Common products:
Delphinium barbeyi is cultivated as an ornamental perennial and sold by native‑plant nurseries for garden borders, native‑plant collections, pollinator‑friendly landscaping, and habitat‑restoration projects. Plants are offered as young plugs, potted specimens, or field‑grown stock. Occasionally, tall flower spikes are harvested for cut‑flower arrangements where a prolonged vase life and striking colour are desired.

Scientific/model‑organism use:
The species has been used in phytochemical research. Whole‑plant material (leaves, stems, flowers) has been extracted and analysed to characterize diterpenoid alkaloid profiles, providing data for chemotaxonomic studies of the genus Delphinium. Genetic investigations of the Ranunculaceae have also referenced D. barbeyi as a representative taxon.

Properties relevant to use:
- Growth habit: erect, herbaceous plant reaching 1–2 m, with dense, terminal racemes of blue‑purple flowers that provide visual impact in ornamental settings.
- Ecological preferences: a deep taproot and a requirement for well‑drained, moist soils make it suitable for alpine and sub‑alpine garden sites, as well as for xeriscape designs that incorporate native flora.
- Chemical composition: contains diterpenoid alkaloids (e.g., barbeyiine‑type compounds) that deter herbivory and render the plant unsuitable for food or medicinal applications. The presence of these alkaloids also necessitates handling precautions for livestock.

Sustainability and sourcing:
Because D. barbeyi is native to the Rocky Mountains, cultivated production from seed or vegetative propagation can be achieved with minimal external inputs, supporting low‑impact horticulture. Wild collection can threaten local populations; therefore, seed‑harvesting and plant‑gathering for commercial purposes are typically conducted under sustainable collection guidelines that limit removal to a small fraction of available individuals. Incorporating the species into restoration plantings contributes to the conservation of native pollinator habitats and promotes regional biodiversity.

Synonyms Top

Scientific name	Authority	First published in
Delphinium bakerianum	Bornm.	Bull. Herb. Boissier , sér. 2, 4: 1084 (1904)
Delphinium barbeyi f. subroseum	(Cockerell) Ewan	Univ. Colorado Stud., Ser. D, Phys. Sci. 2: 140. 1945
Delphinium cockerellii	A.Nelson	Bot. Gaz. 42: 51 (1906)
Delphinium exaltatum var. barbeyi	Huth	Helios 10: 35 (1892)
Delphinium occidentale var. barbeyi	(Huth) S.L.Welsh	Great Basin Naturalist 46: 260 1986
Delphinium occidentale subsp. quercicola	Ewan	Univ. Colorado Stud., Ser. D, Phys. Sci. 2: 139 (1945)
Delphinium occidentale f. subroseum	Cockerell	Bull. Torrey Bot. Club 18(6): 168. 1891 ; Nature Notes, 2: 126. 1891.
Delphinium quercetorum	Greene	Pl. Baker. [Greene] 3: 4. 1901
Delphinium scopulorum var. subalpinum	A.Gray	Bot. Gaz. 12: 52 (1887)
Delphinium subalpinum	A.Nelson	Bull. Torrey Bot. Club 27: 263 (1900)
Delphinium occidentale var. suberosum	Cockerell	Bull. Torrey Bot. Club 18: 168 1891
Delphinium attentuatum	(M.E.Jones) Rydb.	Fl. Rocky Mts. 313. 1917 [31 Dec 1917]
Delphinium exaltatum subsp. barbeyi	(Huth) Huth

Common names Top

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Filter by language:

Language	Common/alternative name
English	subalpine larkspur
Chinese	亚高山翠雀花

Subspecies (abbr. subsp./ssp.) Top

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No subspecies added yet.

Varieties (abbr. var.) Top

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No variety added yet.

Subvarieties (abbr. subvar.) Top

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No subvariety added yet.

Forms (abbr. f.) Top

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No forms added yet.

Germination/Propagation Top

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Sow at 4°C for 3 weeks, then increase to 20°C.

Distribution (via POWO/KEW) Top

Legend for the distribution data:

- Doubtful data

- Extinct

- Introduced

- Native

Northern America click to expand
- Northwestern U.S.A.
  - Colorado
  - Wyoming
- South-central U.S.A.
  - New Mexico
- Southwestern U.S.A.
  - Arizona
  - Utah

Links to other databases Top

Suggest others/fix!

Database	ID/link to page
World Flora Online	wfo-0000639751
USDA Plants	DEBA2
Tropicos	27100924
KEW	urn:lsid:ipni.org:names:77282-2
The Plant List	kew-2759461
Open Tree Of Life	591161
NCBI Taxonomy	136316
Nature Serve	2.146945
IPNI	77282-2
iNaturalist	161655
GBIF	3033713
Freebase	/m/0v3dkbb
EPPO	DELBA
EOL	463421
USDA GRIN	408110
Wikipedia	Delphinium_barbeyi
CMAUP	NPO25932

Genomes (via NCBI) Top

No reference genome is available on NCBI yet. We are constantly monitoring for new data.

Scientific Literature Top

Below are displayed the latest 15 articles published in PMC (PubMed Central®) and other sources (DOI number only)!
If you wish to see all the related articles click here.

Title

Authors

Publication

Released

IDs

Is the plant microbiome transmitted from pollen to seeds?

Cardinale M, Schnell S

Front Microbiol

13-Feb-2024

PMCID:	PMC10897013
doi:	10.3389/fmicb.2024.1343795
PMID:	38414764

Potential revival of cholinesterase inhibitors as drugs in veterinary medicine

Žnidaršič N, Štrbenc M, Grgurevič N, Snoj T

Front Vet Sci

02-Mar-2023

PMCID:	PMC10019356
doi:	10.3389/fvets.2023.1125618
PMID:	36937006

Current and lagged climate affects phenology across diverse taxonomic groups

Prather RM, Dalton RM, barr B, Blumstein DT, Boggs CL, Brody AK, Inouye DW, Irwin RE, Martin JG, Smith RJ, Van Vuren DH, Wells CP, Whiteman HH, Inouye BD, Underwood N

Proc Biol Sci

11-Jan-2023

PMCID:	PMC9832555
doi:	10.1098/rspb.2022.2181
PMID:	36629105

Habitat selection in a fluctuating ground squirrel population: Density‐dependence and fitness consequences

