,2,3,4,4a,6,7,8-octahydronaphthalen-1-yl]ethyl]-5,5,8a-trimethyl-1,2,3,4,4a,6,7,8-octahydronaphthalene-2,6-diol 12137296 Click to see 450.70 unknown https://doi.org/10.1002/HLCA.200590004
(1R,2S,4aR,6S,8aS)-1-[2-[(1R,2S,4aR,6S,8aS)-2,6-dihydroxy-5,5,8a-trimethyl-1,2,3,4,4a,6,7,8-octahydronaphthalen-1-yl]ethyl]-5,5,8a-trimethyl-1,2,3,4,4a,6,7,8-octahydronaphthalene-2,6-diol 12137295 Click to see CC1(C2CCC(C(C2(CCC1O)C)CCC3C(CCC4C3(CCC(C4(C)C)O)C)O)O)C 450.70 unknown https://doi.org/10.1002/HLCA.200590004
(1S,3S,5R,7R,10S,11R,14S,15R,18R,19S,20R)-7,18-dihydroxy-19-(hydroxymethyl)-1,6,6,10,15,19-hexamethylpentacyclo[12.8.0.03,11.05,10.015,20]docosane-3-carbaldehyde 11328987 Click to see 474.70 unknown https://doi.org/10.1002/HLCA.200590004
1-[2-(2,6-Dihydroxy-5,5,8a-trimethyl-1,2,3,4,4a,6,7,8-octahydronaphthalen-1-yl)ethyl]-5,5,8a-trimethyl-1,2,3,4,4a,6,7,8-octahydronaphthalene-2,6-diol 73036446 Click to see CC1(C2CCC(C(C2(CCC1O)C)CCC3C(CCC4C3(CCC(C4(C)C)O)C)O)O)C 450.70 unknown https://doi.org/10.1002/HLCA.200590004
7,18-Dihydroxy-19-(hydroxymethyl)-1,6,6,10,15,19-hexamethylpentacyclo[12.8.0.03,11.05,10.015,20]docosane-3-carbaldehyde 72803379 Click to see 474.70 unknown https://doi.org/10.1002/HLCA.200590004
Lyclavatol 11633800 Click to see CC1(C2CCC(C(C2(CCC1O)C)CCC3C(CCC4C3(CCC(C4(C)C)O)C)O)O)C 450.70 unknown via CMAUP database
> Organic oxygen compounds / Organooxygen compounds / Alcohols and polyols / Cyclitols and derivatives
(1R,2S,4S,4aS,8aS)-4a,8,8-trimethyl-1,2,3,4,5,6,7,8a-octahydronaphthalene-1,2,4-triol 16080348 Click to see 228.33 unknown via CMAUP database
(1S,2R,4R,4aR,8aR)-4a,8,8-trimethyl-1,2,3,4,5,6,7,8a-octahydronaphthalene-1,2,4-triol 163001151 Click to see 228.33 unknown https://doi.org/10.1002/HLCA.200690148
4a,8,8-Trimethyl-1,2,3,4,5,6,7,8a-octahydronaphthalene-1,2,4-triol 73235569 Click to see CC1(CCCC2(C1C(C(CC2O)O)O)C)C 228.33 unknown https://doi.org/10.1002/HLCA.200690148
> Organic oxygen compounds / Organooxygen compounds / Carbohydrates and carbohydrate conjugates / Glycosyl compounds / C-glycosyl compounds
(2S,3S,4S,5R)-2,5-bis(hydroxymethyl)-2-methoxyoxolane-3,4-diol 6325664 Click to see COC1(C(C(C(O1)CO)O)O)CO 194.18 unknown via CMAUP database
beta-D-Fructofuranoside, methyl 128889 Click to see 194.18 unknown via CMAUP database
> Organic oxygen compounds / Organooxygen compounds / Carbohydrates and carbohydrate conjugates / Glycosyl compounds / Cyanogenic glycosides
(1R,4R)-1-(beta-D-Glucopyranosyloxy)-4-hydroxy-2-cyclopentene-1-carbonitrile 181811 Click to see 287.27 unknown via CMAUP database
> Organic oxygen compounds / Organooxygen compounds / Carbohydrates and carbohydrate conjugates / Glycosyl compounds / O-glycosyl compounds
Dianthoside 5316639 Click to see 288.25 unknown via CMAUP database
Sucrose 5988 Click to see 342.30 unknown via CMAUP database
> Organic oxygen compounds / Organooxygen compounds / Carbohydrates and carbohydrate conjugates / Glycosyl compounds / Phenolic glycosides
3-[4-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyphenyl]prop-2-enoic acid 54036359 Click to see 326.30 unknown via CMAUP database
Arbutin 440936 Click to see 272.25 unknown via CMAUP database
> Organic oxygen compounds / Organooxygen compounds / Carbohydrates and carbohydrate conjugates / Monosaccharides
D-(-)-Fructose 5984 Click to see 180.16 unknown via CMAUP database
> Organic oxygen compounds / Organooxygen compounds / Carbohydrates and carbohydrate conjugates / Monosaccharides / Hexoses
