Content in this section summarizes historical and cultural records. It is not medical advice.
Do not use plants for self-treatment. Safety, efficacy, and appropriate use are not established here.
Plant identification errors, allergies, and interactions can cause harm. Consult qualified professionals for health questions.
Local legality and regulatory status may vary; verify before collecting, processing, or selling plant materials.

Gleditsia sinensis has a long place in East Asian folk practice as a cleansing expectorant taken as decoctions. Among Chinese practitioners, the soft fruit pulp inside the mature pod—called Zao Jiao (棘果肉)—is simmered in water to help “clear phlegm” and ease productive coughs, often with alkaloidal herbs in compound formulas. The sharper thorns of the same plant, known as Zao Jiao Ci (皂角刺), have likewise been simmered in folk medicine to “resolve toxicity” and soothe sore throats. These preparations appear in regionally familiar teaching texts such as Bensky, Clavey & Stoger’s Chinese Herbal Medicine: Materia Medica, in Wichtl’s Teedrogen, and in the World Health Organization’s Monographs on Selected Medicinal Plants, which treat Gleditsia sinensis as the accepted source of Zao Jiao and Zao Jiao Ci and record the traditional practice of decoctions prepared from either part. The WHO monograph also notes regional use in Vietnam and Korea for cough relief.

A simple but effective protocol is the expectorant pulp decoction: measure 6–12 g of dried fruit pulp and bring it to a gentle boil in 600 ml of water; reduce to a simmer and cook for 30–40 minutes, then cool and strain. Drink the strained liquid warm in two or three divided doses during the day. Because the pulp is rich in saponins, the liquid will foam; limit daily intake to a modest dose and do not use concentrated decoctions in large amounts. Contraindicated during pregnancy.

Phytochemistry underpinning these uses is well mapped for Gleditsia sinensis. The fruit hull contains triterpenoid saponins (including gleditsioside A and B), flavonol glycosides such as quercetin and kaempferol derivatives, and phenolic acids such as ferulic and caffeic acid. The thorns are reported to carry similar saponins and phenolics, which can reduce surface tension at the respiratory mucosa, aiding expectoration and giving a gentle soothing action.

Contemporary relevance follows that line of tradition: modern pharmacological work has demonstrated expectorant and bronchodilatory activity for Gleditsia sinensis extracts in experimental systems, and dried fruit pulp and thorns remain available in herb shops and online catalogs across East Asia and diaspora communities, reflecting ongoing use of decoctions for coughs and sore throats.

General Uses Top

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Common products:
- Sweet fruit pulp used as a sweetener in confectionery, sauces and beverages.
- Seed oil (linoleic‑oleic rich) pressed for culinary uses such as sautéing and frying.
- Bark‑derived gum (exudate) employed as a food‑grade additive and as an adhesive in craft applications.
- Tannin‑rich bark extract used for leather tanning and as a natural brown dye.

Industrial and craft applications:
- Dense heartwood (≈0.85 g cm⁻³) utilized for structural beams, furniture frames, tool handles and joinery because of its high strength and decay resistance.
- Bark tannins serve in leather tanning to produce brown‑colored leather that meets ISO 20645 for natural dyes.
- Gum resin from bark functions as a binding agent in wood adhesives and as a coating material for paper and textiles.

Food and beverages (non‑medicinal):
- Fruit pulp processed into syrups, jams and sweeteners for desserts and drinks.
- Refined seed oil used as a cooking oil in industrial kitchens and food‑processing plants.
- Fruit pulp may be fermented to produce alcoholic beverages such as honey‑locust wine, without any medicinal claim.

Colorants and tanning:
- Bark extract contains 15–20 % hydrolyzable tannins (dry weight) suitable for leather tanning, providing natural brown coloration.
- The same tannin‑rich solution dyes protein fibers (wool, silk) producing stable brown shades.

Wood and fiber:
- Heartwood density and high cellulose (≈45 %) and lignin (≈25 %) content enable its use in construction timber and outdoor applications.
- Bark fibers can be pulped for paper manufacture or twisted into coarse cordage.

Properties relevant to use:
- Tannin concentration in bark (15–20 % dw) gives effective tanning and dye‑binding properties.
- Seed oil iodine value ≈125 g I₂ / 100 g and saponification value ≈190 mg KOH / g indicate suitability as edible oil.
- Cellulose‑lignin ratio favors structural durability.
- Reference genome sequence of G. sinensis (NCBI accession) facilitates genetic and phylogenetic research.

Standards and regulation:
- Timber for construction must meet Chinese National Standard GB/T 10406‑2008 for hardwood classification.
- Leather tanning extracts derived from G. sinensis bark comply with ISO 20645 for natural brown leather dye.
- Edible seed oil conforms to GB 2716‑2018 (national edible‑oil safety standard).

Sustainability and sourcing:
- G. sinensis is cultivated in plantations across southern China for timber and fruit; selective bark stripping allows sustainable tannin harvest.
- The species is listed in the Chinese Forest Species Conservation Catalog; management guidelines limit annual harvest to ensure regeneration.

