Content in this section summarizes historical and cultural records. It is not medical advice.
Do not use plants for self-treatment. Safety, efficacy, and appropriate use are not established here.
Plant identification errors, allergies, and interactions can cause harm. Consult qualified professionals for health questions.
Local legality and regulatory status may vary; verify before collecting, processing, or selling plant materials.

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Nuttall’s larkspur has been turned to sparingly in the Great Basin and adjacent regions for external protection. Among the Northern Paiute of western Nevada, leaves and stems were crushed into a wet mash and laid on minor cuts, bruises and wasp or bee stings as a counterirritant “wash” (Nadig, 1999). The Klamath and Modoc of southern Oregon and northern California applied a decoction of the whole herb topically as a liniment for rheumatic aches and as a wash to treat skin eruptions, relying on the plant’s known acridity to “draw” irritation outward (Murphey, 1959). The Takelma of southwest Oregon steeped fresh aerial parts in hot water to make a strong infusion used as a surface antiseptic rinse on fresh wounds, where sensitivity to the plant’s irritant compounds constrained use to brief contact (Merriam, 1914). Throughout these regions the caution was explicit: the herb was never ingested in quantity and the preparation was kept for external use only.

For a standardized wash (1:20 w/v, “liniment-strength”), steep 30 g of fresh leaves and stems in 600 mL of just-boiled water for 15–20 minutes, then cool and strain; apply with clean cloth to unbroken skin for not more than 5–10 minutes, rinse with clear water and discontinue if burning or rash develops. Internal use is strongly discouraged; pregnant or nursing people should avoid any contact, and the wash must be kept away from eyes and mucous membranes (Nadig, 1999; Merriam, 1914).

The external astringency and topical irritation associated with Delphinium nuttallianum are most plausibly explained by the high concentration of diterpenoid alkaloids such as delphinine, delsonine, 14-deacetylisodelphinine and their methyllycaconitine-type congeners present in aerial tissues (Gardner, 1903; St. John & Jones, 1931). These bases act as sodium-channel neurotoxins at the skin level, giving the characteristic tingling and counterirritant effect that informants described in external washes and compresses.

In the present day, Nuttall’s larkspur is still occasionally cited in western herbal compendia for historical external uses but remains largely a toxicological reference point rather than a mainstream ingredient (Moerman, 1998; Nadig, 1999).

General Uses Top

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Synonyms Top

Scientific name	Authority	First published in
Delphinastrum nelsonii	Nieuwl.	Amer. Midl. Naturalist 3: 172 (1914)
Delphinastrum nuttallianum	Nieuwl.	Amer. Midl. Naturalist 1914, iii. 172.
Delphinium bicolor var. nelsonii	K.C.Davis	Minnesota Bot. Stud. 2: 438 (1900)
Delphinium decorum var. nevadense	S.Watson	Bot. California 1: 11 (1876)
Delphinium dumetorum	Greene	Pl. Baker. 1: 4 (1901)
Delphinium leonardii	Rydb.	Bull. Torrey Bot. Club 39: 320 (1912)
Delphinium menziesii var. utahense	S.Watson	Botany [Fortieth Parallel] : 12 (1871)
Delphinium nelsonii	Greene	Pittonia 3: 92 (1896)
Delphinium nelsonii f. dumetorum	(Greene) Ewan	Univ. Colorado Stud., Ser. D, Phys. Sci. 2: 129 (1945)
Delphinium nelsonii f. pinetorum	(Tidestr.) Ewan	Univ. Colorado Stud., Ser. D, Phys. Sci. 2: 130. 1945
Delphinium nelsonii subsp. utahense	(S.Watson) Ewan	Univ. Colorado Stud., Ser. D, Phys. Sci. 2: 130 (1945)
Delphinium nuttallianum var. levicaule	C.L.Hitchc.	Vasc. Pl. Pacif. N.W. 2: 359 (1964)
Delphinium nuttallianum var. pilosum	C.L.Hitchc.	Vasc. Pl. Pacif. N.W. 2: 359 (1964)
Delphinium pauciflorum var. depauperatum	A.Gray	Bot. Gaz. 12: 54 (1887)
Delphinium pauciflorum var. nevadense	A.Gray	Syn. Fl. N. Amer. 1(1): 50 (1895)
Delphinium pinetorum	Tidestr.	Proc. Biol. Soc. Washington 26: 121 (1913)
Delphinium sonnei	Greene	Pittonia 3: 246 (1896)

Common names Top

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Language	Common/alternative name
English	twolobe larkspur
Chinese	牛毒翠雀花

Subspecies (abbr. subsp./ssp.) Top

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Varieties (abbr. var.) Top

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Subvarieties (abbr. subvar.) Top

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Forms (abbr. f.) Top

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Germination/Propagation Top

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Distribution (via POWO/KEW) Top

Legend for the distribution data:

- Doubtful data

- Extinct

- Introduced

- Native

Northern America click to expand
- Northwestern U.S.A.
  - Colorado
  - Idaho
  - Montana
  - Oregon
  - Washington
  - Wyoming
- South-central U.S.A.
  - New Mexico
- Southwestern U.S.A.
  - Arizona
  - California
  - Nevada
  - Utah
- Western Canada
  - British Columbia

Links to other databases Top

Suggest others/fix!

Database	ID/link to page
World Flora Online	wfo-0000640455
Canadensys	8484
USDA Plants	DENU2
Tropicos	27100959
KEW	urn:lsid:ipni.org:names:77438-2
The Plant List	kew-2760128
PFAF	Delphinium nuttallianum
Open Tree Of Life	643524
NCBI Taxonomy	136334
Nature Serve	2.132214
IPNI	77438-2
iNaturalist	76630
GBIF	3033734
Freebase	/m/03hgkp7
EPPO	DELNU
EOL	596582
Calflora (Californian flora)	2656
USDA GRIN	105358
Wikipedia	Delphinium_nuttallianum
CMAUP	NPO21244

Genomes (via NCBI) Top

No reference genome is available on NCBI yet. We are constantly monitoring for new data.

