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Kopsia dasyrachis

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Table of Contents

Details
Description
Synonyms
Common Names
Subtypes (subspecies, varieties, subvarieties, forms)
Germination/Propagation
Distribution
Links to other databases
Genome
Scientific Literature
Phytochemical Profile
Biological Material
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Collections

Details Top

Internal ID UUID643fe020ac1af724459654
Scientific name Kopsia dasyrachis
Authority Ridl.
First published in Bull. Misc. Inform. Kew 1934: 123 (1934)

Description Top

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Synonyms Top

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Common names Top

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Subspecies (abbr. subsp./ssp.) Top

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Varieties (abbr. var.) Top

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Subvarieties (abbr. subvar.) Top

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Forms (abbr. f.) Top

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Germination/Propagation Top

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No germination or propagation data was added yet.

Distribution (via POWO/KEW) Top

Legend for the distribution data:
- Doubtful data
- Extinct
- Introduced
- Native

Links to other databases Top

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Database ID/link to page
World Flora Online wfo-0000221358
Tropicos 100211676
KEW urn:lsid:ipni.org:names:79494-1
The Plant List kew-106324
Open Tree Of Life 6068071
IUCN Red List 162008277
IPNI 79494-1
GBIF 5536032
Freebase /m/0wxx56x
Wikipedia Kopsia_dasyrachis

Genomes (via NCBI) Top

No reference genome is available on NCBI yet. We are constantly monitoring for new data.

Scientific Literature Top

Below are displayed the latest 15 articles published in PMC (PubMed Central®) and other sources (DOI number only)!
Title Authors Publication Released IDs
19(<i>R</i>)-Hydroxyeburnamine and 19(<i>R</i>)-Hydroxy-Isoeburnamine from Kopsia Dasyrachis Toh-Seok Kam, G. Subramaniam, Chen Wei Informa UK Limited 07-Jul-2007
doi:10.1080/10575639808048305
Oxo-Derivatives of Kopsine- and Rhazinilam-Type Alkaloids from a North Borneo<i>Kopsia</i> Toh-Seok Kam, G. Subramaniam Informa UK Limited 07-Jul-2007
doi:10.1080/10575639808041209
Monoterpene Alkaloids from<i>Kopsia macrophylla</i> Christiane Kan-fan, Thierry Sevenet, Hamid A. Hadi, Martine Bonin, Jean-Charles Quirion, Henri-Philippe Husson Informa UK Limited 07-Jul-2007
doi:10.1080/10575639508043223
Kopsirachin, ein ungewöhnliches Alkaloid aus der Apocynaceae <i>Kopsia dasyrachis</i> Ridl. 189. Mitteilung über organische Naturstoffe Katharina Homberger, Manfred Hesse Wiley 28-Dec-2004
doi:10.1002/HLCA.19840670130
Indolalkaloide aus <i>Kopsia dasyrachis</i> Ridl. 185.Mitteilung über organische Naturstoffe Katharina Homberger, Manfred Hesse Wiley 28-Dec-2004
doi:10.1002/HLCA.19820650825
Structure and biomimetic, electrochemically-mediated semisynthesis of the novel pentacyclic indole danuphylline Toh-Seok Kam, Tuck-Meng Lim, Yeun-Mun Choo Elsevier BV 23-Apr-2003
doi:10.1016/S0040-4020(98)01125-9
Danuphylline, a novel pentacyclic indole from Kopsia Toh-Seok Kam, Tuck-Meng Lim, Yeun-Mun Choo, G. Subramaniam Elsevier BV 26-Jul-2002
doi:10.1016/S0040-4039(98)01150-2
Indole and monoterpene alkaloids from the leaves of Kopsia dasyrachis Toh-Seok Kam, Yeun-Mun Choo, Wei Chen, Jia-Xing Yao Elsevier BV 26-Jul-2002
doi:10.1016/S0031-9422(99)00265-4
Alkaloids from Kopsia dasyrachis Toh-Seok Kam, G Subramaniam, Wei Chen Elsevier BV 25-Jul-2002
doi:10.1016/S0031-9422(98)00721-3