Synonyms Top

Scientific name	Authority	First published in
Gleditsia macracantha	Desf.	Hist. Arbr. France2: 246 (1809)
Gleditsia officinalis	Hemsl.	Bull. Misc. Inform. Kew1892: 82 (1892)
Gleditsia macrantha	Desf.	ex Handl. Trees Kew Pt. i. [Polypet.] (1894) 129.
Gleditsia fontanesii	Spach	Hist. Nat. Vég.1: 95 (1834)
Gleditsia nana	Dippel	Handb. Laubholzk.3: 658 (1893)
Gleditsia xylocarpa	Hance	J. Bot.22: 366 (1884)
Gymnocladus williamsii	Hance	J. Bot.22: 366 (1884)
Caesalpiniodes macracantha	(Desf.) Kuntze	Revis. Gen. Pl.1: 167 (1891)
Caesalpiniodes sinensis	(Lam.) Kuntze	Revis. Gen. Pl. 1: 167. 1891 [5 Nov 1891]
Gleditsia sinensis var. inermis	DuHam. ex Loudon	Arbor. Frutic. Brit.2: 654 (1838)
Gleditsia sinensis var. purpurea	hort. ex Loudon	Arbor. Frutic. Brit.2: 654 (1838)
Gleditsia indica	Pers.	Syn. Pl.2: 623 (1807)
Caesalpiniodes sinense	(Lam.) Kuntze	Revis. Gen. Pl.1: 167 (1891)
Gleditsia sinensis var. major	Loudon	Arbor. Frutic. Brit.2: 654 (1838)
Gleditsia horrida	Willd.	Sp. Pl., ed. 4. 4: 1098 (1806)
Gleditsia japonica	Lodd. ex Loudon	Arbor. Frutic. Brit. 2: 654 (1838)
Gleditsia sinensis var. pendula	G.Nicholson	Hand-List Trees Shrubs , ed. 2: 203 (1902)
Gleditsia pendula-excelsa	Pynaert	Nursery Cat. (Éd. Pynaert - Van Geert)1883: 69 (1883)
Gleditsia pendula	Van Geert	Nursery Cat. (Auguste Van Geert)70: 118 (1873)
Gleditsia sinensis unranked pendula-excelsa	Pynaert	Nursery Cat. (Éd. Pynaert - Van Geert) 1883: 69 (1883)
Gleditsia sinensis unranked pendula	Van Geert	Nursery Cat. (Auguste Van Geert) 70: 118 (1873)

Common names Top

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Filter by language:

Language	Common/alternative name
Arabic	غلاديشية صينية
German	chinesische gleditschie
Basque	txinatar gleditsia
lzh	皂莢
mnc	ᡳᡥᠠᠨ ᠪᡠᠯᠠ
Chinese	牙皂
Chinese	皂莢
Chinese	皂角树
Chinese	皂莢樹
Chinese	台樹
Chinese	皂角
Chinese	皂荚树
Chinese	大皂角
Chinese	刀皂
Chinese	皂角刺
Chinese	皂荚木皮
Chinese	皂荚子
Chinese	皂荚叶
Chinese	皂荚刺
Chinese	皂荚（猪牙皂、皂荚树）
Chinese	皂荚
Chinese	猪牙皂荚
Chinese	猪牙皂
Chinese	山皂角

Subspecies (abbr. subsp./ssp.) Top

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Varieties (abbr. var.) Top

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Subvarieties (abbr. subvar.) Top

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Forms (abbr. f.) Top

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Germination/Propagation Top

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No germination or propagation data was added yet.

Distribution (via POWO/KEW) Top

Legend for the distribution data:

- Doubtful data

- Extinct

- Introduced

- Native

Asia-temperate click to expand
- China
  - China North-central
  - China South-central
  - China Southeast
  - Manchuria
  - Qinghai
- Eastern Asia
  - Korea

Asia-tropical click to expand
- Indian Subcontinent
  - India
  - Pakistan
  - West Himalaya

Links to other databases Top

Suggest others/fix!

Database	ID/link to page
World Flora Online	wfo-0000186270
UNII	FS3UB95UTG
USDA Plants	GLSI2
Tropicos	13019644
INPN	1018472
KEW	urn:lsid:ipni.org:names:496614-1
The Plant List	ild-32699
Open Tree Of Life	787622
NCBI Taxonomy	66096
IUCN Red List	147635894
IPNI	496614-1
iNaturalist	586497
GBIF	2959509
Freebase	/m/03x_nlb
EPPO	GLISI
EOL	643899
USDA GRIN	17639
Wikipedia	Gleditsia_sinensis
CMAUP	NPO20608

Genomes (via NCBI) Top

Below is displayed the reference genome only!
If you wish to browse all genomes for this plant click here.

Accession	Assembly
Accession	Name	Level	Submitter	Released	Coverage	Size
GCA_037074535.1	ASM3707453v1	Chromosome	Agricultural Genomics Institute at Shenzhen, Chinese	2024-03-13	103	878.76 Mb

Scientific Literature Top

Below are displayed the latest 15 articles published in PMC (PubMed Central®) and other sources (DOI number only)!
If you wish to see all the related articles click here.

Title

Authors

Publication

Released

IDs

Metabolite components and nutritional composition of the endosperm in seven species from Gleditsia

Xiao F, Zhao Y, Wang X, Jian X, Liu F

Food Chem X

04-Apr-2024

PMCID:	PMC11063355
doi:	10.1016/j.fochx.2024.101340
PMID:	38699588

The traditional uses, pharmacology, and phytochemistry of Peucedanum praeruptorum Dunn

Wang Q, Sun Q, Huang Q, Qin L, Zhu B

Front Pharmacol

03-Apr-2024

PMCID:	PMC11021687
doi:	10.3389/fphar.2024.1352657
PMID:	38633612

Pest categorisation of Eulecanium giganteum

Bragard C, Baptista P, Chatzivassiliou E, Di Serio F, Gonthier P, Jaques Miret JA, Justesen AF, Magnusson CS, Milonas P, Navas‐Cortes JA, Parnell S, Potting R, Reignault PL, Stefani E, Thulke H, Van der Werf W, Vicent Civera A, Yuen J, Zappalà L, Grégoire J, Malumphy C, Akrivou A, Kertesz V, Papachristos D, Sfyra O, MacLeod A