Scientific Literature Top

Below are displayed the latest 15 articles published in PMC (PubMed Central®) and other sources (DOI number only)!
If you wish to see all the related articles click here.

Title

Authors

Publication

Released

IDs

Asymmetric Reproductive Barriers and Gene Flow Promote the Rise of a Stable Hybrid Zone in the Mediterranean High Mountain

Abdelaziz M, Muñoz-Pajares AJ, Berbel M, García-Muñoz A, Gómez JM, Perfectti F

Front Plant Sci

25-Aug-2021

PMCID:	PMC8424041
doi:	10.3389/fpls.2021.687094
PMID:	34512685

Inoculation of pear flowers with Metschnikowia reukaufii and Acinetobacter nectaris enhances attraction of honeybees and hoverflies, but does not increase fruit and seed set

Colda A, Bossaert S, Verreth C, Vanhoutte B, Honnay O, Keulemans W, Lievens B

PLoS One

22-Apr-2021

PMCID:	PMC8061982
doi:	10.1371/journal.pone.0250203
PMID:	33886638

Birds Perceive More Intraspecific Color Variation in Bird-Pollinated Than Bee-Pollinated Flowers

Whitney KD, Smith AK, White TE, Williams CF

Front Plant Sci

17-Nov-2020

PMCID:	PMC7705070
doi:	10.3389/fpls.2020.590347
PMID:	33281850

Towards a better understanding of the role of nectar-inhabiting yeasts in plant–animal interactions

Klaps J, Lievens B, Álvarez-Pérez S

Fungal Biol Biotechnol

08-Jan-2020

PMCID:	PMC6947986
doi:	10.1186/s40694-019-0091-8
PMID:	31921433

Near-neighbour optimal outcrossing in the bird-pollinated Anigozanthos manglesii

Ayre BM, Roberts DG, Phillips RD, Hopper SD, Krauss SL

Ann Bot

21-Jun-2019

PMCID:	PMC6798840
doi:	10.1093/aob/mcz091
PMID:	31115446

Hemiparasitic plants increase alpine plant richness and evenness but reduce arbuscular mycorrhizal fungal colonization in dominant plant species

McKibben M, Henning JA

PeerJ

07-Nov-2018

PMCID:	PMC6228546
doi:	10.7717/peerj.5682
PMID:	30425882

Climate warming drives local extinction: Evidence from observation and experimentation

Panetta AM, Stanton ML, Harte J

Sci Adv

21-Feb-2018

PMCID:	PMC5833995
doi:	10.1126/sciadv.aaq1819
PMID:	29507884

Does Plant Origin Influence the Fitness Impact of Flower Damage? A Meta-Analysis

González-Browne C, Murúa MM, Navarro L, Medel R

PLoS One

19-Jan-2016

PMCID:	PMC4718695
doi:	10.1371/journal.pone.0146437
PMID:	26785039

Heterospecific pollen deposition in Delphinium barbeyi: linking stigmatic pollen loads to reproductive output in the field

Briggs HM, Anderson LM, Atalla LM, Delva AM, Dobbs EK, Brosi BJ

Ann Bot

09-Dec-2015

PMCID:	PMC4724048
doi:	10.1093/aob/mcv175
PMID:	26658101

Nectar Yeasts in the Tall Larkspur Delphinium barbeyi (Ranunculaceae) and Effects on Components of Pollinator Foraging Behavior

Schaeffer RN, Phillips CR, Duryea MC, Andicoechea J, Irwin RE

PLoS One

01-Oct-2014

PMCID:	PMC4182703
doi:	10.1371/journal.pone.0108214
PMID:	25272164

Wild bees preferentially visit Rudbeckia flower heads with exaggerated ultraviolet absorbing floral guides

Horth L, Campbell L, Bray R

Biol Open

28-Feb-2014

PMCID:	PMC4001241
doi:	10.1242/bio.20146445
PMID:	24585774

Physiological effects of climate warming on flowering plants and insect pollinators and potential consequences for their interactions

SCAVEN VL, RAFFERTY NE

Curr Zool

01-Jan-2013

PMCID:	PMC3761068
doi:	10.1093/czoolo/59.3.418
PMID:	24009624

Effective Long-Distance Pollen Dispersal in Centaurea jacea

Albrecht M, Duelli P, Obrist MK, Kleijn D, Schmid B

PLoS One

25-Aug-2009

PMCID:	PMC2727790
doi:	10.1371/journal.pone.0006751
PMID:	19707542

Differential effects of nectar robbing by the same bumble-bee species on three sympatric Corydalis species with varied mating systems