Aliperti JR, Jenderseck K, Van Vuren DH

Ecol Evol

29-Aug-2022

PMCID:	PMC9424181
doi:	10.1002/ece3.9241
PMID:	36052297

Plant growth and phytoactive alkaloid synthesis in kratom [Mitragyna speciosa (Korth.)] in response to varying radiance

Zhang M, Sharma A, León F, Avery B, Kjelgren R, McCurdy CR, Pearson BJ

PLoS One

26-Apr-2022

PMCID:	PMC9041851
doi:	10.1371/journal.pone.0259326
PMID:	35472200

Mineral-salt supplementation to ameliorate larkspur poisoning in cattle

Stonecipher CA, Green BT, Welch KD, Gardner DR, Fritz SA, Cook D, Pfister JA

J Anim Sci

14-Apr-2022

PMCID:	PMC9115907
doi:	10.1093/jas/skac133
PMID:	35419604

Global Warming, Advancing Bloom and Evidence for Pollinator Plasticity from Long-Term Bee Emergence Monitoring

Cane J

Insects

16-May-2021

PMCID:	PMC8155920
doi:	10.3390/insects12050457
PMID:	34065667

Selfing rates vary with floral display, pollinator visitation and plant density in natural populations of Mimulus ringens

Christopher DA, Karron JD, Semski WR, Smallwood PA, Trapnell DW, Mitchell RJ

J Evol Biol

27-Mar-2021

PMCID:	PMC8252063
doi:	10.1111/jeb.13781
PMID:	33704852

Community-level reorganizations following migratory pollinator dynamics along a latitudinal gradient

Magrach A, Lara C, Luna UM, Díaz-Infante S, Parker I

Proc Biol Sci

01-Jul-2020

PMCID:	PMC7423476
doi:	10.1098/rspb.2020.0649
PMID:	32605514

Noisy communities and signal detection: why do foragers visit rewardless flowers?

Lichtenberg EM, Heiling JM, Bronstein JL, Barker JL

Philos Trans R Soc Lond B Biol Sci

18-May-2020

PMCID:	PMC7331016
doi:	10.1098/rstb.2019.0486
PMID:	32420846

Pyrodiversity promotes interaction complementarity and population resistance

Ponisio LC

Ecol Evol

26-Mar-2020

PMCID:	PMC7246207
doi:	10.1002/ece3.6210
PMID:	32489608

Early snowmelt projected to cause population decline in a subalpine plant

Campbell DR

Proc Natl Acad Sci U S A

10-Jun-2019

PMCID:	PMC6600911
doi:	10.1073/pnas.1820096116
PMID:	31182600

The effect of alkaloid composition of larkspur (Delphinium) species on the intoxication of Angus heifers

Green BT, Gardner DR, Pfister JA, Welch KD, Bennett GL, Cook D

J Anim Sci

17-Feb-2019

PMCID:	PMC6396257
doi:	10.1093/jas/skz004
PMID:	30772897

Sex-dependent differences for larkspur (Delphinium barbeyi) toxicosis in yearling Angus cattle

Green BT, Keele JW, Gardner DR, Welch KD, Bennett GL, Cook D, Pfister JA, Davis TZ, Stonecipher CA, Lee ST, Stegelmeier BL

J Anim Sci

17-Feb-2019

PMCID:	PMC6396263
doi:	10.1093/jas/skz002
PMID:	30772914

Variation in the degree of reciprocal herkogamy affects the degree of legitimate pollination in a distylous species

Jiang XF, Zhu XF, Li QJ

AoB Plants

02-May-2018

PMCID:	PMC5941151
doi:	10.1093/aobpla/ply022
PMID:	29765587

Phytochemical Profile Top

Add a new one!

Below are displayed the proven (via scientific papers) natural compounds!
You can also contribute to this by clicking here.