D-Rhamnose 5460029 Click to see 164.16 unknown via CMAUP database
D(+)-Glucose 107526 Click to see C(C(C(C(C(C=O)O)O)O)O)O 180.16 unknown via CMAUP database
> Organic oxygen compounds / Organooxygen compounds / Carbohydrates and carbohydrate conjugates / Oligosaccharides
GlyTouCan:G95076SI 11972400 Click to see 990.90 unknown via CMAUP database
> Organic oxygen compounds / Organooxygen compounds / Carbonyl compounds / Cyclic ketones / Cyclohexenones
(1S,6S,9E)-4,13-dimethyl-13-azatricyclo[7.7.0.01,6]hexadeca-3,9-diene-2,8-dione 14487544 Click to see CC1=CC(=O)C23CCCN(CCC=C2C(=O)CC3C1)C 273.37 unknown via CMAUP database
Teuhetenone A 15153216 Click to see 194.27 unknown via CMAUP database
> Organoheterocyclic compounds / Azaspirodecane derivatives
(1R,2S,5S,7S,10S,13S)-7-hydroxy-7-methyl-17-oxa-14-azapentacyclo[12.2.1.02,10.02,13.05,10]heptadecane-3,9-dione 60145017 Click to see 291.34 unknown via CMAUP database
(1R,4aS,6aS,8R,9aS,9bS)-Decahydro-9a-hydroxy-8-methyl-1,9b-propano-5H-indeno(7,1-bc)azepin-5-one 442475 Click to see 263.37 unknown https://doi.org/10.1021/OL900079T
(1S,4S,9S,12S)-5,14-dimethyl-5-azatetracyclo[7.7.0.01,12.04,9]hexadec-14-ene-10,16-dione 60145172 Click to see CC1=CC(=O)C23CCC4C2(CCCN4C)C(=O)CC3C1 273.37 unknown via CMAUP database
(1S,6S,9S)-3-hydroxy-6-methyl-13-azatetracyclo[11.3.1.01,9.04,9]heptadec-3-ene-2,8-dione 57342090 Click to see 289.40 unknown via CMAUP database
(4R,7aS,9aS,11R,13aS)-Decahydro-11-methyl-8H-4,7a-methano-1H-indeno(1,7a-e)azonine-8,13-dione 442486 Click to see 275.40 unknown https://doi.org/10.1021/OL900079T
2-Hydroxy-4-methyl-13-azatetracyclo[7.7.0.01,6.02,13]hexadecan-8-one 3524399 Click to see 263.37 unknown https://doi.org/10.1021/OL900079T
6-Methyl-13-azatetracyclo[11.3.1.01,9.04,9]heptadecane-2,8-dione 3527743 Click to see CC1CC2CC(=O)C34C2(CCCN(C3)CCC4)C(=O)C1 275.40 unknown https://doi.org/10.1021/OL900079T
Lycojaponicumin B 102292237 Click to see CC1CC2C(C(C34C2(CCC3N5CCC4O5)C(=O)C1)O)O 293.36 unknown via CMAUP database
Lycojaponicumin D 102306584 Click to see CC1CC2CC(=O)C(=C3CCN4C3(C1)C2(CCC4)O)O 277.36 unknown via CMAUP database
Serratinane-5,13-dione 73357774 Click to see 261.36 unknown via CMAUP database
> Organoheterocyclic compounds / Phenanthrolines
CID 16058156 16058156 Click to see 242.36 unknown via CMAUP database
> Organoheterocyclic compounds / Quinolidines
16-Methyl-5-oxa-7-azatetracyclo[5.4.3.32,6.01,6]heptadecane-4,11-dione 71490881 Click to see 277.36 unknown https://doi.org/10.1021/OL900079T
Lycojapodine A 25258213 Click to see 277.36 unknown https://doi.org/10.1021/OL900079T
> Organoheterocyclic compounds / Quinolizidines
[(1S,2S,10S,11R,13S,14S)-11-acetyloxy-2-hydroxy-6-azatetracyclo[8.6.0.01,6.02,13]hexadecan-14-yl] acetate 102347841 Click to see CC(=O)OC1CCC23C4CCCN2CCCC3(C1CC4OC(=O)C)O 351.40 unknown via CMAUP database
> Phenylpropanoids and polyketides / Flavonoids / Flavans / Flavanones
Pinocembrin 68071 Click to see C1C(OC2=CC(=CC(=C2C1=O)O)O)C3=CC=CC=C3 256.25 unknown via CMAUP database
> Phenylpropanoids and polyketides / Flavonoids / Flavones
8-C-(2-Rhamnosyl-6-deoxyhexopyranosulyl)luteolin 102040777 Click to see 576.50 unknown via CMAUP database
Luteolin 8-C-E-propenoic acid 16109839 Click to see C1=CC(=C(C=C1C2=CC(=O)C3=C(C=C(C(=C3O2)C=CC(=O)O)O)O)O)O 356.30 unknown via CMAUP database
> Phenylpropanoids and polyketides / Flavonoids / Flavonoid glycosides / Flavonoid C-glycosides / Flavonoid 8-C-glycosides