Phytochemical Profile Top

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Below are displayed the proven (via scientific papers) natural compounds!
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Name PubChem ID Canonical SMILES MW Found in Proof
> Alkaloids and derivatives / Aspidofractine alkaloids
(15R,16S,21S)-8,10-dioxa-5,17-diazaoctacyclo[15.5.3.01,16.04,15.04,21.06,14.07,11.015,19]pentacosa-6(14),7(11),12-triene-18,20-dione 100969169 Click to see C1CC23CCC45C(C2)C(=O)C6C4(C3N(C1)C6=O)C7=C(N5)C8=C(C=C7)OCO8 364.40 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
(1R,2S,3R,14S,16R,17R)-16-hydroxy-8,10-dioxa-13,19-diazaoctacyclo[12.8.2.11,16.02,19.03,14.03,17.04,12.07,11]pentacosa-4(12),5,7(11)-trien-15-one 162966788 Click to see C1CC23CCC45C(=O)C(C2)(C6C4(C3N(C1)C6)C7=C(N5)C8=C(C=C7)OCO8)O 366.40 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
(1R,4S,15R,16S,19S,21S)-21-hydroxy-8,10-dioxa-5,17-diazaoctacyclo[15.5.3.01,16.04,15.04,21.06,14.07,11.015,19]pentacosa-6(14),7(11),12-triene-18,20-dione 162949086 Click to see C1CC23CCC45C(C2)(C(=O)C6C4(C3N(C1)C6=O)C7=C(N5)C8=C(C=C7)OCO8)O 380.40 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
(1R,9R,16R,18R,21S)-6-[(15R,17S,19R)-15-ethyl-1,11-diazapentacyclo[9.6.2.02,7.08,18.015,19]nonadeca-2,4,6,8(18)-tetraen-17-yl]-2,12-diazahexacyclo[14.2.2.19,12.01,9.03,8.016,21]henicosa-3(8),4,6-triene-18-carboxylic acid 162992547 Click to see CCC12CCCN3C1C4=C(CC3)C5=CC=CC=C5N4C(C2)C6=CC7=C(C=C6)NC89C71CCN2C1C(CCC2)(CC8)CC9C(=O)O 602.80 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
(1S,9R,16S,18R,21S)-6-[(15S,17S,19R)-15-ethyl-1,11-diazapentacyclo[9.6.2.02,7.08,18.015,19]nonadeca-2,4,6,8(18)-tetraen-17-yl]-2,12-diazahexacyclo[14.2.2.19,12.01,9.03,8.016,21]henicosa-3(8),4,6-triene-18-carboxylic acid 162992548 Click to see CCC12CCCN3C1C4=C(CC3)C5=CC=CC=C5N4C(C2)C6=CC7=C(C=C6)NC89C71CCN2C1C(CCC2)(CC8)CC9C(=O)O 602.80 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
(2S,3R)-16-hydroxy-8,10-dioxa-13,19-diazaoctacyclo[12.8.2.11,16.02,19.03,14.03,17.04,12.07,11]pentacosa-4(12),5,7(11)-trien-15-one 100969172 Click to see C1CC23CCC45C(=O)C(C2)(C6C4(C3N(C1)C6)C7=C(N5)C8=C(C=C7)OCO8)O 366.40 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
11-Methoxykopsilongine 101081554 Click to see COC1=C(C2=C(C=C1)C34CCN5C3C6(CCC5)CCC4(N2C(=O)OC)C(C6)(C(=O)OC)O)OC 472.50 unknown https://doi.org/10.1016/S0031-9422(99)00265-4
https://doi.org/10.1016/S0031-9422(98)00721-3
14AH-3a,12-ethano-1H-[1,3]dioxolo[4,5-a]indolizino[1,8-fg]carbazole-5a,6-dicarboxylic acid, 2,3,4,5,12,13-hexahydro-15-oxo-, dimethyl ester 366489 Click to see COC(=O)C12CCC34CCCN5C3C1(C(C5)C(=O)C4)C6=C(N2C(=O)OC)C7=C(C=C6)OCO7 454.50 unknown https://doi.org/10.1016/S0031-9422(99)00265-4
16-Hydroxy-8,10-dioxa-13,19-diazaoctacyclo[12.8.2.11,16.02,19.03,14.03,17.04,12.07,11]pentacosa-4(12),5,7(11)-trien-15-one 162966787 Click to see C1CC23CCC45C(=O)C(C2)(C6C4(C3N(C1)C6)C7=C(N5)C8=C(C=C7)OCO8)O 366.40 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
21-Hydroxy-8,10-dioxa-5,17-diazaoctacyclo[15.5.3.01,16.04,15.04,21.06,14.07,11.015,19]pentacosa-6(14),7(11),12-triene-18,20-dione 162949085 Click to see C1CC23CCC45C(C2)(C(=O)C6C4(C3N(C1)C6=O)C7=C(N5)C8=C(C=C7)OCO8)O 380.40 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
6-(15-Ethyl-1,11-diazapentacyclo[9.6.2.02,7.08,18.015,19]nonadeca-2,4,6,8(18)-tetraen-17-yl)-2,12-diazahexacyclo[14.2.2.19,12.01,9.03,8.016,21]henicosa-3(8),4,6-triene-18-carboxylic acid 162992546 Click to see CCC12CCCN3C1C4=C(CC3)C5=CC=CC=C5N4C(C2)C6=CC7=C(C=C6)NC89C71CCN2C1C(CCC2)(CC8)CC9C(=O)O 602.80 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
dimethyl (1R,16R,21S)-2,12-diazahexacyclo[14.2.2.19,12.01,9.03,8.016,21]henicosa-3,5,7-triene-2,18-dicarboxylate 137628534 Click to see COC(=O)C1CC23CCCN4C2C5(C1(CC3)N(C6=CC=CC=C65)C(=O)OC)CC4 396.50 unknown https://doi.org/10.1016/S0031-9422(99)00265-4