Name	PubChem ID	Canonical SMILES	MW	Found in	Proof
> Alkaloids and derivatives / Amaryllidaceae alkaloids / Crinine- and Haemanthamine-type amaryllidaceae alkaloids
(1S,11R,15R)-5,7-dioxa-12-azapentacyclo[10.5.2.01,13.02,10.04,8]nonadeca-2,4(8),9,16-tetraene-11,15-diol	162885746	Click to see C1CN2C3C1(C=CC(C3)O)C4=CC5=C(C=C4C2O)OCO5	287.31	unknown	https://doi.org/10.1248/CPB.37.846
> Benzenoids / Benzene and substituted derivatives
Pemoline	4723	Click to see	176.17	unknown	https://doi.org/10.1016/S0305-1978(01)00120-X https://doi.org/10.1021/JF00025A020
> Lipids and lipid-like molecules / Prenol lipids / Diterpenoids / Aconitane-type diterpenoid alkaloids
(11-Ethyl-8,9-dihydroxy-6,16,18-trimethoxy-4-oxo-11-azahexacyclo[7.7.2.12,5.01,10.03,8.013,17]nonadecan-13-yl)methyl 2-(3-methyl-2,5-dioxopyrrolidin-1-yl)benzoate	4481628	Click to see	666.80	unknown	https://doi.org/10.1016/S0031-9422(00)97779-3
(14-Ethyl-2-hydroxy-6,19-dimethoxy-16-methyl-21-oxo-9,11-dioxa-14-azaheptacyclo[10.7.2.12,5.01,13.03,8.08,12.016,20]docosan-4-yl) acetate	14314600	Click to see	491.60	unknown	https://doi.org/10.1016/S0031-9422(00)97779-3
(1R,2S,3S,4S,5R,6S,8R,12R,13S,16R,19S,20R)-14-ethyl-2-hydroxy-4,6,19-trimethoxy-16-methyl-9,11-dioxa-14-azaheptacyclo[10.7.2.12,5.01,13.03,8.08,12.016,20]docosan-21-one	101826493	Click to see CCN1CC2(CCC(C34C2C(=O)C5(C31)C6(CC(C7CC4(C6C7OC)O)OC)OCO5)OC)C	463.60	unknown	https://doi.org/10.1016/S0031-9422(00)97779-3
(1R,2S,3S,4S,5R,6S,8R,12R,13S,16R,19S,20R)-14-ethyl-4,6,19-trimethoxy-16-methyl-9,11-dioxa-14-azaheptacyclo[10.7.2.12,5.01,13.03,8.08,12.016,20]docosan-2-ol	163055906	Click to see	449.60	unknown	https://doi.org/10.1016/S0040-4039(00)87891-0
(1S,2R,3R,4S,5R,6S,8R,12S,13S,16R,19S,20R,21S)-14-ethyl-4,6,19-trimethoxy-16-methyl-9,11-dioxa-14-azaheptacyclo[10.7.2.12,5.01,13.03,8.08,12.016,20]docosan-21-ol	163052600	Click to see CCN1CC2(CCC(C34C2C(C5(C31)C6(CC(C7CC4C6C7OC)OC)OCO5)O)OC)C	449.60	unknown	https://doi.org/10.1016/S0031-9422(00)97779-3
(1S,2R,3R,4S,5R,6S,8R,9S,10S,13S,16R,17R,18S)-11-ethyl-13-(hydroxymethyl)-4,6,16,18-tetramethoxy-11-azahexacyclo[7.7.2.12,5.01,10.03,8.013,17]nonadecane-8,9-diol	162944122	Click to see	467.60	unknown	https://doi.org/10.1021/JA01126A014
(1S,2R,3R,4S,5R,6S,8R,9S,10S,13S,16S,17R,18S)-11-ethyl-4,6,16,18-tetramethoxy-13-(methoxymethyl)-11-azahexacyclo[7.7.2.12,5.01,10.03,8.013,17]nonadecane-8,9-diol	97960151	Click to see CCN1CC2(CCC(C34C2C(C(C31)(C5(CC(C6CC4C5C6OC)OC)O)O)OC)OC)COC	481.60	unknown	https://doi.org/10.1016/S0040-4039(00)87891-0 https://doi.org/10.1016/S0305-1978(01)00120-X
(1S,2R,3R,4S,5S,6S,8R,12S,13S,16R,19S,20R,21S)-14-ethyl-6,19-dimethoxy-16-methyl-9,11-dioxa-14-azaheptacyclo[10.7.2.12,5.01,13.03,8.08,12.016,20]docosane-4,21-diol	101662590	Click to see CCN1CC2(CCC(C34C2C(C5(C31)C6(CC(C7CC4C6C7O)OC)OCO5)O)OC)C	435.60	unknown	https://doi.org/10.1016/S0031-9422(00)97779-3
(1S,2R,3R,4S,5S,6S,8R,9S,10S,13S,16S,17R,18S)-11-ethyl-6,16,18-trimethoxy-13-(methoxymethyl)-11-azahexacyclo[7.7.2.12,5.01,10.03,8.013,17]nonadecane-4,8,9-triol	92854545	Click to see	467.60	unknown	https://doi.org/10.1016/S0040-4039(00)87891-0 https://doi.org/10.1016/S0031-9422(00)97779-3 https://doi.org/10.1021/JF00025A020
(1S,2R,3S,4R,5R,6R,8R,9S,13S,16R,17R,18R)-11-ethyl-4,6,18-trimethoxy-13-(methoxymethyl)-11-azahexacyclo[7.7.2.12,5.01,10.03,8.013,17]nonadecane-8,9,16-triol	137705073	Click to see CCN1CC2(CCC(C34C2C(C(C31)(C5(CC(C6CC4C5C6OC)OC)O)O)OC)O)COC	467.60	unknown	https://doi.org/10.1016/S0305-1978(01)00120-X
(1S,2R,3S,5R,6S,8R,9R,10S,13S,16S,17R,18S)-11-ethyl-8,9-dihydroxy-6,16,18-trimethoxy-13-(methoxymethyl)-11-azahexacyclo[7.7.2.12,5.01,10.03,8.013,17]nonadecan-4-one	162921562	Click to see	465.60	unknown	https://doi.org/10.1016/S0031-9422(00)97779-3
(1S,5R,6S,8R,9S,13S,16S)-11-ethyl-13-(hydroxymethyl)-4,6,16,18-tetramethoxy-11-azahexacyclo[7.7.2.12,5.01,10.03,8.013,17]nonadecane-8,9-diol	145994515	Click to see CCN1CC2(CCC(C34C2C(C(C31)(C5(CC(C6CC4C5C6OC)OC)O)O)OC)OC)CO	467.60	unknown	https://doi.org/10.1021/JF00025A020 https://doi.org/10.1016/S0305-1978(01)00120-X