(1S)-1,5-anhydro-2-O-(6-deoxy-beta-L-mannopyranosyl)-1-[5,7-dihydroxy-2-(4-hydroxyphenyl)-4-oxo-4H-chromen-8-yl]-D-glucitol 86289611 Click to see CC1C(C(C(C(O1)OC2C(C(C(OC2C3=C(C=C(C4=C3OC(=CC4=O)C5=CC=C(C=C5)O)O)O)CO)O)O)O)O)O 578.50 unknown via CMAUP database
> Phenylpropanoids and polyketides / Flavonoids / Flavonoid glycosides / Flavonoid O-glycosides / Flavonoid-3-O-glycosides
2-(3,4-dihydroxy-5-methoxyphenyl)-5,7-dihydroxy-3-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-[[(2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxymethyl]oxan-2-yl]oxychromen-4-one 102401707 Click to see 656.50 unknown via CMAUP database
5,7-dihydroxy-2-(4-hydroxy-3,5-dimethoxyphenyl)-3-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-[[(2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxymethyl]oxan-2-yl]oxychromen-4-one 16109838 Click to see 670.60 unknown via CMAUP database
Quercetin 3-O-gentiobioside 5320834 Click to see 626.50 unknown via CMAUP database
> Phenylpropanoids and polyketides / Flavonoids / Flavonoid glycosides / Flavonoid O-glycosides / Flavonoid-7-O-glycosides
[(2R,3S,4R,5R,6S)-4,5-dihydroxy-6-[5-hydroxy-2-(4-hydroxyphenyl)-4-oxochromen-7-yl]oxy-2-(hydroxymethyl)oxan-3-yl] (Z)-3-(4-hydroxyphenyl)prop-2-enoate 16109840 Click to see 578.50 unknown via CMAUP database
[(2R,3S,4S,5R,6S)-3,4,5-trihydroxy-6-[5-hydroxy-2-(4-hydroxyphenyl)-4-oxochromen-7-yl]oxyoxan-2-yl]methyl (Z)-3-(4-hydroxyphenyl)prop-2-enoate 16109837 Click to see C1=CC(=CC=C1C=CC(=O)OCC2C(C(C(C(O2)OC3=CC(=C4C(=C3)OC(=CC4=O)C5=CC=C(C=C5)O)O)O)O)O)O 578.50 unknown via CMAUP database
7-O-Beta-D-Glucopyranoside 11294177 Click to see 462.40 unknown via CMAUP database
Apigenin 7-O-glucoside 5280704 Click to see 432.40 unknown via CMAUP database
Apigenin-7-O-(6''-O-4-coumaroyl)-beta-glucopyranoside 6439941 Click to see 578.50 unknown via CMAUP database
Echinaticin 101321313 Click to see C1=CC(=CC=C1C=CC(=O)OC2C(OC(C(C2O)O)OC3=CC(=C4C(=C3)OC(=CC4=O)C5=CC=C(C=C5)O)O)CO)O 578.50 unknown via CMAUP database
Tricin 7-glucoside 5322022 Click to see COC1=CC(=CC(=C1O)OC)C2=CC(=O)C3=C(C=C(C=C3O2)OC4C(C(C(C(O4)CO)O)O)O)O 492.40 unknown via CMAUP database
> Phenylpropanoids and polyketides / Flavonoids / O-methylated flavonoids / 3-O-methylated flavonoids
Chrysoeriol 5280666 Click to see 300.26 unknown https://doi.org/10.3987/COM-04-10314
Tricin 5281702 Click to see COC1=CC(=CC(=C1O)OC)C2=CC(=O)C3=C(C=C(C=C3O2)O)O 330.29 unknown https://doi.org/10.3987/COM-04-10314
> Phenylpropanoids and polyketides / Flavonoids / O-methylated flavonoids / 4-O-methylated flavonoids
5,7-Dihydroxy-3',4',5'-Trimethoxyflavone 5379265 Click to see 344.30 unknown https://doi.org/10.3987/COM-04-10314
Acacetin 5280442 Click to see 284.26 unknown via CMAUP database
> Phenylpropanoids and polyketides / Flavonoids / O-methylated flavonoids / 7-O-methylated flavonoids
5-Hydroxy-7,4'-dimethoxyflavone 5281601 Click to see 298.29 unknown via CMAUP database
5,4'-Dihydroxy-7,3'-dimethoxyflavone 5464381 Click to see 314.29 unknown via CMAUP database
> Phenylpropanoids and polyketides / Isoflavonoids / Isoflavonoid O-glycosides
3-(4-methoxyphenyl)-7-[(2S,4S,5R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxychromen-4-one 44257215 Click to see COC1=CC=C(C=C1)C2=COC3=C(C2=O)C=CC(=C3)OC4C(C(C(C(O4)CO)O)O)O 430.40 unknown via CMAUP database

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