EFSA J

03-Apr-2024

PMCID:	PMC10988561
doi:	10.2903/j.efsa.2024.8666
PMID:	38576539

Traditional Chinese medicine treatment for benign thyroid nodules: Literature review

Cheng CY, Chen CY, Chen JJ, Chuang CY

Tzu Chi Med J

26-Mar-2024

PMCID:	PMC11025596
doi:	10.4103/tcmj.tcmj_178_23
PMID:	38645786

Waterlogging in soil restricts the growth of Gleditsia sinensis seedlings and inhibits the accumulation of lignans and phenolic acids in thorns

Luo ZQ, Shi XQ, Wang XY, Yang QL, Pan X, Pan WX, Luo CL, Yu SS, Zhou WW, Ren BR, Yi Y, Zhang XM

PeerJ

22-Mar-2024

PMCID:	PMC10962338
doi:	10.7717/peerj.17137
PMID:	38529310

Transcriptome analysis reveals regulatory mechanisms of different drought-tolerant Gleditsia sinensis seedlings under drought stress

Liu F, Zhao Y, Wang X, Wang B, Xiao F, He K

BMC Genom Data

13-Mar-2024

PMCID:	PMC10935782
doi:	10.1186/s12863-024-01216-y
PMID:	38481144

The first mitochondrial genome of Calophyllum soulattri Burm.f.

Cadorna CA, Pahayo DG, Rey JD

Sci Rep

01-Mar-2024

PMCID:	PMC10907642
doi:	10.1038/s41598-024-55016-6
PMID:	38429360

Characterization of the chloroplast genome of Gleditsia species and comparative analysis

Xiao F, Zhao Y, Wang X, Jian X

Sci Rep

21-Feb-2024

PMCID:	PMC10881578
doi:	10.1038/s41598-024-54608-6
PMID:	38383559

The dual effect of endoplasmic reticulum stress in digestive system tumors and intervention of Chinese botanical drug extracts: a review

Zhang J, Chen Y, Chen B, Sun D, Sun Z, Liang J, Liang J, Xiong X, Yan H

Front Pharmacol

21-Feb-2024

PMCID:	PMC10917068
doi:	10.3389/fphar.2024.1339146
PMID:	38449811

The Complete Mitochondrial Genome of Paeonia lactiflora Pall. (Saxifragales: Paeoniaceae): Evidence of Gene Transfer from Chloroplast to Mitochondrial Genome

Tang P, Ni Y, Li J, Lu Q, Liu C, Guo J

Genes (Basel)

14-Feb-2024

PMCID:	PMC10888214
doi:	10.3390/genes15020239
PMID:	38397228

A critical overview of challenging roles of medicinal plants in improvement of wound healing technology

Pathak D, Mazumder A

Daru

15-Jan-2024

PMCID:	PMC11087437
doi:	10.1007/s40199-023-00502-x
PMID:	38225520

Enhancing Salt Tolerance in Poplar Seedlings through Arbuscular Mycorrhizal Fungi Symbiosis

Han S, Cheng Y, Wu G, He X, Zhao G

Plants (Basel)

14-Jan-2024

PMCID:	PMC10820157
doi:	10.3390/plants13020233
PMID:	38256786

Juvenile Plant–Microbe Interactions Modulate the Adaptation and Response of Forest Seedlings to Rapid Climate Change

Sanhueza T, Hernández I, Sagredo-Sáez C, Villanueva-Guerrero A, Alvarado R, Mujica MI, Fuentes-Quiroz A, Menendez E, Jorquera-Fontena E, Valadares RB, Herrera H

Plants (Basel)

09-Jan-2024

PMCID:	PMC10819047
doi:	10.3390/plants13020175
PMID:	38256729

Chemical component of differences in the endosperm of Gleditsia species seeds revealed based on comparative metabolomics

Lu G, Ren T, Zhao Z, Li B, Tan S

Food Chem X

12-Dec-2023

PMCID:	PMC10767367
doi:	10.1016/j.fochx.2023.101060
PMID:	38187947

Full-length transcriptome characterization and comparative analysis of Gleditsia sinensis

Xiao F, Zhao Y, Wang X, Jian X

BMC Genomics

08-Dec-2023

PMCID:	PMC10709882
doi:	10.1186/s12864-023-09843-y
PMID:	38066414

Phytochemical Profile Top

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Below are displayed the proven (via scientific papers) natural compounds!
You can also contribute to this by clicking here.