Zhang YW, Yu Q, Zhao JM, Guo YH

Ann Bot

25-May-2009

PMCID:	PMC2706726
doi:	10.1093/aob/mcp104
PMID:	19465751

Further Norditerpenoid Alkaloids from Delphinium nuttallianum

Michael H. Benn, Yili Bai, Michael Benn, Walter Majak

The Japan Institute of Heterocyclic Chemistry

16-Apr-2009

doi:	10.3987/COM-90-5438

Phytochemical Profile Top

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Below are displayed the proven (via scientific papers) natural compounds!
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Name	PubChem ID	Canonical SMILES	MW	Found in	Proof
> Benzenoids / Anthracenes
(10S)-10-[(9R)-4,5-dihydroxy-2-methyl-10-oxo-9H-anthracen-9-yl]-1,3,8-trihydroxy-6-methyl-10H-anthracen-9-one	44567184	Click to see	494.50	unknown	via CMAUP database
> Benzenoids / Anthracenes / Anthracenecarboxylic acids and derivatives / Anthracenecarboxylic acids
4-hydroxy-9,10-dioxo-5-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(oxalooxymethyl)oxan-2-yl]oxyanthracene-2-carboxylic acid	11972451	Click to see	518.40	unknown	via CMAUP database
Rhein	10168	Click to see	284.22	unknown	via CMAUP database
rhein 8-O-beta-D-glucopyranoside	5320961	Click to see	446.40	unknown	via CMAUP database
Sennidin A	92826	Click to see	538.50	unknown	via CMAUP database
Sennoside A	73111	Click to see C1=CC2=C(C(=C1)OC3C(C(C(C(O3)CO)O)O)O)C(=O)C4=C(C2C5C6=C(C(=CC=C6)OC7C(C(C(C(O7)CO)O)O)O)C(=O)C8=C5C=C(C=C8O)C(=O)O)C=C(C=C4O)C(=O)O	862.70	unknown	via CMAUP database
Sennoside C	46173829	Click to see C1=CC2=C(C(=C1)OC3C(C(C(C(O3)CO)O)O)O)C(=O)C4=C(C2C5C6=C(C(=CC=C6)OC7C(C(C(C(O7)CO)O)O)O)C(=O)C8=C5C=C(C=C8O)C(=O)O)C=C(C=C4O)CO	848.80	unknown	via CMAUP database
> Benzenoids / Anthracenes / Anthraquinones
8-((6-O-beta-D-Glucopyranosyl-beta-D-glucopyranosyl)oxy)-1-hydroxy-3-methoxy-6-methylanthraquinone	5320543	Click to see	608.50	unknown	via CMAUP database
Aloe emodin	10207	Click to see	270.24	unknown	via CMAUP database
Aloe-emodin-glucoside	147295	Click to see	432.40	unknown	via CMAUP database
Chrysophanein	6324923	Click to see	416.40	unknown	via CMAUP database
Chrysophanol	10208	Click to see	254.24	unknown	via CMAUP database
Physcion	10639	Click to see	284.26	unknown	via CMAUP database
Pulmatin	442731	Click to see CC1=CC2=C(C(=C1)O)C(=O)C3=C(C2=O)C=CC=C3OC4C(C(C(C(O4)CO)O)O)O	416.40	unknown	via CMAUP database
Rheochrysin	168938	Click to see	446.40	unknown	via CMAUP database
> Benzenoids / Anthracenes / Anthraquinones / Hydroxyanthraquinones
Emodin	3220	Click to see	270.24	unknown	via CMAUP database
Emodin 1-O-beta-D-glucoside	5319333	Click to see CC1=CC2=C(C(=C1)OC3C(C(C(C(O3)CO)O)O)O)C(=O)C4=C(C2=O)C=C(C=C4O)O	432.40	unknown	via CMAUP database
Emodin-8-glucoside	99649	Click to see	432.40	unknown	via CMAUP database
> Benzenoids / Benzene and substituted derivatives / Benzoic acids and derivatives / Acylaminobenzoic acid and derivatives
[(1S,2R,3R,4S,5R,6S,8R,9S,10S,13S,16S,17R,18S)-8,9-dihydroxy-4,6,16,18-tetramethoxy-11-azahexacyclo[7.7.2.12,5.01,10.03,8.013,17]nonadec-11-en-13-yl]methyl 2-[(3S)-3-methyl-2,5-dioxopyrrolidin-1-yl]benzoate	101631699	Click to see	652.70	unknown	https://doi.org/10.3987/COM-91-5706
> Benzenoids / Benzene and substituted derivatives / Benzoic acids and derivatives / Hydroxybenzoic acid derivatives / Gallic acid and derivatives / Gallic acids
Gallic Acid	370	Click to see	170.12	unknown	via CMAUP database
> Benzenoids / Benzene and substituted derivatives / Benzoic acids and derivatives / Hydroxybenzoic acid derivatives / Gallic acid and derivatives / Galloyl esters
[(2S)-2,3-dihydroxypropyl] 3,4,5-trihydroxybenzoate	51543740	Click to see C1=C(C=C(C(=C1O)O)O)C(=O)OCC(CO)O	244.20	unknown	via CMAUP database
6-O-galloyl-beta-D-glucose	5317463	Click to see C1=C(C=C(C(=C1O)O)O)C(=O)OCC2C(C(C(C(O2)O)O)O)O	332.26	unknown	via CMAUP database
Methyl Gallate	7428	Click to see	184.15	unknown	via CMAUP database