(6S,8R,9R,13S,18S)-11-ethyl-4,6,16,18-tetramethoxy-13-(methoxymethyl)-11-azahexacyclo[7.7.2.12,5.01,10.03,8.013,17]nonadecane-8,9-diol	5316490	Click to see CCN1CC2(CCC(C34C2C(C(C31)(C5(CC(C6CC4C5C6OC)OC)O)O)OC)OC)COC	481.60	unknown	https://doi.org/10.1016/S0040-4039(00)87891-0 https://doi.org/10.1016/S0305-1978(01)00120-X
[(1R,2S,3S,4S,5R,6S,8R,12R,13S,16R,19S,20R)-14-ethyl-2-hydroxy-6,19-dimethoxy-16-methyl-21-oxo-9,11-dioxa-14-azaheptacyclo[10.7.2.12,5.01,13.03,8.08,12.016,20]docosan-4-yl] acetate	162963558	Click to see CCN1CC2(CCC(C34C2C(=O)C5(C31)C6(CC(C7CC4(C6C7OC(=O)C)O)OC)OCO5)OC)C	491.60	unknown	https://doi.org/10.1016/S0031-9422(00)97779-3
[(1R,2S,3S,4S,5R,6S,8R,12S,13S,16R,19S,20R,21S)-21-acetyloxy-14-ethyl-2-hydroxy-6,19-dimethoxy-16-methyl-9,11-dioxa-14-azaheptacyclo[10.7.2.12,5.01,13.03,8.08,12.016,20]docosan-4-yl] (2S)-2-methylbutanoate	101665413	Click to see	577.70	unknown	https://doi.org/10.1016/S0031-9422(00)97779-3 https://doi.org/10.1016/S0305-1978(01)00120-X https://doi.org/10.1016/S0040-4039(00)87891-0
[(1R,2S,3S,4S,5R,6S,8R,12S,13S,16R,19S,20R,21S)-21-acetyloxy-14-ethyl-2-hydroxy-6,19-dimethoxy-16-methyl-9,11-dioxa-14-azaheptacyclo[10.7.2.12,5.01,13.03,8.08,12.016,20]docosan-4-yl] acetate	102411261	Click to see CCN1CC2(CCC(C34C2C(C5(C31)C6(CC(C7CC4(C6C7OC(=O)C)O)OC)OCO5)OC(=O)C)OC)C	535.60	unknown	https://doi.org/10.1016/S0031-9422(00)97779-3 https://doi.org/10.1021/JF00025A020
[(1R,2S,3S,4S,5S,6S,8R,12S,13S,16R,19S,20R,21S)-14-ethyl-2,4-dihydroxy-6,19-dimethoxy-16-methyl-9,11-dioxa-14-azaheptacyclo[10.7.2.12,5.01,13.03,8.08,12.016,20]docosan-21-yl] acetate	101927049	Click to see CCN1CC2(CCC(C34C2C(C5(C31)C6(CC(C7CC4(C6C7O)O)OC)OCO5)OC(=O)C)OC)C	493.60	unknown	https://doi.org/10.1016/S0031-9422(00)97779-3
[(1S,2R,3R,4S,5R,6S,8R,9S,10S,13S,16R,17R,18S)-11-ethyl-8,9-dihydroxy-4,6,16,18-tetramethoxy-11-azahexacyclo[7.7.2.12,5.01,10.03,8.013,17]nonadecan-13-yl]methyl 2-aminobenzoate	162982812	Click to see	586.70	unknown	https://doi.org/10.1021/JA01126A014
[(1S,2R,3R,4S,5R,6S,8R,9S,10S,13S,16S,17R,18S)-11-ethyl-8,9-dihydroxy-4,6,16,18-tetramethoxy-11-azahexacyclo[7.7.2.12,5.01,10.03,8.013,17]nonadecan-13-yl]methyl 2-aminobenzoate	57519466	Click to see	586.70	unknown	https://doi.org/10.1021/JA01295A048
[(1S,2R,3R,4S,5R,6S,8R,9S,10S,13S,16S,17R,18S)-11-ethyl-8,9-dihydroxy-6,16,18-trimethoxy-13-(methoxymethyl)-11-azahexacyclo[7.7.2.12,5.01,10.03,8.013,17]nonadecan-4-yl] (2S)-2-methylbutanoate	101190667	Click to see	551.70	unknown	https://doi.org/10.1016/S0305-1978(01)00120-X
[(1S,2R,3R,4S,5R,6S,8R,9S,10S,13S,16S,17R,18S)-11-ethyl-8,9,16-trihydroxy-4,6,18-trimethoxy-11-azahexacyclo[7.7.2.12,5.01,10.03,8.013,17]nonadecan-13-yl]methyl 2-[(3S)-3-methyl-2,5-dioxopyrrolidin-1-yl]benzoate	100915311	Click to see	668.80	unknown	https://doi.org/10.1016/S0305-1978(01)00120-X
[(1S,2R,3R,4S,5S,6S,8R,9S,10S,13S,16S,17R,18S)-11-ethyl-4,8,9-trihydroxy-6,16,18-trimethoxy-11-azahexacyclo[7.7.2.12,5.01,10.03,8.013,17]nonadecan-13-yl]methyl 2-[(3S)-3-methyl-2,5-dioxopyrrolidin-1-yl]benzoate	101631700	Click to see CCN1CC2(CCC(C34C2C(C(C31)(C5(CC(C6CC4C5C6O)OC)O)O)OC)OC)COC(=O)C7=CC=CC=C7N8C(=O)CC(C8=O)C	668.80	unknown	https://doi.org/10.1016/0031-9422(95)00009-7
[(1S,2R,3S,5R,6S,8R,9S,10S,13S,16S,17R,18S)-11-ethyl-8,9-dihydroxy-6,16,18-trimethoxy-4-oxo-11-azahexacyclo[7.7.2.12,5.01,10.03,8.013,17]nonadecan-13-yl]methyl 2-[(3S)-3-methyl-2,5-dioxopyrrolidin-1-yl]benzoate	101927325	Click to see CCN1CC2(CCC(C34C2C(C(C31)(C5(CC(C6CC4C5C6=O)OC)O)O)OC)OC)COC(=O)C7=CC=CC=C7N8C(=O)CC(C8=O)C	666.80	unknown	https://doi.org/10.1016/S0031-9422(00)97779-3 https://doi.org/10.1016/S0305-1978(01)00120-X https://doi.org/10.1002/(SICI)1099-1565(199703)8:2<55::AID-PCA338>3.0.CO;2-Q