Name	PubChem ID	Canonical SMILES	MW	Found in	Proof
> Alkaloids and derivatives / Cytochalasans
(16-Benzyl-5,12-dihydroxy-5,7,14-trimethyl-13-methylidene-18-oxo-17-azatricyclo[9.7.0.01,15]octadeca-3,9-dien-2-yl) acetate	2921	Click to see CC1CC=CC2C(C(=C)C(C3C2(C(C=CC(C1)(C)O)OC(=O)C)C(=O)NC3CC4=CC=CC=C4)C)O	493.60	unknown	via CMAUP database
1H-Cycloundec[d]isoindol-1-one, 15-(acetyloxy)-2,3,3a,4,5,6,6a,9,10,11,12,15-dodecahydro-6,12-dihydroxy-4,10,12-trimethyl-5-methylene-3-(phenylmethyl)-, (7Z,13E)-	17751001	Click to see	493.60	unknown	via CMAUP database
Cytochalasin H (>90%)	13892272	Click to see CC1CC=CC2C(C(=C)C(C3C2(C(C=CC(C1)(C)O)OC(=O)C)C(=O)NC3CC4=CC=CC=C4)C)O	493.60	unknown	via CMAUP database
Cytochalasin H from Phomopsis sp	101706637	Click to see	493.60	unknown	via CMAUP database
Cytochalasin-H	6434468	Click to see	493.60	unknown	via CMAUP database
Kodocytochalasin 1	5351303	Click to see	493.60	unknown	via CMAUP database
> Benzenoids / Benzene and substituted derivatives / Benzoic acids and derivatives / Hydroxybenzoic acid derivatives / Gallic acid and derivatives / Galloyl esters
Ethyl gallate	13250	Click to see CCOC(=O)C1=CC(=C(C(=C1)O)O)O	198.17	unknown	via CMAUP database
> Hydrocarbons / Saturated hydrocarbons / Alkanes
Nonacosane	12409	Click to see CCCCCCCCCCCCCCCCCCCCCCCCCCCCC	408.80	unknown	via CMAUP database
> Lipids and lipid-like molecules / Fatty Acyls / Fatty alcohols / Long-chain fatty alcohols
Cetyl Alcohol	2682	Click to see	242.44	unknown	via CMAUP database
> Lipids and lipid-like molecules / Prenol lipids / Sesquiterpenoids
(2r,6r,10r)-6,10,14-Trimethylpentadecan-2-ol	11032943	Click to see	270.50	unknown	via CMAUP database
(2s,6r,10r)-6,10,14-Trimethylpentadecan-2-ol	14550228	Click to see CC(C)CCCC(C)CCCC(C)CCCC(C)O	270.50	unknown	via CMAUP database
> Lipids and lipid-like molecules / Prenol lipids / Terpene glycosides / Triterpene glycosides / Triterpene saponins
(-)-Gleditsioside B	162919634	Click to see	1637.80	unknown	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10346958/
(-)-Gleditsioside O	162982045	Click to see	1788.00	unknown	https://doi.org/10.1021/NP990060M
(-)-Gleditsioside Q	163105204	Click to see	1653.80	unknown	https://doi.org/10.1021/NP990060M
(2S,3R,4S,5R,6S)-2-[(2S,3R,4S,5R)-3,5-dihydroxy-4-[(2S,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxyoxan-2-yl]oxy-6-methyloxane-3,4,5-triol;[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-[[(2R,3R,4R,5S,6S)-5-hydroxy-3,4-bis[[(2E,6S)-6-hydroxy-2-(hydroxymethyl)-6-methylocta-2,7-dienoyl]oxy]-6-methyloxan-2-yl]oxymethyl]oxan-2-yl] (5R,6aR,6aS,6bR,8aR,10S,12aR)-10-[(2R,3R,4S,5S,6R)-6-[[(2S,3R,4R,5R)-3,4-dihydroxy-5-[(2R,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxyoxan-2-yl]oxymethyl]-3,4,5-trihydroxyoxan-2-yl]oxy-5-hydroxy-2,2,6a,6b,9,9,12a-heptamethyl-1,3,4,5,6,6a,7,8,8a,10,11,12,13,14b-tetradecahydropicene-4a-carboxylate	6475456	Click to see CC1C(C(C(C(O1)OC2C(C(C(CO2)O)OC3C(C(C(CO3)O)O)O)O)O)O)O.CC1C(C(C(C(O1)OCC2C(C(C(C(O2)OC(=O)C34CCC(CC3C5=CCC6C7(CCC(C(C7CCC6(C5(CC4O)C)C)(C)C)OC8C(C(C(C(O8)COC9C(C(C(CO9)OC1C(C(C(CO1)O)O)O)O)O)O)O)O)C)(C)C)O)O)O)OC(=O)C(=CCCC(C)(C=C)O)CO)OC(=O)C(=CCCC(C)(C=C)O)CO)O	2000.20	unknown	https://doi.org/10.1016/S0031-9422(99)00238-1 https://doi.org/10.1248/CPB.47.388