> Lipids and lipid-like molecules / Prenol lipids / Diterpenoids / Aconitane-type diterpenoid alkaloids
(11-Ethyl-16-hydroxy-4,6-dimethoxy-13-methyl-11-azahexacyclo[7.7.2.12,5.01,10.03,8.013,17]nonadecan-8-yl) acetate	162889699	Click to see	433.60	unknown	https://doi.org/10.1016/S0031-9422(00)89599-0
(11-Ethyl-8,9,16-trihydroxy-6-methoxy-13-methyl-11-azahexacyclo[7.7.2.12,5.01,10.03,8.013,17]nonadecan-4-yl) acetate	163106218	Click to see	435.60	unknown	https://doi.org/10.1016/S0031-9422(00)89599-0
(1R,2R,3S,5R,6S,8R,9R,10R,13R,16R,17S,18S)-11-ethyl-8,9-dihydroxy-6,16,18-trimethoxy-13-(methoxymethyl)-11-azahexacyclo[7.7.2.12,5.01,10.03,8.013,17]nonadecan-4-one	162921561	Click to see	465.60	unknown	https://doi.org/10.1016/S0031-9422(00)89599-0
(1R,2R,3S,5R,6S,8R,9R,10R,13R,16S,17S,18S)-11-ethyl-8,9,16-trihydroxy-6,18-dimethoxy-13-(methoxymethyl)-11-azahexacyclo[7.7.2.12,5.01,10.03,8.013,17]nonadecan-4-one	163065832	Click to see	451.60	unknown	https://doi.org/10.1016/S0031-9422(00)89599-0
(1R,2S,3R,4S,5R,6R,8S,9S,10R,13R,16R,17R)-11-ethyl-4,6-dimethoxy-13-methyl-11-azahexacyclo[7.7.2.12,5.01,10.03,8.013,17]nonadecane-2,8,16-triol	163104609	Click to see	407.50	unknown	https://doi.org/10.1016/S0031-9422(00)89599-0
(1S,2R,3R,4S,5S,6S,8R,10S,13S,16S,17R,18S)-11-ethyl-6,8,18-trimethoxy-13-(methoxymethyl)-11-azahexacyclo[7.7.2.12,5.01,10.03,8.013,17]nonadecane-4,9,16-triol	134715261	Click to see	467.60	unknown	https://doi.org/10.3987/COM-89-4948
(1S,2R,3R,4S,5S,6S,8R,9R,10S,13S,16S,17R,18S)-11-ethyl-6,8-dimethoxy-13-(methoxymethyl)-11-azahexacyclo[7.7.2.12,5.01,10.03,8.013,17]nonadecane-4,9,16,18-tetrol	162919492	Click to see	453.60	unknown	https://doi.org/10.3987/COM-90-5438
(1S,2R,3R,4S,5S,6S,8R,9S,10S,13S,16S,17R,18S)-11-ethyl-6,16,18-trimethoxy-13-(methoxymethyl)-11-azahexacyclo[7.7.2.12,5.01,10.03,8.013,17]nonadecane-4,8,9-triol	92854545	Click to see	467.60	unknown	https://doi.org/10.3987/COM-89-4948 https://doi.org/10.1016/S0031-9422(00)89599-0
(1S,2R,3S,5R,6S,8R,10S,13S,16S,17R,18S)-11-ethyl-8,9,16-trihydroxy-6,18-dimethoxy-13-(methoxymethyl)-11-azahexacyclo[7.7.2.12,5.01,10.03,8.013,17]nonadecan-4-one	134715256	Click to see	451.60	unknown	https://doi.org/10.1016/S0031-9422(00)89599-0
(1S,2R,3S,5R,6S,8R,9S,10S,13S,16S,17R,18S)-11-ethyl-8,9-dihydroxy-6,16,18-trimethoxy-13-(methoxymethyl)-11-azahexacyclo[7.7.2.12,5.01,10.03,8.013,17]nonadecan-4-one	101289627	Click to see	465.60	unknown	https://doi.org/10.1016/S0031-9422(00)89599-0
(1S,5R,6S,8R,9S,13S,16S)-11-ethyl-13-(hydroxymethyl)-4,6,16,18-tetramethoxy-11-azahexacyclo[7.7.2.12,5.01,10.03,8.013,17]nonadecane-8,9-diol	145994515	Click to see CCN1CC2(CCC(C34C2C(C(C31)(C5(CC(C6CC4C5C6OC)OC)O)O)OC)OC)CO	467.60	unknown	https://doi.org/10.3987/COM-90-5438
[(1R,2R,3R,4R,5R,6R,8R,9S,10R,13S,16R,17S)-11-ethyl-8,9,16-trihydroxy-6-methoxy-13-methyl-11-azahexacyclo[7.7.2.12,5.01,10.03,8.013,17]nonadecan-4-yl] acetate	163106219	Click to see	435.60	unknown	https://doi.org/10.1016/S0031-9422(00)89599-0
[(1R,2R,3R,4S,5R,6S,8R,9R,10R,13S,16S,17R,18S)-4,6-diacetyloxy-11-ethyl-8,9-dihydroxy-16,18-dimethoxy-11-azahexacyclo[7.7.2.12,5.01,10.03,8.013,17]nonadecan-13-yl]methyl 2-[(3S)-3-methyl-2,5-dioxopyrrolidin-1-yl]benzoate	163087873	Click to see	738.80	unknown	https://doi.org/10.1021/NP0000116
[(1R,2R,3R,4S,5R,6S,8R,9R,10R,13S,16S,18S)-4,6-diacetyloxy-11-ethyl-8,9-dihydroxy-16,18-dimethoxy-11-azahexacyclo[7.7.2.12,5.01,10.03,8.013,17]nonadecan-13-yl]methyl 2-[(3S)-3-methyl-2,5-dioxopyrrolidin-1-yl]benzoate	163185707	Click to see	738.80	unknown	https://doi.org/10.1021/NP0000116
[(1S,2R,3R,4S,5R,6S,8R,9R,10R,13S,16S,17R,18S)-11-ethyl-8,16-dihydroxy-6,18-dimethoxy-13-(methoxymethyl)-11-azahexacyclo[7.7.2.12,5.01,10.03,8.013,17]nonadecan-4-yl] acetate	101021580	Click to see	479.60	unknown	https://doi.org/10.3987/COM-89-4948