[(1S,2S,4S,5R,6S,8R,9R,10R,13S,16S,18S)-6-acetyloxy-11-ethyl-8,9-dihydroxy-4,16,18-trimethoxy-11-azahexacyclo[7.7.2.12,5.01,10.03,8.013,17]nonadecan-13-yl]methyl 2-[(3S)-3-methyl-2,5-dioxopyrrolidin-1-yl]benzoate	138404357	Click to see	710.80	unknown	https://doi.org/10.1016/S0305-1978(01)00120-X
[(1S,4S,5R,6S,8R,9S,13S,16S)-11-ethyl-8,9-dihydroxy-4,6,16,18-tetramethoxy-11-azahexacyclo[7.7.2.12,5.01,10.03,8.013,17]nonadecan-13-yl]methyl 2-(3-methyl-2,5-dioxopyrrolidin-1-yl)benzoate	139292146	Click to see CCN1CC2(CCC(C34C2C(C(C31)(C5(CC(C6CC4C5C6OC)OC)O)O)OC)OC)COC(=O)C7=CC=CC=C7N8C(=O)CC(C8=O)C	682.80	unknown	https://doi.org/10.1021/JF00025A020 https://doi.org/10.1002/(SICI)1099-1565(199703)8:2<55::AID-PCA338>3.0.CO;2-Q https://doi.org/10.1002/PCA.2800040104 https://doi.org/10.1016/S0031-9422(00)97779-3 https://doi.org/10.1016/S0305-1978(01)00120-X
[(2R,3R,4S,5R,6S,8R,13S,16S,17R,18S)-11-ethyl-8,9-dihydroxy-4,6,16,18-tetramethoxy-11-azahexacyclo[7.7.2.12,5.01,10.03,8.013,17]nonadecan-13-yl]methyl 2-aminobenzoate	24884114	Click to see	586.70	unknown	via CMAUP database
[(2S,5R,6S,8R,13S,16R)-14-ethyl-2-hydroxy-4,6,19-trimethoxy-16-methyl-9,11-dioxa-14-azaheptacyclo[10.7.2.12,5.01,13.03,8.08,12.016,20]docosan-21-yl] acetate	145994496	Click to see	507.60	unknown	https://doi.org/10.1016/S0031-9422(00)97779-3 https://doi.org/10.1016/S0305-1978(01)00120-X https://doi.org/10.1002/(SICI)1099-1565(199703)8:2<55::AID-PCA338>3.0.CO;2-Q https://doi.org/10.1021/JF00025A020
[(5R,6S,8R,9S,13S)-4-acetyloxy-11-ethyl-8,9-dihydroxy-6,16,18-trimethoxy-11-azahexacyclo[7.7.2.12,5.01,10.03,8.013,17]nonadecan-13-yl]methyl 2-(3-methyl-2,5-dioxopyrrolidin-1-yl)benzoate	145994475	Click to see CCN1CC2(CCC(C34C2C(C(C31)(C5(CC(C6CC4C5C6OC(=O)C)OC)O)O)OC)OC)COC(=O)C7=CC=CC=C7N8C(=O)CC(C8=O)C	710.80	unknown	https://doi.org/10.1016/S0305-1978(01)00120-X
14-Acetyldictyocarpine	156836	Click to see	535.60	unknown	https://doi.org/10.1016/S0031-9422(00)97779-3 https://doi.org/10.1016/S0305-1978(01)00120-X
14-Deacetylnudicauline	441722	Click to see CCN1CC2(CCC(C34C2C(C(C31)(C5(CC(C6CC4C5C6O)OC)O)O)OC)OC)COC(=O)C7=CC=CC=C7N8C(=O)CC(C8=O)C	668.80	unknown	https://doi.org/10.1016/S0031-9422(00)97779-3 https://doi.org/10.1002/(SICI)1099-1565(199703)8:2<55::AID-PCA338>3.0.CO;2-Q https://doi.org/10.1016/0031-9422(95)00009-7 https://doi.org/10.1002/PCA.2800040104 https://doi.org/10.1021/JF00025A020
14-Ethyl-4,6,19-trimethoxy-16-methyl-9,11-dioxa-14-azaheptacyclo[10.7.2.12,5.01,13.03,8.08,12.016,20]docosan-2-ol	14108126	Click to see	449.60	unknown	https://doi.org/10.1016/S0040-4039(00)87891-0
14-Ethyl-4,6,19-trimethoxy-16-methyl-9,11-dioxa-14-azaheptacyclo[10.7.2.12,5.01,13.03,8.08,12.016,20]docosan-21-ol	14108117	Click to see	449.60	unknown	https://doi.org/10.1021/JF00025A020 https://doi.org/10.1016/S0031-9422(00)97779-3
16-Deacetylgeyerline	100993186	Click to see CCN1CC2(CCC(C34C2C(C(C31)(C5(CC(C6CC4C5C6OC)O)O)O)OC)OC)COC(=O)C7=CC=CC=C7N8C(=O)CC(C8=O)C	668.80	unknown	https://doi.org/10.1016/S0305-1978(01)00120-X
Aconitan-6-one, 20-ethyl-10-hydroxy-1,14,16-trimethoxy-4-methyl-7,8-(methylenebis(oxy))-, (1alpha,14alpha,16beta)-	182686	Click to see	463.60	unknown	https://doi.org/10.1016/S0031-9422(00)97779-3
Anthranoyllycoctonine	441708	Click to see	586.70	unknown	https://doi.org/10.1021/JF00025A020 https://doi.org/10.1021/JA01295A048
Barbinine	441711	Click to see	666.80	unknown	https://doi.org/10.1016/S0031-9422(00)97779-3 https://doi.org/10.1016/S0305-1978(01)00120-X https://doi.org/10.1002/(SICI)1099-1565(199703)8:2<55::AID-PCA338>3.0.CO;2-Q
Browniine	441714	Click to see CCN1CC2(CCC(C34C2C(C(C31)(C5(CC(C6CC4C5C6O)OC)O)O)OC)OC)COC	467.60	unknown	https://doi.org/10.1016/S0040-4039(00)87891-0 https://doi.org/10.1016/S0031-9422(00)97779-3 https://doi.org/10.1021/JF00025A020
CID 11972492	11972492	Click to see CCN1CC2(CCC(C34C2C(C(C31)(C5(CC(C6CC4C5C6OC)OC)O)O)OC)OC)CO	467.60	unknown	https://doi.org/10.1021/JF00025A020 https://doi.org/10.1016/S0305-1978(01)00120-X