https://doi.org/10.1016/S0031-9422(98)00721-3
dimethyl (1R,18S,21S)-18-hydroxy-4,5-dimethoxy-12-oxido-2-aza-12-azoniahexacyclo[14.2.2.19,12.01,9.03,8.016,21]henicosa-3(8),4,6-triene-2,18-dicarboxylate 163188498 Click to see COC1=C(C2=C(C=C1)C34CC[N+]5(C3C6(CCC5)CCC4(N2C(=O)OC)C(C6)(C(=O)OC)O)[O-])OC 488.50 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
dimethyl (1R,4S,15R,16S,19R)-20-oxo-8,10-dioxa-5,17-diazaheptacyclo[15.4.3.01,16.04,15.06,14.07,11.015,19]tetracosa-6(14),7(11),12-triene-4,5-dicarboxylate 10994092 Click to see COC(=O)C12CCC34CCCN5C3C1(C(C5)C(=O)C4)C6=C(N2C(=O)OC)C7=C(C=C6)OCO7 454.50 unknown https://doi.org/10.1016/S0031-9422(99)00265-4
dimethyl (1R,9R,16R,18R,21S)-4-methoxy-2,12-diazahexacyclo[14.2.2.19,12.01,9.03,8.016,21]henicosa-3(8),4,6-triene-2,18-dicarboxylate 101938868 Click to see COC1=CC=CC2=C1N(C34C25CCN6C5C(CCC6)(CC3)CC4C(=O)OC)C(=O)OC 426.50 unknown https://doi.org/10.1016/S0031-9422(99)00265-4
https://doi.org/10.1016/S0031-9422(98)00721-3
dimethyl (1R,9R,16R,18S,21S)-18-hydroxy-4,5-dimethoxy-12-oxido-2-aza-12-azoniahexacyclo[14.2.2.19,12.01,9.03,8.016,21]henicosa-3(8),4,6-triene-2,18-dicarboxylate 163072369 Click to see COC1=C(C2=C(C=C1)C34CC[N+]5(C3C6(CCC5)CCC4(N2C(=O)OC)C(C6)(C(=O)OC)O)[O-])OC 488.50 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
dimethyl (1S,12R,19R,21S,24S)-21-hydroxy-5,7-dioxa-2,15-diazaheptacyclo[17.2.2.112,15.01,12.03,11.04,8.019,24]tetracosa-3(11),4(8),9-triene-2,21-dicarboxylate 11015920 Click to see COC(=O)C1(CC23CCCN4C2C5(C1(CC3)N(C6=C5C=CC7=C6OCO7)C(=O)OC)CC4)O 456.50 unknown https://doi.org/10.1016/S0031-9422(99)00265-4
dimethyl (1S,9R,12S,16R,18S,21S)-18-hydroxy-12-oxido-2-aza-12-azoniahexacyclo[14.2.2.19,12.01,9.03,8.016,21]henicosa-3,5,7-triene-2,18-dicarboxylate 163189489 Click to see COC(=O)C1(CC23CCC[N+]4(C2C5(C1(CC3)N(C6=CC=CC=C65)C(=O)OC)CC4)[O-])O 428.50 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
dimethyl (1S,9R,16R,18S,21S)-18-hydroxy-12-oxido-2-aza-12-azoniahexacyclo[14.2.2.19,12.01,9.03,8.016,21]henicosa-3,5,7-triene-2,18-dicarboxylate 15479217 Click to see COC(=O)C1(CC23CCC[N+]4(C2C5(C1(CC3)N(C6=CC=CC=C65)C(=O)OC)CC4)[O-])O 428.50 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
dimethyl (1S,9R,16R,18S,21S)-18-hydroxy-2,12-diazahexacyclo[14.2.2.19,12.01,9.03,8.016,21]henicosa-3,5,7-triene-2,18-dicarboxylate 15479227 Click to see COC(=O)C1(CC23CCCN4C2C5(C1(CC3)N(C6=CC=CC=C65)C(=O)OC)CC4)O 412.50 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
dimethyl (1S,9R,16R,18S,21S)-18-hydroxy-4-methoxy-2,12-diazahexacyclo[14.2.2.19,12.01,9.03,8.016,21]henicosa-3(8),4,6-triene-2,18-dicarboxylate 163053161 Click to see COC1=CC=CC2=C1N(C34C25CCN6C5C(CCC6)(CC3)CC4(C(=O)OC)O)C(=O)OC 442.50 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
dimethyl (1S,9R,16S,18R,21S)-2,12-diazahexacyclo[14.2.2.19,12.01,9.03,8.016,21]henicosa-3,5,7-triene-2,18-dicarboxylate 162987877 Click to see COC(=O)C1CC23CCCN4C2C5(C1(CC3)N(C6=CC=CC=C65)C(=O)OC)CC4 396.50 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
dimethyl (1S,9R,16S,18R,21S)-4-methoxy-2,12-diazahexacyclo[14.2.2.19,12.01,9.03,8.016,21]henicosa-3(8),4,6-triene-2,18-dicarboxylate 163084653 Click to see COC1=CC=CC2=C1N(C34C25CCN6C5C(CCC6)(CC3)CC4C(=O)OC)C(=O)OC 426.50 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
dimethyl (9R,18S,21S)-18-hydroxy-12-oxido-2-aza-12-azoniahexacyclo[14.2.2.19,12.01,9.03,8.016,21]henicosa-3,5,7-triene-2,18-dicarboxylate 100969166 Click to see COC(=O)C1(CC23CCC[N+]4(C2C5(C1(CC3)N(C6=CC=CC=C65)C(=O)OC)CC4)[O-])O 428.50 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
Dimethyl 17-oxo-5,14-diazahexacyclo[12.4.3.01,13.04,12.06,11.012,16]henicosa-6,8,10-triene-4,5-dicarboxylate 124222258 Click to see COC(=O)C12CCC34CCCN5C3C1(C(C5)C(=O)C4)C6=CC=CC=C6N2C(=O)OC 410.50 unknown https://doi.org/10.1016/S0031-9422(99)00265-4