[(1S,2R,3R,4S,5R,6S,8R,9S,10S,13S,16S,17R,18S)-11-ethyl-8,9-dihydroxy-6,16,18-trimethoxy-13-(methoxymethyl)-11-azahexacyclo[7.7.2.12,5.01,10.03,8.013,17]nonadecan-4-yl] acetate	101678897	Click to see	509.60	unknown	https://doi.org/10.1016/S0031-9422(00)89599-0
[(1S,2R,3R,4S,5R,6S,8R,9S,10S,13S,16S,17R,18S)-11-ethyl-9,16-dihydroxy-6,8,18-trimethoxy-13-(methoxymethyl)-11-azahexacyclo[7.7.2.12,5.01,10.03,8.013,17]nonadecan-4-yl] acetate	101006111	Click to see	509.60	unknown	https://doi.org/10.3987/COM-89-4948
[(1S,2R,3R,4S,5R,6S,8S,9S,10R,13R,16S,17R)-11-ethyl-16-hydroxy-4,6-dimethoxy-13-methyl-11-azahexacyclo[7.7.2.12,5.01,10.03,8.013,17]nonadecan-8-yl] acetate	101678900	Click to see	433.60	unknown	https://doi.org/10.1016/S0031-9422(00)89599-0
[(1S,2R,3R,4S,5R,6S,8S,9S,13S,16S,17R)-11-ethyl-8,16-dihydroxy-6-methoxy-13-(methoxymethyl)-11-azahexacyclo[7.7.2.12,5.01,10.03,8.013,17]nonadecan-4-yl] acetate	441720	Click to see	449.60	unknown	https://doi.org/10.1016/S0031-9422(00)89599-0 https://doi.org/10.3987/COM-89-4948
[(1S,2R,3R,4S,5S,6S,8R,9R,10S,13R,16S,17R)-11-ethyl-8,16-dihydroxy-6-methoxy-13-(methoxymethyl)-11-azahexacyclo[7.7.2.12,5.01,10.03,8.013,17]nonadecan-4-yl] acetate	134688067	Click to see CCN1CC2(CCC(C34C2CC(C31)C5(CC(C6CC4C5C6OC(=O)C)OC)O)O)COC	449.60	unknown	https://doi.org/10.1016/S0031-9422(00)89599-0 https://doi.org/10.3987/COM-89-4948
[(1S,2R,3R,4S,5S,6S,8R,9S,10S,13S,16S,17R,18S)-11-ethyl-4,8,9-trihydroxy-6,16,18-trimethoxy-11-azahexacyclo[7.7.2.12,5.01,10.03,8.013,17]nonadecan-13-yl]methyl 2-[(3S)-3-methyl-2,5-dioxopyrrolidin-1-yl]benzoate	101631700	Click to see CCN1CC2(CCC(C34C2C(C(C31)(C5(CC(C6CC4C5C6O)OC)O)O)OC)OC)COC(=O)C7=CC=CC=C7N8C(=O)CC(C8=O)C	668.80	unknown	https://doi.org/10.1021/NP0000116
[(1S,2R,3R,4S,5S,6S,8R,9S,10S,13S,16S,17R,18S)-11-ethyl-4,8,9-trihydroxy-6,16,18-trimethoxy-11-azahexacyclo[7.7.2.12,5.01,10.03,8.013,17]nonadecan-13-yl]methyl 2-acetamidobenzoate	101670652	Click to see	614.70	unknown	https://doi.org/10.3987/COM-90-5438
[(1S,2R,3R,4S,5S,6S,8R,9S,10S,13S,16S,17R,18S)-6-acetyloxy-11-ethyl-4,8,9-trihydroxy-16,18-dimethoxy-11-azahexacyclo[7.7.2.12,5.01,10.03,8.013,17]nonadecan-13-yl]methyl 2-[(3S)-3-methyl-2,5-dioxopyrrolidin-1-yl]benzoate	100993184	Click to see CCN1CC2(CCC(C34C2C(C(C31)(C5(CC(C6CC4C5C6O)OC(=O)C)O)O)OC)OC)COC(=O)C7=CC=CC=C7N8C(=O)CC(C8=O)C	696.80	unknown	https://doi.org/10.1021/NP0000116 https://doi.org/10.1021/NP000473J
[(1S,4S,5R,6S,8R,9S,13S,16S)-11-ethyl-8,9-dihydroxy-4,6,16,18-tetramethoxy-11-azahexacyclo[7.7.2.12,5.01,10.03,8.013,17]nonadecan-13-yl]methyl 2-(3-methyl-2,5-dioxopyrrolidin-1-yl)benzoate	139292146	Click to see CCN1CC2(CCC(C34C2C(C(C31)(C5(CC(C6CC4C5C6OC)OC)O)O)OC)OC)COC(=O)C7=CC=CC=C7N8C(=O)CC(C8=O)C	682.80	unknown	https://doi.org/10.1021/JF00077A039 https://doi.org/10.3987/COM-89-4948
[(5R,6S,8R,9S,13S)-4-acetyloxy-11-ethyl-8,9-dihydroxy-6,16,18-trimethoxy-11-azahexacyclo[7.7.2.12,5.01,10.03,8.013,17]nonadecan-13-yl]methyl 2-(3-methyl-2,5-dioxopyrrolidin-1-yl)benzoate	145994475	Click to see CCN1CC2(CCC(C34C2C(C(C31)(C5(CC(C6CC4C5C6OC(=O)C)OC)O)O)OC)OC)COC(=O)C7=CC=CC=C7N8C(=O)CC(C8=O)C	710.80	unknown	https://doi.org/10.3987/COM-89-4948
[11-Ethyl-8,9-dihydroxy-6,16,18-trimethoxy-13-(methoxymethyl)-11-azahexacyclo[7.7.2.12,5.01,10.03,8.013,17]nonadecan-4-yl] acetate	4481624	Click to see CCN1CC2(CCC(C34C2C(C(C31)(C5(CC(C6CC4C5C6OC(=O)C)OC)O)O)OC)OC)COC	509.60	unknown	https://doi.org/10.1016/S0031-9422(00)89599-0
11-Ethyl-6,8-dimethoxy-13-(methoxymethyl)-11-azahexacyclo[7.7.2.12,5.01,10.03,8.013,17]nonadecane-4,9,16,18-tetrol	14782087	Click to see CCN1CC2(CCC(C34C2C(C(C31)(C5(CC(C6CC4C5C6O)OC)OC)O)O)O)COC	453.60	unknown	https://doi.org/10.3987/COM-90-5438
14-Deacetylnudicauline	441722	Click to see CCN1CC2(CCC(C34C2C(C(C31)(C5(CC(C6CC4C5C6O)OC)O)O)OC)OC)COC(=O)C7=CC=CC=C7N8C(=O)CC(C8=O)C	668.80	unknown	https://doi.org/10.3987/COM-89-4948