CID 99924	99924	Click to see CCN1CC2(CCC(C34C2C(C(C31)(C5(CC(C6CC4C5C6OC)OC)O)O)OC)OC)CO	467.60	unknown	https://doi.org/10.1021/JA01126A014
Dehydrobrowniine	165269	Click to see	465.60	unknown	https://doi.org/10.1021/JF00025A020 https://doi.org/10.1016/S0031-9422(00)97779-3
Delcosin	145925533	Click to see CCN1CC2(CCC(C34C2C(C(C31)(C5(CC(C6CC4C5C6O)OC)O)O)OC)O)COC	453.60	unknown	https://doi.org/10.1016/S0031-9422(00)97779-3 https://doi.org/10.1016/S0305-1978(01)00120-X
Delcosine	120726	Click to see CCN1CC2(CCC(C34C2C(C(C31)(C5(CC(C6CC4C5C6O)OC)O)O)OC)O)COC	453.60	unknown	https://doi.org/10.1016/S0031-9422(00)97779-3 https://doi.org/10.1016/S0305-1978(01)00120-X
Delpheline	3083605	Click to see CCN1CC2(CCC(C34C2C(C5(C31)C6(CC(C7CC4C6C7OC)OC)OCO5)O)OC)C	449.60	unknown	https://doi.org/10.1021/JF00025A020 https://doi.org/10.1016/S0031-9422(00)97779-3
Deltaline	441728	Click to see	507.60	unknown	https://doi.org/10.1016/S0031-9422(00)97779-3 https://doi.org/10.1016/S0305-1978(01)00120-X https://doi.org/10.1002/(SICI)1099-1565(199703)8:2<55::AID-PCA338>3.0.CO;2-Q https://doi.org/10.1021/JF00025A020
Deltamine 6-acetate	165537	Click to see CCN1CC2(CCC(C34C2C(C5(C31)C6(CC(C7CC4(C6C7OC)O)OC)OCO5)OC(=O)C)OC)C	507.60	unknown	https://doi.org/10.1016/S0040-4039(00)87891-0 https://doi.org/10.1016/S0031-9422(00)97779-3
Dictyocarpinine 6-acetate	185280	Click to see	493.60	unknown	https://doi.org/10.1021/JF00025A020 https://doi.org/10.1016/S0031-9422(00)97779-3
Eldeline	92854547	Click to see	507.60	unknown	https://doi.org/10.1016/S0031-9422(00)97779-3 https://doi.org/10.1016/S0040-4039(00)87891-0
Glaucerine	157146	Click to see CCN1CC2(CCC(C34C2C(C5(C31)C6(CC(C7CC4(C6C7OC(=O)C(C)C)O)OC)OCO5)OC(=O)C)OC)C	563.70	unknown	https://doi.org/10.1016/S0031-9422(00)97779-3
Inuline	3800367	Click to see CCN1CC2(CCC(C34C2C(C(C31)(C5(CC(C6CC4C5C6OC)OC)O)O)OC)OC)COC(=O)C7=CC=CC=C7N	586.70	unknown	https://doi.org/10.1021/JA01126A014
Ipwqjeoncufcor-rnnmqtrdsa-	441750	Click to see	710.80	unknown	https://doi.org/10.1016/S0305-1978(01)00120-X
> Lipids and lipid-like molecules / Prenol lipids / Diterpenoids / Villanovane, atisane, trachylobane or helvifulvane diterpenoids / Atisane diterpenoids
(4,17-Diacetyloxy-7-formyl-18-hydroxy-7,10-dimethyl-15-methylidene-13-oxo-10-azahexacyclo[7.7.1.12,14.01,12.03,8.03,11]octadecan-5-yl) benzoate	14463123	Click to see	577.60	unknown	https://doi.org/10.1016/0031-9422(90)89053-C
(4,6,18-Triacetyloxy-7-formyl-17-hydroxy-7,10-dimethyl-15-methylidene-13-oxo-10-azahexacyclo[7.7.1.12,14.01,12.03,8.03,11]octadecan-5-yl) benzoate	163082364	Click to see	635.70	unknown	https://doi.org/10.1016/0031-9422(95)00009-7
[(1R,2R,3R,4S,5R,6S,7S,8S,9R,11R,12S,14R,17R,18R)-4,6,18-triacetyloxy-7-formyl-17-hydroxy-7,10-dimethyl-15-methylidene-13-oxo-10-azahexacyclo[7.7.1.12,14.01,12.03,8.03,11]octadecan-5-yl] benzoate	163082366	Click to see	635.70	unknown	https://doi.org/10.1016/0031-9422(95)00009-7
[(1R,2R,3R,4S,5R,6S,7S,8S,9R,11R,12S,14R,17R,18S)-4,6,18-triacetyloxy-7-formyl-17-hydroxy-7,10-dimethyl-15-methylidene-13-oxo-10-azahexacyclo[7.7.1.12,14.01,12.03,8.03,11]octadecan-5-yl] benzoate	163082365	Click to see	635.70	unknown	https://doi.org/10.1016/0031-9422(95)00009-7
[(1R,2R,3R,4S,5R,6S,7S,8S,9R,11R,12S,14R,17S,18S)-4,6,18-triacetyloxy-7-formyl-17-hydroxy-7,10-dimethyl-15-methylidene-13-oxo-10-azahexacyclo[7.7.1.12,14.01,12.03,8.03,11]octadecan-5-yl] benzoate	101995294	Click to see CC(=O)OC1C2C(=C)CC34C1C56C(C(C3O)N(C5C4C2=O)C)C(C(C(C6OC(=O)C)OC(=O)C7=CC=CC=C7)OC(=O)C)(C)C=O	635.70	unknown	https://doi.org/10.1016/0031-9422(95)00009-7
[(1R,2R,3R,4S,5R,7R,8S,9R,11R,12S,14R,17S,18R)-4,17-diacetyloxy-7-formyl-18-hydroxy-7,10-dimethyl-15-methylidene-13-oxo-10-azahexacyclo[7.7.1.12,14.01,12.03,8.03,11]octadecan-5-yl] benzoate	101422143	Click to see	577.60	unknown	https://doi.org/10.1016/S0305-1978(01)00120-X https://doi.org/10.1016/0031-9422(90)89053-C