Dimethyl 18-hydroxy-2,12-diazahexacyclo[14.2.2.19,12.01,9.03,8.016,21]henicosa-3,5,7-triene-2,18-dicarboxylate 75010320 Click to see COC(=O)C1(CC23CCCN4C2C5(C1(CC3)N(C6=CC=CC=C65)C(=O)OC)CC4)O 412.50 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
Dimethyl 18-hydroxy-4-methoxy-2,12-diazahexacyclo[14.2.2.19,12.01,9.03,8.016,21]henicosa-3(8),4,6-triene-2,18-dicarboxylate 74995840 Click to see COC1=CC=CC2=C1N(C34C25CCN6C5C(CCC6)(CC3)CC4(C(=O)OC)O)C(=O)OC 442.50 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
Dimethyl 18-hydroxy-4,5-dimethoxy-2,12-diazahexacyclo[14.2.2.19,12.01,9.03,8.016,21]henicosa-3(8),4,6-triene-2,18-dicarboxylate 72758498 Click to see COC1=C(C2=C(C=C1)C34CCN5C3C6(CCC5)CCC4(N2C(=O)OC)C(C6)(C(=O)OC)O)OC 472.50 unknown https://doi.org/10.1016/S0031-9422(99)00265-4
https://doi.org/10.1016/S0031-9422(98)00721-3
Dimethyl 2,12-diazahexacyclo[14.2.2.19,12.01,9.03,8.016,21]henicosa-3,5,7-triene-2,18-dicarboxylate 12314384 Click to see COC(=O)C1CC23CCCN4C2C5(C1(CC3)N(C6=CC=CC=C65)C(=O)OC)CC4 396.50 unknown https://doi.org/10.1016/S0031-9422(99)00265-4
https://doi.org/10.1016/S0031-9422(98)00721-3
Dimethyl 21-hydroxy-6-methoxy-2,12-diazahexacyclo[14.2.2.19,12.01,9.03,8.016,21]henicosa-3(8),4,6,17-tetraene-2,18-dicarboxylate 73113056 Click to see COC1=CC2=C(C=C1)N(C34C25CCN6C5(C(CCC6)(CC3)C=C4C(=O)OC)O)C(=O)OC 440.50 unknown https://doi.org/10.1002/HLCA.19820650825
Dimethyl 4-methoxy-2,12-diazahexacyclo[14.2.2.19,12.01,9.03,8.016,21]henicosa-3(8),4,6-triene-2,18-dicarboxylate 74995867 Click to see COC1=CC=CC2=C1N(C34C25CCN6C5C(CCC6)(CC3)CC4C(=O)OC)C(=O)OC 426.50 unknown https://doi.org/10.1016/S0031-9422(99)00265-4
https://doi.org/10.1016/S0031-9422(98)00721-3
Kopsamine 44326373 Click to see COC(=O)C1(CC23CCCN4C2C5(C1(CC3)N(C6=C5C=CC7=C6OCO7)C(=O)OC)CC4)O 456.50 unknown https://doi.org/10.1016/S0031-9422(99)00265-4
https://doi.org/10.1016/S0031-9422(98)00721-3
Kopsidasine 11812230 Click to see COC1=CC2=C(C=C1)N(C34C25CCN6C5(C(CCC6)(CC3)C=C4C(=O)OC)O)C(=O)OC 440.50 unknown https://doi.org/10.1002/HLCA.19820650825
Kopsiflorine 10024663 Click to see COC(=O)C1(CC23CCCN4C2C5(C1(CC3)N(C6=CC=CC=C65)C(=O)OC)CC4)O 412.50 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
Kopsilongine 44326354 Click to see COC1=CC=CC2=C1N(C34C25CCN6C5C(CCC6)(CC3)CC4(C(=O)OC)O)C(=O)OC 442.50 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
Kopsine 20054949 Click to see COC(=O)N1C2=CC=CC=C2C34C15CCC67C3N(CCC6)CC4C(=O)C5(C7)O 380.40 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
Kopsinine 7069830 Click to see COC(=O)C1CC23CCCN4C2C5(C1(CC3)NC6=CC=CC=C65)CC4 338.40 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
Kopsoffine 158148 Click to see CCC12CCCN3C1C4=C(CC3)C5=CC=CC=C5N4C(C2)C6=CC7=C(C=C6)NC89C71CCN2C1C(CCC2)(CC8)CC9C(=O)OC 616.80 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
Kopsoffinol 180723 Click to see CC(C12CCCN3C1C4=C(CC3)C5=CC=CC=C5N4C(C2)C6=CC7=C(C=C6)NC89C71CCN2C1C(CCC2)(CC8)CC9C(=O)OC)O 632.80 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
methyl (12R,13S,16R,18S)-18-hydroxy-17-oxo-5,14-diazaheptacyclo[12.5.3.01,13.04,12.04,18.06,11.012,16]docosa-6,8,10-triene-5-carboxylate 133550442 Click to see COC(=O)N1C2=CC=CC=C2C34C15CCC67C3N(CCC6)CC4C(=O)C5(C7)O 380.40 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
methyl (12R,13S,18S)-7,8-dimethoxy-15,17-dioxo-5,14-diazaheptacyclo[12.5.3.01,13.04,12.04,18.06,11.012,16]docosa-6(11),7,9-triene-5-carboxylate 100969170 Click to see COC1=C(C2=C(C=C1)C34C5C(=O)C6C3(N2C(=O)OC)CCC7(C6)C4N(C5=O)CCC7)OC 438.50 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