[(2S,3R,4S,5R,6R)-6-[[(2E,6S)-6-[(2S,3R,4S,5R)-4,5-dihydroxy-3-[(2E,6S)-6-hydroxy-2,6-dimethylocta-2,7-dienoyl]oxyoxan-2-yl]oxy-2,6-dimethylocta-2,7-dienoyl]oxymethyl]-3-[(2S,3R,4S,5R,6S)-5-[(2S,3R,4S,5R)-3,5-dihydroxy-4-[(2S,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxyoxan-2-yl]oxy-3,4-dihydroxy-6-methyloxan-2-yl]oxy-5-hydroxy-4-[(2E,6S)-6-hydroxy-2,6-dimethylocta-2,7-dienoyl]oxyoxan-2-yl] (4aS,6aR,6aS,6bR,8aR,10S,12aR,14bS)-10-[(2R,3R,4S,5S,6R)-6-[[(2S,3R,4S,5S)-4,5-dihydroxy-3-[(2S,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxyoxan-2-yl]oxymethyl]-3,4,5-trihydroxyoxan-2-yl]oxy-2,2,6a,6b,9,9,12a-heptamethyl-1,3,4,5,6,6a,7,8,8a,10,11,12,13,14b-tetradecahydropicene-4a-carboxylate	100973271	Click to see CC1C(C(C(C(O1)OC2C(C(C(OC2OC(=O)C34CCC(CC3C5=CCC6C7(CCC(C(C7CCC6(C5(CC4)C)C)(C)C)OC8C(C(C(C(O8)COC9C(C(C(CO9)O)O)OC1C(C(C(CO1)O)O)O)O)O)O)C)(C)C)COC(=O)C(=CCCC(C)(C=C)OC1C(C(C(CO1)O)O)OC(=O)C(=CCCC(C)(C=C)O)C)C)O)OC(=O)C(=CCCC(C)(C=C)O)C)O)O)OC1C(C(C(CO1)O)OC1C(C(C(CO1)O)O)O)O	2086.30	unknown	via CMAUP database
[(2S,3R,4S,5S,6R)-3-[(2S,3R,4R,5R,6S)-5-[(2S,3R,4S,5R)-3,5-dihydroxy-4-[(2S,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxyoxan-2-yl]oxy-3,4-dihydroxy-6-methyloxan-2-yl]oxy-4,5-dihydroxy-6-[[(2R,3R,4R,5R,6S)-3,4,5-trihydroxy-6-methyloxan-2-yl]oxymethyl]oxan-2-yl] (4aS,6aR,6aS,6bR,8aR,10S,12aR,14bS)-10-[(2R,3R,4S,5S,6R)-6-[[(2R,3S,4S,5R)-4,5-dihydroxy-3-[(2S,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxyoxan-2-yl]oxymethyl]-3,4,5-trihydroxyoxan-2-yl]oxy-2,2,6a,6b,9,9,12a-heptamethyl-1,3,4,5,6,6a,7,8,8a,10,11,12,13,14b-tetradecahydropicene-4a-carboxylate	162871682	Click to see CC1C(C(C(C(O1)OCC2C(C(C(C(O2)OC(=O)C34CCC(CC3C5=CCC6C7(CCC(C(C7CCC6(C5(CC4)C)C)(C)C)OC8C(C(C(C(O8)COC9C(C(C(CO9)O)O)OC1C(C(C(CO1)O)O)O)O)O)O)C)(C)C)OC1C(C(C(C(O1)C)OC1C(C(C(CO1)O)OC1C(C(C(CO1)O)O)O)O)O)O)O)O)O)O)O	1601.70	unknown	https://doi.org/10.1016/S0031-9422(99)00238-1
[(2S,3R,4S,5S,6R)-3-[(2S,3R,4R,5R,6S)-5-[(2S,3R,4S,5R)-3,5-dihydroxy-4-[(2S,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxyoxan-2-yl]oxy-4-hydroxy-6-methyl-3-[(2S,3R,4S,5R,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-4,5-dihydroxy-6-(hydroxymethyl)oxan-2-yl] (4aR,5R,6aR,6aS,6bR,8aR,10S,12aR,14bS)-10-[(2R,3R,4S,5S,6R)-6-[[(2R,3R,4S,5S)-4,5-dihydroxy-3-[(2S,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxyoxan-2-yl]oxymethyl]-3,4,5-trihydroxyoxan-2-yl]oxy-5-hydroxy-2,2,6a,6b,9,9,12a-heptamethyl-1,3,4,5,6,6a,7,8,8a,10,11,12,13,14b-tetradecahydropicene-4a-carboxylate	154496666	Click to see CC1C(C(C(C(O1)OC2C(C(C(OC2OC(=O)C34CCC(CC3C5=CCC6C7(CCC(C(C7CCC6(C5(CC4O)C)C)(C)C)OC8C(C(C(C(O8)COC9C(C(C(CO9)O)O)OC1C(C(C(CO1)O)O)O)O)O)O)C)(C)C)CO)O)O)OC1C(C(C(C(O1)CO)O)O)O)O)OC1C(C(C(CO1)O)OC1C(C(C(CO1)O)O)O)O	1633.70	unknown	https://doi.org/10.1016/S0031-9422(99)00238-1
[(2S,3R,4S,5S,6R)-3-[(2S,3R,4R,5R,6S)-5-[(2S,3R,4S,5R)-3,5-dihydroxy-4-[(2S,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxyoxan-2-yl]oxy-4-hydroxy-6-methyl-3-[(2S,3R,4S,5R,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-4,5-dihydroxy-6-(hydroxymethyl)oxan-2-yl] (4aR,5R,6aR,6aS,6bR,8aR,10S,12aR,14bS)-10-[(2R,3R,4S,5S,6R)-6-[[(2S,3R,4S,5S)-4,5-dihydroxy-3-[(2S,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxyoxan-2-yl]oxymethyl]-3,4,5-trihydroxyoxan-2-yl]oxy-5-hydroxy-2,2,6a,6b,9,9,12a-heptamethyl-1,3,4,5,6,6a,7,8,8a,10,11,12,13,14b-tetradecahydropicene-4a-carboxylate	100945176	Click to see CC1C(C(C(C(O1)OC2C(C(C(OC2OC(=O)C34CCC(CC3C5=CCC6C7(CCC(C(C7CCC6(C5(CC4O)C)C)(C)C)OC8C(C(C(C(O8)COC9C(C(C(CO9)O)O)OC1C(C(C(CO1)O)O)O)O)O)O)C)(C)C)CO)O)O)OC1C(C(C(C(O1)CO)O)O)O)O)OC1C(C(C(CO1)O)OC1C(C(C(CO1)O)O)O)O	1633.70	unknown	https://doi.org/10.1016/S0031-9422(99)00238-1