[(1R,2R,3R,4S,5S,7R,8S,9R,11R,12S,14R,17S,18R)-4,17-diacetyloxy-7-formyl-18-hydroxy-7,10-dimethyl-15-methylidene-13-oxo-10-azahexacyclo[7.7.1.12,14.01,12.03,8.03,11]octadecan-5-yl] benzoate	163028596	Click to see	577.60	unknown	https://doi.org/10.1016/0031-9422(90)89053-C
[(1R,2R,3R,4S,5S,7R,8S,9R,11R,12S,14R,17S,18S)-4,17-diacetyloxy-7-formyl-18-hydroxy-7,10-dimethyl-15-methylidene-13-oxo-10-azahexacyclo[7.7.1.12,14.01,12.03,8.03,11]octadecan-5-yl] benzoate	163028595	Click to see CC(=O)OC1C(CC(C2C13C4C(C5C(=C)CC46C(C3N(C2C6OC(=O)C)C)C5=O)O)(C)C=O)OC(=O)C7=CC=CC=C7	577.60	unknown	https://doi.org/10.1016/0031-9422(90)89053-C
> Lipids and lipid-like molecules / Prenol lipids / Monoterpenoids / Acyclic monoterpenoids
trans-Ocimenone	6428431	Click to see CC(=CC(=O)C=C(C)C=C)C	150.22	unknown	https://doi.org/10.1016/0031-9422(95)00009-7
> Lipids and lipid-like molecules / Prenol lipids / Terpene glycosides / Triterpene glycosides / Triterpene saponins
(2S,3S,4S,5R,6R)-6-[[(3S,4aR,6aR,6bS,8aR,9R,12aS,14aR,14bR)-9-acetyloxy-4,4,6a,6b,8a,11,11,14b-octamethyl-1,2,3,4a,5,6,7,8,9,10,12,12a,14,14a-tetradecahydropicen-3-yl]oxy]-5-[(2S,3R,4S,5R,6R)-4,5-dihydroxy-6-(hydroxymethyl)-3-[(2S,3R,4R,5R,6S)-3,4,5-trihydroxy-6-methyloxan-2-yl]oxyoxan-2-yl]oxy-3,4-dihydroxyoxane-2-carboxylic acid	101997830	Click to see	969.20	unknown	via CMAUP database
(2S,3S,4S,5R,6R)-6-[[(3S,4Ar,6aR,6bS,8aR,9R,12aS,14aR,14bR)-9-hydroxy-4,4,6a,6b,8a,11,11,14b-octamethyl-1,2,3,4a,5,6,7,8,9,10,12,12a,14,14a-tetradecahydropicen-3-yl]oxy]-5-[(2S,3R,4S,5R,6R)-4,5-dihydroxy-6-(hydroxymethyl)-3-[(2S,3R,4R,5R,6S)-3,4,5-trihydroxy-6-methyloxan-2-yl]oxyoxan-2-yl]oxy-3,4-dihydroxyoxane-2-carboxylic acid	21629874	Click to see	927.10	unknown	via CMAUP database
(2S,3S,4S,5R,6R)-6-[[(3S,4aR,6aR,6bS,8aR,9R,12aS,14aR,14bR)-9-hydroxy-4,4,6a,6b,8a,11,11,14b-octamethyl-1,2,3,4a,5,6,7,8,9,10,12,12a,14,14a-tetradecahydropicen-3-yl]oxy]-5-[(2S,3R,4S,5S)-4,5-dihydroxy-3-[(2S,3R,4R,5R,6S)-3,4,5-trihydroxy-6-methyloxan-2-yl]oxyoxan-2-yl]oxy-3,4-dihydroxyoxane-2-carboxylic acid	100945993	Click to see	897.10	unknown	via CMAUP database
(2S,3S,4S,5R,6R)-6-[[(3S,4S,4aR,6aR,6bS,8aR,9S,10R,11S,12aS,14aR,14bR)-11-carboxy-9,10-dihydroxy-4-(hydroxymethyl)-4,6a,6b,8a,11,14b-hexamethyl-1,2,3,4a,5,6,7,8,9,10,12,12a,14,14a-tetradecahydropicen-3-yl]oxy]-5-[(2S,3R,4S,5R,6R)-4,5-dihydroxy-6-(hydroxymethyl)-3-[(2S,3R,4R,5R,6S)-3,4,5-trihydroxy-6-methyloxan-2-yl]oxyoxan-2-yl]oxy-3,4-dihydroxyoxane-2-carboxylic acid	101998410	Click to see CC1C(C(C(C(O1)OC2C(C(C(OC2OC3C(C(C(OC3OC4CCC5(C(C4(C)CO)CCC6(C5CC=C7C6(CCC8(C7CC(C(C8O)O)(C)C(=O)O)C)C)C)C)C(=O)O)O)O)CO)O)O)O)O)O	989.10	unknown	via CMAUP database
Acetylsoyasaponin I	101997831	Click to see CC1C(C(C(C(O1)OC2C(C(C(OC2OC3C(C(C(OC3OC4CCC5(C(C4(C)CO)CCC6(C5CC=C7C6(CCC8(C7CC(CC8OC(=O)C)(C)C)C)C)C)C)C(=O)O)O)O)CO)O)O)O)O)O	985.20	unknown	via CMAUP database
Soyasaponin I	122097	Click to see	943.10	unknown	via CMAUP database
> Lipids and lipid-like molecules / Prenol lipids / Triterpenoids
(3R,4S,4aR,6aR,6aS,6bR,8aR,10S,12aR,14bS)-2,2,4a,6a,6b,9,9,12a-octamethyl-1,3,4,5,6,6a,7,8,8a,10,11,12,13,14b-tetradecahydropicene-3,4,10-triol	14335979	Click to see	458.70	unknown	https://doi.org/10.1248/CPB.37.846
(3S,4Ar,6aR,6bS,8aR,9R,11R,12aS,14aR,14bR)-11-(hydroxymethyl)-4,4,6a,6b,8a,11,14b-heptamethyl-1,2,3,4a,5,6,7,8,9,10,12,12a,14,14a-tetradecahydropicene-3,9-diol	14335975	Click to see CC1(C2CCC3(C(C2(CCC1O)C)CC=C4C3(CCC5(C4CC(CC5O)(C)CO)C)C)C)C	458.70	unknown	https://doi.org/10.1248/CPB.37.846
(3S,4aR,6aR,6bS,8aR,9R,14aR,14bR)-4,4,6a,6b,8a,11,11,14b-octamethyl-1,2,3,4a,5,6,7,8,9,10,12,13,14,14a-tetradecahydropicene-3,9-diol	14335986	Click to see	442.70	unknown	https://doi.org/10.1248/CPB.37.846
(3S,4R,4aR,6aR,6bS,8aR,9R,11R,12aS,14aR,14bR)-4,11-bis(hydroxymethyl)-4,6a,6b,8a,11,14b-hexamethyl-1,2,3,4a,5,6,7,8,9,10,12,12a,14,14a-tetradecahydropicene-3,9-diol	14335968	Click to see	474.70	unknown	https://doi.org/10.1248/CPB.37.846