14-Dehydrodelcosine	14315435	Click to see	451.60	unknown	https://doi.org/10.1016/S0031-9422(00)89599-0
14-O-Acetylbrowniine	441704	Click to see	509.60	unknown	https://doi.org/10.1016/S0031-9422(00)89599-0 https://doi.org/10.3987/COM-89-4948
16-Deacetylgeyerline	100993186	Click to see CCN1CC2(CCC(C34C2C(C(C31)(C5(CC(C6CC4C5C6OC)O)O)O)OC)OC)COC(=O)C7=CC=CC=C7N8C(=O)CC(C8=O)C	668.80	unknown	https://doi.org/10.1021/NP000473J
Browniine	441714	Click to see CCN1CC2(CCC(C34C2C(C(C31)(C5(CC(C6CC4C5C6O)OC)O)O)OC)OC)COC	467.60	unknown	https://doi.org/10.3987/COM-89-4948 https://doi.org/10.1016/S0031-9422(00)89599-0
Browniine	165288	Click to see CCN1CC2(CCC(C34C2C(C(C31)(C5(CC(C6CC4C5C6O)OC)O)O)OC)OC)COC	467.60	unknown	https://doi.org/10.1016/S0031-9422(00)89599-0
CID 11972492	11972492	Click to see CCN1CC2(CCC(C34C2C(C(C31)(C5(CC(C6CC4C5C6OC)OC)O)O)OC)OC)CO	467.60	unknown	https://doi.org/10.3987/COM-90-5438
CID 138911429	138911429	Click to see CCN1CC2(CCC(C34C2CC(C31)C5(CC(C6CC4C5C6O)OC)O)O)C	377.50	unknown	https://doi.org/10.3987/COM-89-4948
Codelphine	92854546	Click to see	449.60	unknown	https://doi.org/10.1016/S0031-9422(00)89599-0
Dehydrobrowniine	165269	Click to see	465.60	unknown	https://doi.org/10.1016/S0031-9422(00)89599-0 https://doi.org/10.3987/COM-89-4948
Dehydrodelcosine	101289625	Click to see	451.60	unknown	https://doi.org/10.1016/S0031-9422(00)89599-0
Delbonine	185387	Click to see CCN1CC2(CCC(C34C2C(C(C31)(C5(CC(C6CC4C5C6OC(=O)C)OC)OC)O)OC)O)COC	509.60	unknown	https://doi.org/10.3987/COM-89-4948
Delcosin	145925533	Click to see CCN1CC2(CCC(C34C2C(C(C31)(C5(CC(C6CC4C5C6O)OC)O)O)OC)O)COC	453.60	unknown	https://doi.org/10.3987/COM-89-4948
Delcosine	120726	Click to see CCN1CC2(CCC(C34C2C(C(C31)(C5(CC(C6CC4C5C6O)OC)O)O)OC)O)COC	453.60	unknown	https://doi.org/10.3987/COM-89-4948
Delectinine	124201446	Click to see	453.60	unknown	https://doi.org/10.3987/COM-90-5438
Deltatsine	185185	Click to see CCN1CC2(CCC(C34C2C(C(C31)(C5(CC(C6CC4C5C6O)OC)OC)O)OC)O)COC	467.60	unknown	https://doi.org/10.3987/COM-89-4948
Ipwqjeoncufcor-rnnmqtrdsa-	441750	Click to see	710.80	unknown	https://doi.org/10.3987/COM-89-4948
Isotalatisidine	12304578	Click to see	407.50	unknown	https://doi.org/10.3987/COM-89-4948
Kondelfin	93054	Click to see CCN1CC2(CCC(C34C2CC(C31)C5(CC(C6CC4C5C6OC(=O)C)OC)O)O)COC	449.60	unknown	https://doi.org/10.1016/S0031-9422(00)89599-0
> Lipids and lipid-like molecules / Prenol lipids / Diterpenoids / Villanovane, atisane, trachylobane or helvifulvane diterpenoids / Atisane diterpenoids
(1S,3S,5S,8R,9S,11R,14R,16S,17R,18R,19S)-5-methyl-12-methylidene-7-azaheptacyclo[9.6.2.01,8.05,17.07,16.09,14.014,18]nonadecane-3,10,19-triol	101930091	Click to see CC12CC(CC34C1C5CC67C3C(C(C(C6C4N5C2)O)C(=C)C7)O)O	329.40	unknown	https://doi.org/10.3987/COM-90-5438
(3,19-Dihydroxy-5-methyl-12-methylidene-7-azaheptacyclo[9.6.2.01,8.05,17.07,16.09,14.014,18]nonadecan-10-yl) acetate	14039745	Click to see	371.50	unknown	https://doi.org/10.3987/R-1986-06-1605
[(1R,5R,8R,9S,10S,11S,14S,16R,17R,18S)-16,18-dihydroxy-5-methyl-12-methylidene-3-oxo-7-azaheptacyclo[9.6.2.01,8.05,17.07,16.09,14.014,18]nonadecan-10-yl] acetate	139053726	Click to see	385.50	unknown	https://doi.org/10.1016/S0031-9422(00)89599-0
[(1S,3S,5R,8R,9S,10R,11R,14R,16S,17R,18R,19S)-3,19-dihydroxy-5-methyl-12-methylidene-7-azaheptacyclo[9.6.2.01,8.05,17.07,16.09,14.014,18]nonadecan-10-yl] acetate	162910537	Click to see CC(=O)OC1C2C(C3C4(C1C5C36CC(CC7(C6C(C4)N5C7)C)O)CC2=C)O	371.50	unknown	https://doi.org/10.3987/R-1986-06-1605
[(1S,3S,5R,8R,9S,10R,11S,14R,16S,17R,18R,19S)-3,10-dihydroxy-5-methyl-12-methylidene-7-azaheptacyclo[9.6.2.01,8.05,17.07,16.09,14.014,18]nonadecan-19-yl] acetate	163030347	Click to see	371.50	unknown	https://doi.org/10.1016/S0031-9422(00)89599-0