methyl (15R,16S,21S)-18,20-dioxo-8,10-dioxa-5,17-diazaoctacyclo[15.5.3.01,16.04,15.04,21.06,14.07,11.015,19]pentacosa-6(14),7(11),12-triene-5-carboxylate 100969168 Click to see COC(=O)N1C2=C(C=CC3=C2OCO3)C45C16CCC78C4N(CCC7)C(=O)C5C(=O)C6C8 422.40 unknown https://doi.org/10.1080/10575639808041209
https://doi.org/10.1016/S0031-9422(99)00265-4
https://doi.org/10.1016/S0031-9422(98)00721-3
methyl (15S,16S,19R)-22-hydroxy-18,21-dioxo-8,10,20-trioxa-5,17-diazaoctacyclo[15.6.3.01,16.04,15.04,22.06,14.07,11.015,19]hexacosa-6(14),7(11),12-triene-5-carboxylate 101699203 Click to see COC(=O)N1C2=C(C=CC3=C2OCO3)C45C16CCC78C4N(CCC7)C(=O)C5OC(=O)C6(C8)O 454.40 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
methyl (1R,12R,19S,21S,24S)-21-hydroxy-5,7-dioxa-2,15-diazaheptacyclo[17.2.2.112,15.01,12.03,11.04,8.019,24]tetracosa-3(11),4(8),9-triene-21-carboxylate 162933943 Click to see COC(=O)C1(CC23CCCN4C2C5(C1(CC3)NC6=C5C=CC7=C6OCO7)CC4)O 398.50 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
methyl (1R,4R,12R,13S,16S,18R)-15,17-dioxo-5,14-diazaheptacyclo[12.5.3.01,13.04,12.04,18.06,11.012,16]docosa-6,8,10-triene-5-carboxylate 163106958 Click to see COC(=O)N1C2=CC=CC=C2C34C15CCC67C3N(CCC6)C(=O)C4C(=O)C5C7 378.40 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
methyl (1R,4S,12R,13S,16S,18S)-18-hydroxy-7,8-dimethoxy-15,17-dioxo-5,14-diazaheptacyclo[12.5.3.01,13.04,12.04,18.06,11.012,16]docosa-6(11),7,9-triene-5-carboxylate 163103638 Click to see COC1=C(C2=C(C=C1)C34C5C(=O)C6(C3(N2C(=O)OC)CCC7(C6)C4N(C5=O)CCC7)O)OC 454.50 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
methyl (1R,4S,15R,16S,19R,21S)-21-hydroxy-20-oxo-8,10-dioxa-5,17-diazaoctacyclo[15.5.3.01,16.04,15.04,21.06,14.07,11.015,19]pentacosa-6(14),7(11),12-triene-5-carboxylate 163038115 Click to see COC(=O)N1C2=C(C=CC3=C2OCO3)C45C16CCC78C4N(CCC7)CC5C(=O)C6(C8)O 424.40 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
methyl (1R,4S,15R,16S,19R)-20-oxo-8,10-dioxa-5,17-diazaheptacyclo[15.4.3.01,16.04,15.06,14.07,11.015,19]tetracosa-6(14),7(11),12-triene-4-carboxylate 162934292 Click to see COC(=O)C12CCC34CCCN5C3C1(C(C5)C(=O)C4)C6=C(N2)C7=C(C=C6)OCO7 396.40 unknown https://doi.org/10.1016/S0031-9422(99)00265-4
methyl (1R,4S,15R,16S,19S,21S)-21-hydroxy-18,20-dioxo-8,10-dioxa-5,17-diazaoctacyclo[15.5.3.01,16.04,15.04,21.06,14.07,11.015,19]pentacosa-6(14),7(11),12-triene-5-carboxylate 162873685 Click to see COC(=O)N1C2=C(C=CC3=C2OCO3)C45C16CCC78C4N(CCC7)C(=O)C5C(=O)C6(C8)O 438.40 unknown https://doi.org/10.1016/S0031-9422(99)00265-4
https://doi.org/10.1016/S0031-9422(98)00721-3
methyl (1R,9R,16R,18R,21S)-6-[(15R,17R,19S)-15-[(1R)-1-hydroxyethyl]-1,11-diazapentacyclo[9.6.2.02,7.08,18.015,19]nonadeca-2,4,6,8(18)-tetraen-17-yl]-2,12-diazahexacyclo[14.2.2.19,12.01,9.03,8.016,21]henicosa-3(8),4,6-triene-18-carboxylate 162873522 Click to see CC(C12CCCN3C1C4=C(CC3)C5=CC=CC=C5N4C(C2)C6=CC7=C(C=C6)NC89C71CCN2C1C(CCC2)(CC8)CC9C(=O)OC)O 632.80 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
methyl (1R,9R,16R,18R,21S)-6-[(15R,17S,19R)-15-ethyl-1,11-diazapentacyclo[9.6.2.02,7.08,18.015,19]nonadeca-2,4,6,8(18)-tetraen-17-yl]-2,12-diazahexacyclo[14.2.2.19,12.01,9.03,8.016,21]henicosa-3(8),4,6-triene-18-carboxylate 162930399 Click to see CCC12CCCN3C1C4=C(CC3)C5=CC=CC=C5N4C(C2)C6=CC7=C(C=C6)NC89C71CCN2C1C(CCC2)(CC8)CC9C(=O)OC 616.80 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
methyl (1R,9R,16R,18R,21S)-6-[(15S,17S,19R)-15-[(1R)-1-hydroxyethyl]-1,11-diazapentacyclo[9.6.2.02,7.08,18.015,19]nonadeca-2,4,6,8(18)-tetraen-17-yl]-2,12-diazahexacyclo[14.2.2.19,12.01,9.03,8.016,21]henicosa-3(8),4,6-triene-18-carboxylate 162873521 Click to see CC(C12CCCN3C1C4=C(CC3)C5=CC=CC=C5N4C(C2)C6=CC7=C(C=C6)NC89C71CCN2C1C(CCC2)(CC8)CC9C(=O)OC)O 632.80 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