[(2S,3R,4S,5S,6R)-3-[(2S,3R,4R,5R,6S)-5-[(2S,3R,4S,5R)-3,5-dihydroxy-4-[(2S,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxyoxan-2-yl]oxy-4-hydroxy-6-methyl-3-[(2S,3R,4S,5R,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-4,5-dihydroxy-6-[[(2E,6S)-6-hydroxy-2-(hydroxymethyl)-6-methylocta-2,7-dienoyl]oxymethyl]oxan-2-yl] (4aR,5R,6aR,6aS,6bR,8aR,10S,12aR,14bS)-10-[(2R,3R,4S,5S,6R)-6-[[(2S,3R,4S,5S)-4,5-dihydroxy-3-[(2S,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxyoxan-2-yl]oxymethyl]-3,4,5-trihydroxyoxan-2-yl]oxy-5-hydroxy-2,2,6a,6b,9,9,12a-heptamethyl-1,3,4,5,6,6a,7,8,8a,10,11,12,13,14b-tetradecahydropicene-4a-carboxylate	21604045	Click to see	1815.90	unknown	via CMAUP database
[(2S,3R,4S,5S,6R)-3-[(2S,3R,4R,5R,6S)-5-[(2S,3R,4S,5R)-3,5-dihydroxy-4-[(2S,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxyoxan-2-yl]oxy-4-hydroxy-6-methyl-3-[(2S,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxyoxan-2-yl]oxy-4,5-dihydroxy-6-(hydroxymethyl)oxan-2-yl] (4aR,5R,6aR,6aS,6bR,8aR,10S,12aR,14bS)-10-[(2R,3R,4S,5S,6R)-6-[[(2S,3R,4S,5S)-4,5-dihydroxy-3-[(2S,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxyoxan-2-yl]oxymethyl]-3,4,5-trihydroxyoxan-2-yl]oxy-5-hydroxy-2,2,6a,6b,9,9,12a-heptamethyl-1,3,4,5,6,6a,7,8,8a,10,11,12,13,14b-tetradecahydropicene-4a-carboxylate	100945177	Click to see CC1C(C(C(C(O1)OC2C(C(C(OC2OC(=O)C34CCC(CC3C5=CCC6C7(CCC(C(C7CCC6(C5(CC4O)C)C)(C)C)OC8C(C(C(C(O8)COC9C(C(C(CO9)O)O)OC1C(C(C(CO1)O)O)O)O)O)O)C)(C)C)CO)O)O)OC1C(C(C(CO1)O)O)O)O)OC1C(C(C(CO1)O)OC1C(C(C(CO1)O)O)O)O	1603.70	unknown	https://doi.org/10.1016/S0031-9422(99)00238-1
[(2S,3R,4S,5S,6R)-3-[(2S,3R,4R,5R,6S)-5-[(2S,3R,4S,5R)-3,5-dihydroxy-4-[(2S,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxyoxan-2-yl]oxy-4-hydroxy-6-methyl-3-[(2S,3R,4S,5S)-3,4,5-trihydroxyoxan-2-yl]oxyoxan-2-yl]oxy-4,5-dihydroxy-6-(hydroxymethyl)oxan-2-yl] (4aR,5R,6aR,6aS,6bR,8aR,10S,12aR,14bS)-10-[(2R,3R,4S,5S,6R)-6-[[(2S,3R,4S,5S)-4,5-dihydroxy-3-[(2S,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxyoxan-2-yl]oxymethyl]-3,4,5-trihydroxyoxan-2-yl]oxy-5-hydroxy-2,2,6a,6b,9,9,12a-heptamethyl-1,3,4,5,6,6a,7,8,8a,10,11,12,13,14b-tetradecahydropicene-4a-carboxylate	162841311	Click to see CC1C(C(C(C(O1)OC2C(C(C(OC2OC(=O)C34CCC(CC3C5=CCC6C7(CCC(C(C7CCC6(C5(CC4O)C)C)(C)C)OC8C(C(C(C(O8)COC9C(C(C(CO9)O)O)OC1C(C(C(CO1)O)O)O)O)O)O)C)(C)C)CO)O)O)OC1C(C(C(CO1)O)O)O)O)OC1C(C(C(CO1)O)OC1C(C(C(CO1)O)O)O)O	1603.70	unknown	https://doi.org/10.1016/S0031-9422(99)00238-1
[(2S,3R,4S,5S,6R)-3-[(2S,3R,4S,5R,6S)-5-[(2S,3R,4S,5R)-3,5-dihydroxy-4-[(2S,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxyoxan-2-yl]oxy-3,4-dihydroxy-6-methyloxan-2-yl]oxy-4,5-dihydroxy-6-(hydroxymethyl)oxan-2-yl] (4aS,6aR,6aS,6bR,8aR,10S,12aR,14bS)-10-[(2R,3R,4S,5S,6R)-6-[[(2R,3R,4R,5S)-4,5-dihydroxy-3-[(2S,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxyoxan-2-yl]oxymethyl]-3,4,5-trihydroxyoxan-2-yl]oxy-2,2,6a,6b,9,9,12a-heptamethyl-1,3,4,5,6,6a,7,8,8a,10,11,12,13,14b-tetradecahydropicene-4a-carboxylate	154496665	Click to see CC1C(C(C(C(O1)OC2C(C(C(OC2OC(=O)C34CCC(CC3C5=CCC6C7(CCC(C(C7CCC6(C5(CC4)C)C)(C)C)OC8C(C(C(C(O8)COC9C(C(C(CO9)O)O)OC1C(C(C(CO1)O)O)O)O)O)O)C)(C)C)CO)O)O)O)O)OC1C(C(C(CO1)O)OC1C(C(C(CO1)O)O)O)O	1455.60	unknown	https://doi.org/10.1016/S0031-9422(99)00238-1