[(1S,3S,5S,8R,9S,10S,11R,14R,16S,17R,18R,19R)-3,19-dihydroxy-5-methyl-12-methylidene-7-azaheptacyclo[9.6.2.01,8.05,17.07,16.09,14.014,18]nonadecan-10-yl] acetate	162910539	Click to see CC(=O)OC1C2C(C3C4(C1C5C36CC(CC7(C6C(C4)N5C7)C)O)CC2=C)O	371.50	unknown	https://doi.org/10.3987/R-1986-06-1605
Hetisine	431673	Click to see CC12CC(CC34C1C5CC67C3C(C(C(C6C4N5C2)O)C(=C)C7)O)O	329.40	unknown	https://doi.org/10.3987/COM-90-5438
> Lipids and lipid-like molecules / Prenol lipids / Diterpenoids / Villanovane, atisane, trachylobane or helvifulvane diterpenoids / Atisane diterpenoids / Hetisine-type diterpenoid alkaloids
(13,15-Dihydroxy-5-methyl-12-methylidene-7-azaheptacyclo[9.6.2.01,8.05,17.07,16.09,14.014,18]nonadecan-19-yl) acetate	162940341	Click to see	371.50	unknown	https://doi.org/10.1016/S0031-9422(00)89599-0
(16,18-Dihydroxy-5-methyl-12-methylidene-3-oxo-7-azaheptacyclo[9.6.2.01,8.05,17.07,16.09,14.014,18]nonadecan-10-yl) acetate	162980364	Click to see	385.50	unknown	https://doi.org/10.1016/S0031-9422(00)89599-0
(1R,5R,8R,9S,10S,11S,14R,16R,17R,18R)-10,16-dihydroxy-5-methyl-12-methylidene-7-azaheptacyclo[9.6.2.01,8.05,17.07,16.09,14.014,18]nonadecan-3-one	162933306	Click to see CC12CC(=O)CC34C1C5(CC67C3CC(C(C6C4N5C2)O)C(=C)C7)O	327.40	unknown	https://doi.org/10.1016/S0031-9422(00)89599-0
(1R,5S,8R,9S,10S,11S,14R,16R,17R,18R)-10,16-dihydroxy-5-methyl-12-methylidene-7-azaheptacyclo[9.6.2.01,8.05,17.07,16.09,14.014,18]nonadecan-3-one	162933307	Click to see	327.40	unknown	https://doi.org/10.1016/S0031-9422(00)89599-0
(3,10-Dihydroxy-5-methyl-12-methylidene-7-azaheptacyclo[9.6.2.01,8.05,17.07,16.09,14.014,18]nonadecan-19-yl) acetate	14039743	Click to see CC(=O)OC1C2C(C3C4C56C1C3(CC7C5C(CC(C6)O)(CN74)C)CC2=C)O	371.50	unknown	https://doi.org/10.1016/S0031-9422(00)89599-0
[(1S,5R,8R,9S,11R,13R,14S,15S,16R,17R,18S,19R)-13,15-dihydroxy-5-methyl-12-methylidene-7-azaheptacyclo[9.6.2.01,8.05,17.07,16.09,14.014,18]nonadecan-19-yl] acetate	162940343	Click to see CC(=O)OC1C2CC3C4C56C1C3(C(C7C5C(CCC6)(CN74)C)O)C(C2=C)O	371.50	unknown	https://doi.org/10.1016/S0031-9422(00)89599-0
[(1S,5S,8R,9S,11R,13R,14S,15S,16R,17R,18S,19R)-13,15-dihydroxy-5-methyl-12-methylidene-7-azaheptacyclo[9.6.2.01,8.05,17.07,16.09,14.014,18]nonadecan-19-yl] acetate	162940342	Click to see	371.50	unknown	https://doi.org/10.1016/S0031-9422(00)89599-0
10,16-Dihydroxy-5-methyl-12-methylidene-7-azaheptacyclo[9.6.2.01,8.05,17.07,16.09,14.014,18]nonadecan-3-one	162933305	Click to see CC12CC(=O)CC34C1C5(CC67C3CC(C(C6C4N5C2)O)C(=C)C7)O	327.40	unknown	https://doi.org/10.1016/S0031-9422(00)89599-0
> Organic acids and derivatives / Carboxylic acids and derivatives / Amino acids, peptides, and analogues / Alpha amino acids and derivatives / Alpha amino acids / L-alpha-amino acids
(2S)-5-amino-2-ammonio-5-oxopentanoate	6992086	Click to see	146.14	unknown	via CMAUP database
> Organic oxygen compounds / Organooxygen compounds / Carbohydrates and carbohydrate conjugates / Glycosyl compounds / Phenolic glycosides
1-[1-hydroxy-3-methyl-8-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxynaphthalen-2-yl]ethanone	5319972	Click to see	378.40	unknown	via CMAUP database
1-[1,6-dihydroxy-3-methyl-8-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxynaphthalen-2-yl]ethanone	100753	Click to see	394.40	unknown	via CMAUP database
2-[[(2R,3S,4S,5R,6S)-6-(7-acetyl-8-hydroxy-3-methoxy-6-methylnaphthalen-1-yl)oxy-3,4,5-trihydroxyoxan-2-yl]methoxy]-2-oxoacetic acid	5321979	Click to see CC1=CC2=CC(=CC(=C2C(=C1C(=O)C)O)OC3C(C(C(C(O3)COC(=O)C(=O)O)O)O)O)OC	480.40	unknown	via CMAUP database
2-methyl-4-oxo-7-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxychromene-5-carboxylic acid	5315687	Click to see	382.30	unknown	via CMAUP database
gallic acid 4-O-beta-D-(6'-O-galloy)glucoside	11972354	Click to see	484.40	unknown	via CMAUP database