methyl (1R,9R,16R,18S,21S)-6-[(15R,17S,19R)-15-ethyl-1,11-diazapentacyclo[9.6.2.02,7.08,18.015,19]nonadeca-2,4,6,8(18)-tetraen-17-yl]-2,12-diazahexacyclo[14.2.2.19,12.01,9.03,8.016,21]henicosa-3(8),4,6-triene-18-carboxylate 162930401 Click to see CCC12CCCN3C1C4=C(CC3)C5=CC=CC=C5N4C(C2)C6=CC7=C(C=C6)NC89C71CCN2C1C(CCC2)(CC8)CC9C(=O)OC 616.80 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
methyl (1R,9R,16S,18R,21S)-6-[(15R,17R,19S)-15-(1-hydroxyethyl)-1,11-diazapentacyclo[9.6.2.02,7.08,18.015,19]nonadeca-2,4,6,8(18)-tetraen-17-yl]-2,12-diazahexacyclo[14.2.2.19,12.01,9.03,8.016,21]henicosa-3(8),4,6-triene-18-carboxylate 102156619 Click to see CC(C12CCCN3C1C4=C(CC3)C5=CC=CC=C5N4C(C2)C6=CC7=C(C=C6)NC89C71CCN2C1C(CCC2)(CC8)CC9C(=O)OC)O 632.80 unknown https://doi.org/10.1080/10575639808048305
methyl (1R,9R,16S,18R,21S)-6-[(15S,17R,19S)-15-ethyl-1,11-diazapentacyclo[9.6.2.02,7.08,18.015,19]nonadeca-2,4,6,8(18)-tetraen-17-yl]-2,12-diazahexacyclo[14.2.2.19,12.01,9.03,8.016,21]henicosa-3(8),4,6-triene-18-carboxylate 132966072 Click to see CCC12CCCN3C1C4=C(CC3)C5=CC=CC=C5N4C(C2)C6=CC7=C(C=C6)NC89C71CCN2C1C(CCC2)(CC8)CC9C(=O)OC 616.80 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
methyl (1S,4R,15R,16R,19S,22R)-22-hydroxy-18,21-dioxo-8,10,20-trioxa-5,17-diazaoctacyclo[15.6.3.01,16.04,15.04,22.06,14.07,11.015,19]hexacosa-6(14),7(11),12-triene-5-carboxylate 163106491 Click to see COC(=O)N1C2=C(C=CC3=C2OCO3)C45C16CCC78C4N(CCC7)C(=O)C5OC(=O)C6(C8)O 454.40 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
methyl (1S,9R,16S,18R,21S)-2,12-diazahexacyclo[14.2.2.19,12.01,9.03,8.016,21]henicosa-3,5,7-triene-18-carboxylate 51397011 Click to see COC(=O)C1CC23CCCN4C2C5(C1(CC3)NC6=CC=CC=C65)CC4 338.40 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
Methyl (9R,18R,21S)-2,12-diazahexacyclo[14.2.2.19,12.01,9.03,8.016,21]henicosa-3,5,7-triene-18-carboxylate 21123851 Click to see COC(=O)C1CC23CCCN4C2C5(C1(CC3)NC6=CC=CC=C65)CC4 338.40 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
Methyl 17-oxo-5,14-diazahexacyclo[12.4.3.01,13.04,12.06,11.012,16]henicosa-6,8,10-triene-4-carboxylate 138376544 Click to see COC(=O)C12CCC34CCCN5C3C1(C(C5)C(=O)C4)C6=CC=CC=C6N2 352.40 unknown https://doi.org/10.1016/S0031-9422(99)00265-4
Methyl 20-oxo-8,10-dioxa-5,17-diazaheptacyclo[15.4.3.01,16.04,15.06,14.07,11.015,19]tetracosa-6(14),7(11),12-triene-4-carboxylate 162934291 Click to see COC(=O)C12CCC34CCCN5C3C1(C(C5)C(=O)C4)C6=C(N2)C7=C(C=C6)OCO7 396.40 unknown https://doi.org/10.1016/S0031-9422(99)00265-4
Methyl 21-hydroxy-18,20-dioxo-8,10-dioxa-5,17-diazaoctacyclo[15.5.3.01,16.04,15.04,21.06,14.07,11.015,19]pentacosa-6(14),7(11),12-triene-5-carboxylate 162873684 Click to see COC(=O)N1C2=C(C=CC3=C2OCO3)C45C16CCC78C4N(CCC7)C(=O)C5C(=O)C6(C8)O 438.40 unknown https://doi.org/10.1016/S0031-9422(99)00265-4
https://doi.org/10.1016/S0031-9422(98)00721-3
Methyl 21-hydroxy-20-oxo-8,10-dioxa-5,17-diazaoctacyclo[15.5.3.01,16.04,15.04,21.06,14.07,11.015,19]pentacosa-6(14),7(11),12-triene-5-carboxylate 163038114 Click to see COC(=O)N1C2=C(C=CC3=C2OCO3)C45C16CCC78C4N(CCC7)CC5C(=O)C6(C8)O 424.40 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
Methyl 21-hydroxy-5,7-dioxa-2,15-diazaheptacyclo[17.2.2.112,15.01,12.03,11.04,8.019,24]tetracosa-3(11),4(8),9-triene-21-carboxylate 139291917 Click to see COC(=O)C1(CC23CCCN4C2C5(C1(CC3)NC6=C5C=CC7=C6OCO7)CC4)O 398.50 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
Methyl 3-hydroxy-22-oxokopsan-1-carboxylate 624835 Click to see COC(=O)N1C2=CC=CC=C2C34C15CCC67C3N(CCC6)CC4C(=O)C5(C7)O 380.40 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
Methyl aspidofractinine-3-carboxylate 573380 Click to see COC(=O)C1CC23CCCN4C2C5(C1(CC3)NC6=CC=CC=C65)CC4 338.40 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
Methyl chanofruticosinate 91895274 Click to see COC(=O)C12CCC34CCCN5C3C1(C(C5)C(=O)C4)C6=CC=CC=C6N2C(=O)OC 410.50 unknown https://doi.org/10.1016/S0031-9422(99)00265-4