[(2S,3R,4S,5S,6R)-3-[(2S,3R,4S,5R,6S)-5-[(2S,3R,4S,5R)-3,5-dihydroxy-4-[(2S,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxyoxan-2-yl]oxy-3,4-dihydroxy-6-methyloxan-2-yl]oxy-4,5-dihydroxy-6-(hydroxymethyl)oxan-2-yl] (4aS,6aR,6aS,6bR,8aR,10S,12aR,14bS)-10-[(2R,3R,4S,5S,6R)-6-[[(2S,3R,4S,5S)-4,5-dihydroxy-3-[(2S,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxyoxan-2-yl]oxymethyl]-3,4,5-trihydroxyoxan-2-yl]oxy-2,2,6a,6b,9,9,12a-heptamethyl-1,3,4,5,6,6a,7,8,8a,10,11,12,13,14b-tetradecahydropicene-4a-carboxylate	10558461	Click to see CC1C(C(C(C(O1)OC2C(C(C(OC2OC(=O)C34CCC(CC3C5=CCC6C7(CCC(C(C7CCC6(C5(CC4)C)C)(C)C)OC8C(C(C(C(O8)COC9C(C(C(CO9)O)O)OC1C(C(C(CO1)O)O)O)O)O)O)C)(C)C)CO)O)O)O)O)OC1C(C(C(CO1)O)OC1C(C(C(CO1)O)O)O)O	1455.60	unknown	https://doi.org/10.1016/S0031-9422(99)00238-1
[(2S,3R,4S,5S,6R)-3-[(2S,3R,4S,5R,6S)-5-[(2S,3R,4S,5R)-3,5-dihydroxy-4-[(2S,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxyoxan-2-yl]oxy-3,4-dihydroxy-6-methyloxan-2-yl]oxy-4,5-dihydroxy-6-[[(2E,6S)-6-hydroxy-2-(hydroxymethyl)-6-methylocta-2,7-dienoyl]oxymethyl]oxan-2-yl] (4aR,5R,6aR,6aS,6bR,8aR,10S,12aR,14bS)-10-[(2R,3R,4S,5S,6R)-6-[[(2S,3R,4S,5S)-4,5-dihydroxy-3-[(2S,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxyoxan-2-yl]oxymethyl]-3,4,5-trihydroxyoxan-2-yl]oxy-5-hydroxy-2,2,6a,6b,9,9,12a-heptamethyl-1,3,4,5,6,6a,7,8,8a,10,11,12,13,14b-tetradecahydropicene-4a-carboxylate	100973272	Click to see	1653.80	unknown	via CMAUP database
[(2S,3R,4S,5S,6R)-3-[(2S,3R,4S,5R,6S)-5-[(2S,3R,4S,5R)-3,5-dihydroxy-4-[(2S,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxyoxan-2-yl]oxy-3,4-dihydroxy-6-methyloxan-2-yl]oxy-4,5-dihydroxy-6-[[(2E,6S)-6-hydroxy-2,6-dimethylocta-2,7-dienoyl]oxymethyl]oxan-2-yl] (4aS,6aR,6aS,6bR,8aR,10S,12aR,14bS)-10-[(2R,3R,4S,5S,6R)-6-[[(2S,3R,4S,5R)-4,5-dihydroxy-3-[(2S,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxyoxan-2-yl]oxymethyl]-3,4,5-trihydroxyoxan-2-yl]oxy-2,2,6a,6b,9,9,12a-heptamethyl-1,3,4,5,6,6a,7,8,8a,10,11,12,13,14b-tetradecahydropicene-4a-carboxylate	163010914	Click to see	1621.80	unknown	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10346958/
[(2S,3R,4S,5S,6R)-3-[(2S,3R,4S,5R,6S)-5-[(2S,3R,4S,5R)-3,5-dihydroxy-4-[(2S,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxyoxan-2-yl]oxy-3,4-dihydroxy-6-methyloxan-2-yl]oxy-4,5-dihydroxy-6-[[(2R,3R,4R,5R,6S)-3,4,5-trihydroxy-6-methyloxan-2-yl]oxymethyl]oxan-2-yl] (4aR,5R,6aR,6aS,6bR,8aR,10S,12aR,14bS)-5-hydroxy-2,2,6a,6b,9,9,12a-heptamethyl-10-[(2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-[[(2S,3R,4S,5S)-3,4,5-trihydroxyoxan-2-yl]oxymethyl]oxan-2-yl]oxy-1,3,4,5,6,6a,7,8,8a,10,11,12,13,14b-tetradecahydropicene-4a-carboxylate	100945175	Click to see	1485.60	unknown	via CMAUP database