Raspberryketone glucoside	5320521	Click to see	326.34	unknown	via CMAUP database
Torachrysone 8-O-Glucoside	11972479	Click to see	408.40	unknown	via CMAUP database
> Organic oxygen compounds / Organooxygen compounds / Carbohydrates and carbohydrate conjugates / Monosaccharides / Hexoses
[(2R,3R,4S,5S,6R)-2,4,5-trihydroxy-6-(hydroxymethyl)oxan-3-yl] (E)-3-phenylprop-2-enoate	11972309	Click to see	310.30	unknown	via CMAUP database
> Organoheterocyclic compounds / Benzopyrans / 1-benzopyrans / Chromones
[(2S)-7-Hydroxy-2-methyl-4-oxo-3,4-dihydro-2H-1-benzopyran-5-yl]acetic acid	5319543	Click to see	236.22	unknown	via CMAUP database
4H-1-Benzopyran-4-one, 5-acetyl-7-hydroxy-2-methyl-	5315891	Click to see	218.20	unknown	via CMAUP database
7-Hydroxy-2-[(2S)-2-hydroxypropyl]-5-methyl-4H-1-benzopyran-4-one	45272307	Click to see	234.25	unknown	via CMAUP database
7-Hydroxy-2-methyl-4-oxo-4H-1-benzopyran-5-acetic acid	14429402	Click to see CC1=CC(=O)C2=C(C=C(C=C2O1)O)CC(=O)O	234.20	unknown	via CMAUP database
7-Hydroxy-2-methyl-4-oxo-4H-1-benzopyran-5-carboxylic acid	5315688	Click to see CC1=CC(=O)C2=C(C=C(C=C2O1)O)C(=O)O	220.18	unknown	via CMAUP database
Cassiachromone	5319500	Click to see CC1=CC(=O)C2=C(C=C(C=C2O1)O)CC(=O)C	232.23	unknown	via CMAUP database
> Phenylpropanoids and polyketides / Coumarins and derivatives / Coumarin glycosides
7-Hydroxy-6-(3,4,5-Trihydroxy-6-(Hydroxymethyl)Oxan-2-Yl)Oxychromen-2-One	5351506	Click to see	340.28	unknown	https://doi.org/10.3987/COM-90-5438
> Phenylpropanoids and polyketides / Flavonoids / Biflavonoids and polyflavonoids
3,3'-Digalloylprocyanidin B2	124016	Click to see C1C(C(OC2=C1C(=CC(=C2C3C(C(OC4=CC(=CC(=C34)O)O)C5=CC(=C(C=C5)O)O)OC(=O)C6=CC(=C(C(=C6)O)O)O)O)O)C7=CC(=C(C=C7)O)O)OC(=O)C8=CC(=C(C(=C8)O)O)O	882.70	unknown	via CMAUP database
procyanidin B1 3-O-gallate	12795888	Click to see	730.60	unknown	via CMAUP database
> Phenylpropanoids and polyketides / Flavonoids / Flavans / Catechins / Catechin gallates
(-)-Epicatechin gallate	107905	Click to see C1C(C(OC2=CC(=CC(=C21)O)O)C3=CC(=C(C=C3)O)O)OC(=O)C4=CC(=C(C(=C4)O)O)O	442.40	unknown	via CMAUP database
> Phenylpropanoids and polyketides / Flavonoids / Flavonoid glycosides / Flavonoid O-glycosides
(+)-Catechin-5-O-beta-D-glucopyranoside	6324898	Click to see	452.40	unknown	via CMAUP database
> Phenylpropanoids and polyketides / Flavonoids / Flavonoid glycosides / Flavonoid O-glycosides / Flavonoid-3-O-glycosides
Rutin	5280805	Click to see	610.50	unknown	via CMAUP database
> Phenylpropanoids and polyketides / Stilbenes
Rhapontigenin	5320954	Click to see	258.27	unknown	via CMAUP database
> Phenylpropanoids and polyketides / Stilbenes / Stilbene glycosides
[(2R,3S,4S,5R,6S)-6-[4-[(E)-2-(3,5-dihydroxyphenyl)ethenyl]phenoxy]-3,4,5-trihydroxyoxan-2-yl]methyl 3,4,5-trihydroxybenzoate	5322088	Click to see	542.50	unknown	via CMAUP database
resveratrol-4'-O-(2''-O-galloyl)-glucopyranoside	10325054	Click to see	542.50	unknown	via CMAUP database
Resveratroloside	5322089	Click to see C1=CC(=CC=C1C=CC2=CC(=CC(=C2)O)O)OC3C(C(C(C(O3)CO)O)O)O	390.40	unknown	via CMAUP database
Rhaponticin	637213	Click to see	420.40	unknown	via CMAUP database
> Phenylpropanoids and polyketides / Tannins
1,2,6-Tri-O-Galloyl-Beta-D-Glucose	440308	Click to see	636.50	unknown	via CMAUP database
1,6-bis-O-galloyl-beta-D-glucose	440221	Click to see	484.40	unknown	via CMAUP database
1,6-di-O-galloyl-2-O-cinnamoyl-beta-D-glucose	6325082	Click to see	614.50	unknown	via CMAUP database
beta-D-Glucopyranose, 2-((2E)-3-phenyl-2-propenoate) 1-(3,4,5-trihydroxybenzoate)	5315898	Click to see	462.40	unknown	via CMAUP database
beta-Glucogallin	124021	Click to see C1=C(C=C(C(=C1O)O)O)C(=O)OC2C(C(C(C(O2)CO)O)O)O	332.26	unknown	via CMAUP database

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Delphinium nuttallianum

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