Methyl demethoxycarbonylchanofruticosinate 25104767 Click to see COC(=O)C12CCC34CCCN5C3C1(C(C5)C(=O)C4)C6=CC=CC=C6N2 352.40 unknown https://doi.org/10.1016/S0031-9422(99)00265-4
Pleiocarpine 101650372 Click to see COC(=O)C1CC23CCCN4C2C5(C1(CC3)N(C6=CC=CC=C65)C(=O)OC)CC4 396.50 unknown https://doi.org/10.1016/S0031-9422(99)00265-4
> Alkaloids and derivatives / Corynanthean-type alkaloids
methyl (1R,10R,12R,13Z,18R)-13-ethylidene-18-formyl-8,15-diazapentacyclo[10.5.1.01,9.02,7.010,15]octadeca-2,4,6,8-tetraene-18-carboxylate 163186541 Click to see CC=C1CN2CCC34C5=CC=CC=C5N=C3C2CC1C4(C=O)C(=O)OC 350.40 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
> Alkaloids and derivatives / Eburnan-type alkaloids
(15S,17R,19R)-15-[(1R)-1-hydroxyethyl]-1,11-diazapentacyclo[9.6.2.02,7.08,18.015,19]nonadeca-2,4,6,8(18)-tetraen-17-ol 100969164 Click to see CC(C12CCCN3C1C4=C(CC3)C5=CC=CC=C5N4C(C2)O)O 312.40 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
(15S,17S,19R)-15-[(1R)-1-hydroxyethyl]-1,11-diazapentacyclo[9.6.2.02,7.08,18.015,19]nonadeca-2,4,6,8(18)-tetraen-17-ol 100969165 Click to see CC(C12CCCN3C1C4=C(CC3)C5=CC=CC=C5N4C(C2)O)O 312.40 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
(1R)-1-[(15S,19R)-1,11-diazapentacyclo[9.6.2.02,7.08,18.015,19]nonadeca-2,4,6,8(18)-tetraen-15-yl]ethanol 162929132 Click to see CC(C12CCCN3C1C4=C(CC3)C5=CC=CC=C5N4CC2)O 296.40 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
1-(1,11-Diazapentacyclo[9.6.2.02,7.08,18.015,19]nonadeca-2,4,6,8(18)-tetraen-15-yl)ethanol 162929131 Click to see CC(C12CCCN3C1C4=C(CC3)C5=CC=CC=C5N4CC2)O 296.40 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
15-(1-Hydroxyethyl)-1,11-diazapentacyclo[9.6.2.02,7.08,18.015,19]nonadeca-2,4,6,8(18)-tetraen-17-ol 163017142 Click to see CC(C12CCCN3C1C4=C(CC3)C5=CC=CC=C5N4C(C2)O)O 312.40 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
Eburnamenin-14-ol, 14,15-dihydro-, (14alpha)- 442066 Click to see CCC12CCCN3C1C4=C(CC3)C5=CC=CC=C5N4C(C2)O 296.40 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
Eburnamenin-14(15H)-one 92112 Click to see CCC12CCCN3C1C4=C(CC3)C5=CC=CC=C5N4C(=O)C2 294.40 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
Eburnamine 101699 Click to see CCC12CCCN3C1C4=C(CC3)C5=CC=CC=C5N4C(C2)O 296.40 unknown https://doi.org/10.1080/10575639808048305
https://doi.org/10.1016/S0031-9422(98)00721-3
Eburnamonine 3195 Click to see CCC12CCCN3C1C4=C(CC3)C5=CC=CC=C5N4C(=O)C2 294.40 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
> Alkaloids and derivatives / Pleiocarpaman alkaloids
methyl (13Z,14S,16S,18R)-13-ethylidene-1,11-diazapentacyclo[12.3.1.02,7.08,17.011,16]octadeca-2,4,6,8(17)-tetraene-18-carboxylate 163087785 Click to see CC=C1CN2CCC3=C4C2CC1C(N4C5=CC=CC=C35)C(=O)OC 322.40 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
methyl (13Z,14S,16S,18R)-13-ethylidene-18-methoxy-1,11-diazapentacyclo[12.3.1.02,7.08,17.011,16]octadeca-2,4,6,8(17)-tetraene-18-carboxylate 163188311 Click to see CC=C1CN2CCC3=C4C2CC1C(N4C5=CC=CC=C35)(C(=O)OC)OC 352.40 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
methyl (13Z,14S,16S,18S)-13-ethylidene-1,11-diazapentacyclo[12.3.1.02,7.08,17.011,16]octadeca-2,4,6,8(17)-tetraene-18-carboxylate 10448813 Click to see CC=C1CN2CCC3=C4C2CC1C(N4C5=CC=CC=C35)C(=O)OC 322.40 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
Methyl 13-ethylidene-1,11-diazapentacyclo[12.3.1.02,7.08,17.011,16]octadeca-2,4,6,8(17)-tetraene-18-carboxylate 558637 Click to see CC=C1CN2CCC3=C4C2CC1C(N4C5=CC=CC=C35)C(=O)OC 322.40 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
Methyl 13-ethylidene-18-methoxy-1,11-diazapentacyclo[12.3.1.02,7.08,17.011,16]octadeca-2,4,6,8(17)-tetraene-18-carboxylate 163019949 Click to see CC=C1CN2CCC3=C4C2CC1C(N4C5=CC=CC=C35)(C(=O)OC)OC 352.40 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