(3S,4S,4aR,6aR,6bS,8aR,9R,11S,12aS,14aR,14bR)-4,11-bis(hydroxymethyl)-4,6a,6b,8a,11,14b-hexamethyl-1,2,3,4a,5,6,7,8,9,10,12,12a,14,14a-tetradecahydropicene-3,9-diol	14335972	Click to see CC12CCC(C(C1CCC3(C2CC=C4C3(CCC5(C4CC(CC5O)(C)CO)C)C)C)(C)CO)O	474.70	unknown	https://doi.org/10.1248/CPB.37.846
(4aR,6bR,9S,10S,12aR,14bS)-9-(hydroxymethyl)-2,2,4a,6a,6b,9,12a-heptamethyl-1,3,4,5,6,6a,7,8,8a,10,11,12,13,14b-tetradecahydropicene-3,4,10-triol	5321406	Click to see	474.70	unknown	https://doi.org/10.1248/CPB.37.846
10-hydroxy-2,2,4a,6a,6b,9,9,12a-octamethyl-3,5,6,6a,7,8,8a,10,11,12,13,14b-dodecahydro-1H-picen-4-one	5315569	Click to see CC1(CC2C3=CCC4C5(CCC(C(C5CCC4(C3(CCC2(C(=O)C1)C)C)C)(C)C)O)C)C	440.70	unknown	https://doi.org/10.1248/CPB.37.846
11-(Hydroxymethyl)-4,4,6a,6b,8a,11,14b-heptamethyl-1,2,3,4a,5,6,7,8,9,10,12,12a,14,14a-tetradecahydropicene-3,9-diol	5315112	Click to see	458.70	unknown	https://doi.org/10.1248/CPB.37.846
4,11-Bis(hydroxymethyl)-4,6a,6b,8a,11,14b-hexamethyl-1,2,3,4a,5,6,7,8,9,10,12,12a,14,14a-tetradecahydropicene-3,9-diol	5315488	Click to see	474.70	unknown	https://doi.org/10.1248/CPB.37.846
4,4,6a,6b,8a,11,11,14b-Octamethyl-1,2,3,4a,5,6,7,8,9,10,12,13,14,14a-tetradecahydropicene-3,9-diol	5315647	Click to see CC1(CC(C2(CCC3(C(=C2C1)CCC4C3(CCC5C4(CCC(C5(C)C)O)C)C)C)C)O)C	442.70	unknown	https://doi.org/10.1248/CPB.37.846
Sophoradiol	9846221	Click to see	442.70	unknown	https://doi.org/10.1248/CPB.37.846
Soyasapogenol A	12442849	Click to see CC1(CC2C3=CCC4C5(CCC(C(C5CCC4(C3(CCC2(C(C1O)O)C)C)C)(C)CO)O)C)C	474.70	unknown	https://doi.org/10.1248/CPB.37.846
Soyasapogenol B	115012	Click to see CC1(CC2C3=CCC4C5(CCC(C(C5CCC4(C3(CCC2(C(C1)O)C)C)C)(C)CO)O)C)C	458.70	unknown	https://doi.org/10.1248/CPB.37.846
> Organoheterocyclic compounds / Azepines
(2-Hydroxy-4,6,19-trimethoxy-16-methyl-9,11-dioxa-14-azaheptacyclo[10.7.2.12,5.01,13.03,8.08,12.016,20]docos-14-en-21-yl) acetate	14136139	Click to see	477.50	unknown	https://doi.org/10.1016/S0040-4039(00)87891-0
[(1R,2S,3S,4S,5R,6S,8R,12S,13S,16R,19S,20R,21S)-2-hydroxy-4,6,19-trimethoxy-16-methyl-9,11-dioxa-14-azaheptacyclo[10.7.2.12,5.01,13.03,8.08,12.016,20]docos-14-en-21-yl] acetate	162883605	Click to see	477.50	unknown	https://doi.org/10.1016/S0040-4039(00)87891-0
> Organoheterocyclic compounds / Benzazepines
13-Methyl-12,12a,13,14-tetrahydro-2H,6H,9H-6a,14-epoxy(1,3)dioxolo(4,5-i)(1,3)dioxolo(5,6)indeno(2,1-c)(2)benzazepine	494334	Click to see	351.40	unknown	https://doi.org/10.1016/S0305-1978(01)00120-X
> Phenylpropanoids and polyketides / Isoflavonoids / Isoflav-2-enes / Isoflavones
Daidzein	5281708	Click to see	254.24	unknown	via CMAUP database
Genistein	5280961	Click to see	270.24	unknown	via CMAUP database
Glycitein	5317750	Click to see	284.26	unknown	via CMAUP database
Tectorigenin	5281811	Click to see	300.26	unknown	via CMAUP database
> Phenylpropanoids and polyketides / Isoflavonoids / Isoflavonoid C-glycosides
4'-Methoxypuerarin	5319486	Click to see COC1=CC=C(C=C1)C2=COC3=C(C2=O)C=CC(=C3C4C(C(C(C(O4)CO)O)O)O)O	430.40	unknown	via CMAUP database
Puerarin	5281807	Click to see C1=CC(=CC=C1C2=COC3=C(C2=O)C=CC(=C3C4C(C(C(C(O4)CO)O)O)O)O)O	416.40	unknown	via CMAUP database
> Phenylpropanoids and polyketides / Isoflavonoids / Isoflavonoid O-glycosides
5,6,7,40-Tetrahydroxyisoflavone-6,7-di-o-b-D-glucopyranoside	44207161	Click to see	610.50	unknown	via CMAUP database
Daidzin	107971	Click to see	416.40	unknown	via CMAUP database
Genistin	5281377	Click to see	432.40	unknown	via CMAUP database
Glycitin	187808	Click to see	446.40	unknown	via CMAUP database
Npc208554	100968221	Click to see	594.50	unknown	via CMAUP database
Tectoridin	5281810	Click to see COC1=C(C=C2C(=C1O)C(=O)C(=CO2)C3=CC=C(C=C3)O)OC4C(C(C(C(O4)CO)O)O)O	462.40	unknown	via CMAUP database

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Delphinium barbeyi

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