Pleiocarpamine 5385014 Click to see CC=C1CN2CCC3=C4C2CC1C(N4C5=CC=CC=C35)C(=O)OC 322.40 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
> Alkaloids and derivatives / Rhazinilam alkaloids
(8R,15S,19R)-15-ethyl-1,11-diazapentacyclo[9.7.1.02,7.08,19.015,19]nonadeca-2,4,6-triene-10,18-dione 154496893 Click to see CCC12CCCN3C14C(CC3=O)C5=CC=CC=C5N4C(=O)CC2 310.40 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
Leuconoxine 70698272 Click to see CCC12CCCN3C14C(CC3=O)C5=CC=CC=C5N4C(=O)CC2 310.40 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
> Alkaloids and derivatives / Yohimbine alkaloids
Lamuran 251561 Click to see CC1C2CN3CCC4=C(C3CC2C(=CO1)C(=O)OC)NC5=CC=CC=C45 352.40 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
Tetrahydroalstonine 72340 Click to see CC1C2CN3CCC4=C(C3CC2C(=CO1)C(=O)OC)NC5=CC=CC=C45 352.40 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
> Benzenoids
8a-Ethyl-7,8,8a,9,10,11-hexahydroindolizino[8,1-ef][1]benzoazonine-6(5H),11-dione 15479224 Click to see CCC12CCC(=O)NC3=CC=CC=C3C4=C1N(C=C4)C(=O)CC2 308.40 unknown https://doi.org/10.1080/10575639808041209
https://doi.org/10.1016/S0031-9422(98)00721-3
> Lignans, neolignans and related compounds / Furanoid lignans
Syringaresinol 100067 Click to see COC1=CC(=CC(=C1O)OC)C2C3COC(C3CO2)C4=CC(=C(C(=C4)OC)O)OC 418.40 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
Syringaresinol, (+)- 443023 Click to see COC1=CC(=CC(=C1O)OC)C2C3COC(C3CO2)C4=CC(=C(C(=C4)OC)O)OC 418.40 unknown https://doi.org/10.1016/S0031-9422(98)00721-3
> Organoheterocyclic compounds / Indoles and derivatives / Carbazoles
dimethyl (1R,9S,16R,19S,20S)-6-methoxy-21-oxo-2,12-diazahexacyclo[10.6.2.19,16.01,9.03,8.016,20]henicosa-3(8),4,6-triene-2,19-dicarboxylate 163104455 Click to see COC1=CC2=C(C=C1)N(C34C25CCN6CCCC(C6C3C(=O)OC)(C5=O)CC4)C(=O)OC 440.50 unknown https://doi.org/10.1080/10575639508043223
dimethyl (1S,12R,15S,20S)-19-formyl-22-oxo-6,8-dioxa-11,19-diazahexacyclo[13.5.3.01,12.02,10.05,9.015,20]tricosa-2(10),3,5(9)-triene-11,12-dicarboxylate 163068381 Click to see COC(=O)C12CCC34CCCN(C3C1(CC(=O)C4)C5=C(N2C(=O)OC)C6=C(C=C5)OCO6)C=O 470.50 unknown https://doi.org/10.1016/S0031-9422(99)00265-4
Dimethyl 19-formyl-22-oxo-6,8-dioxa-11,19-diazahexacyclo[13.5.3.01,12.02,10.05,9.015,20]tricosa-2(10),3,5(9)-triene-11,12-dicarboxylate 73193302 Click to see COC(=O)C12CCC34CCCN(C3C1(CC(=O)C4)C5=C(N2C(=O)OC)C6=C(C=C5)OCO6)C=O 470.50 unknown https://doi.org/10.1016/S0040-4039(98)01150-2
https://doi.org/10.1016/S0031-9422(99)00265-4
https://doi.org/10.1016/S0040-4020(98)01125-9
> Organoheterocyclic compounds / Piperidines
(2S,4S,4aR,7S,7aS)-2,4,7-trimethyl-2-oxido-3,4,4a,5,6,7-hexahydro-1H-cyclopenta[c]pyridin-2-ium-7a-ol 163185831 Click to see CC1CCC2C1(C[N+](CC2C)(C)[O-])O 199.29 unknown https://doi.org/10.1016/S0031-9422(99)00265-4
(4S,4aR,7S,7aS)-2,4,7-trimethyl-2-oxido-3,4,4a,5,6,7-hexahydro-1H-cyclopenta[c]pyridin-2-ium-7a-ol 15489797 Click to see CC1CCC2C1(C[N+](CC2C)(C)[O-])O 199.29 unknown https://doi.org/10.1016/S0031-9422(99)00265-4
> Phenylpropanoids and polyketides / Flavonoids / Flavans / Catechins
(2R,3S)-6,8-bis[(1R,4R,4aR,7S,7aR)-2,4,7-trimethyl-1,3,4,4a,5,6,7,7a-octahydrocyclopenta[c]pyridin-1-yl]-2-(3,4-dihydroxyphenyl)-3,4-dihydro-2H-chromene-3,5,7-triol 163009766 Click to see CC1CCC2C1C(N(CC2C)C)C3=C(C(=C4C(=C3O)CC(C(O4)C5=CC(=C(C=C5)O)O)O)C6C7C(CCC7C(CN6C)C)C)O 620.80 unknown https://doi.org/10.1016/S0031-9422(99)00265-4
https://doi.org/10.1002/HLCA.19840670130
2-(3,4-dihydroxyphenyl)-6,8-bis(2,4,7-trimethyl-1,3,4,4a,5,6,7,7a-octahydrocyclopenta[c]pyridin-1-yl)-3,4-dihydro-2H-chromene-3,5,7-triol 73808884 Click to see CC1CCC2C1C(N(CC2C)C)C3=C(C(=C4C(=C3O)CC(C(O4)C5=CC(=C(C=C5)O)O)O)C6C7C(CCC7C(CN6C)C)C)O 620.80 unknown https://doi.org/10.1016/S0031-9422(99)00265-4
https://doi.org/10.1002/HLCA.19840670130

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