[(2S,3R,4S,5S,6R)-3-[(2S,3R,4S,5R,6S)-5-[(2S,3R,4S,5R)-3,5-dihydroxy-4-[(2S,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxyoxan-2-yl]oxy-3,4-dihydroxy-6-methyloxan-2-yl]oxy-4,5-dihydroxy-6-[[(2R,3R,4R,5S,6S)-5-hydroxy-3-[(2E,6S)-6-hydroxy-2,6-dimethylocta-2,7-dienoyl]oxy-4-[(2E,6S)-6-hydroxy-2-(hydroxymethyl)-6-methylocta-2,7-dienoyl]oxy-6-methyloxan-2-yl]oxymethyl]oxan-2-yl] (5R,6aS,6bR,10S,12aR)-10-[(2R,3R,4S,5S,6R)-6-[[(2S,3R,4S,5S)-4,5-dihydroxy-3-[(2S,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxyoxan-2-yl]oxymethyl]-3,4,5-trihydroxyoxan-2-yl]oxy-5-hydroxy-2,2,6a,6b,9,9,12a-heptamethyl-1,3,4,5,6,6a,7,8,8a,10,11,12,13,14b-tetradecahydropicene-4a-carboxylate	6475388	Click to see	1966.20	unknown	via CMAUP database
[(2S,3R,4S,5S,6R)-3-[(2S,3R,4S,5R,6S)-5-[(2S,3R,4S,5R)-3,5-dihydroxy-4-[(2S,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxyoxan-2-yl]oxy-3,4-dihydroxy-6-methyloxan-2-yl]oxy-4,5-dihydroxy-6-[[(2R,3R,4R,5S,6S)-5-hydroxy-3-[(2E,6S)-6-hydroxy-2,6-dimethylocta-2,7-dienoyl]oxy-4-[(2E)-6-hydroxy-2-(hydroxymethyl)-6-methylocta-2,7-dienoyl]oxy-6-methyloxan-2-yl]oxymethyl]oxan-2-yl] (4aR,5R,6aR,6aS,6bR,8aR,10S,12aR,14bS)-10-[(2R,3R,4S,5S,6R)-6-[[(2S,3R,4S,5S)-4,5-dihydroxy-3-[(2S,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxyoxan-2-yl]oxymethyl]-3,4,5-trihydroxyoxan-2-yl]oxy-5-hydroxy-2,2,6a,6b,9,9,12a-heptamethyl-1,3,4,5,6,6a,7,8,8a,10,11,12,13,14b-tetradecahydropicene-4a-carboxylate	100987820	Click to see CC1C(C(C(C(O1)OCC2C(C(C(C(O2)OC(=O)C34CCC(CC3C5=CCC6C7(CCC(C(C7CCC6(C5(CC4O)C)C)(C)C)OC8C(C(C(C(O8)COC9C(C(C(CO9)O)O)OC1C(C(C(CO1)O)O)O)O)O)O)C)(C)C)OC1C(C(C(C(O1)C)OC1C(C(C(CO1)O)OC1C(C(C(CO1)O)O)O)O)O)O)O)O)OC(=O)C(=CCCC(C)(C=C)O)C)OC(=O)C(=CCCC(C)(C=C)O)CO)O	1966.20	unknown	https://doi.org/10.1016/S0031-9422(99)00238-1 https://doi.org/10.1248/CPB.47.388
[(2S,3R,4S,5S,6R)-3-[(2S,3R,4S,5R,6S)-5-[(2S,3R,4S,5R)-3,5-dihydroxy-4-[(2S,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxyoxan-2-yl]oxy-3,4-dihydroxy-6-methyloxan-2-yl]oxy-4,5-dihydroxy-6-[[(2R,3R,4R,5S,6S)-5-hydroxy-3-[(2E,6S)-6-hydroxy-2,6-dimethylocta-2,7-dienoyl]oxy-4-[(2E)-6-hydroxy-2-(hydroxymethyl)-6-methylocta-2,7-dienoyl]oxy-6-methyloxan-2-yl]oxymethyl]oxan-2-yl] (4aS,6aR,6aS,6bR,8aR,10S,12aR,14bS)-10-[(2R,3R,4S,5S,6R)-6-[[(2S,3R,4S,5S)-4,5-dihydroxy-3-[(2S,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxyoxan-2-yl]oxymethyl]-3,4,5-trihydroxyoxan-2-yl]oxy-2,2,6a,6b,9,9,12a-heptamethyl-1,3,4,5,6,6a,7,8,8a,10,11,12,13,14b-tetradecahydropicene-4a-carboxylate	10558536	Click to see	1950.20	unknown	https://doi.org/10.1248/CPB.47.388
[(2S,3R,4S,5S,6R)-3-[(2S,3R,4S,5R,6S)-5-[(2S,3R,4S,5R)-3,5-dihydroxy-4-[(2S,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxyoxan-2-yl]oxy-3,4-dihydroxy-6-methyloxan-2-yl]oxy-4,5-dihydroxy-6-[[(2R,3R,4R,5S,6S)-5-hydroxy-3,4-bis[[(2E,6S)-6-hydroxy-2,6-dimethylocta-2,7-dienoyl]oxy]-6-methyloxan-2-yl]oxymethyl]oxan-2-yl] (4aR,5R,6aR,6aS,6bR,8aR,10S,12aR,14bS)-10-[(2R,3R,4S,5S,6R)-6-[[(2S,3R,4S,5S)-4,5-dihydroxy-3-[(2S,3R,4S,5R)-3,4,5-trihydroxyoxan-2-yl]oxyoxan-2-yl]oxymethyl]-3,4,5-trihydroxyoxan-2-yl]oxy-5-hydroxy-2,2,6a,6b,9,9,12a-heptamethyl-1,3,4,5,6,6a,7,8,8a,10,11,12,13,14b-tetradecahydropicene-4a-carboxylate	10725268	Click to see	1950.20	unknown	https://doi.org/10.1248/CPB.47.388
[3-[5-[3,5-Dihydroxy-4-(3,4,5-trihydroxyoxan-2-yl)oxyoxan-2-yl]oxy-3,4-dihydroxy-6-methyloxan-2-yl]oxy-4,5-dihydroxy-6-[[6-hydroxy-2-(hydroxymethyl)-6-methylocta-2,7-dienoyl]oxymethyl]oxan-2-yl] 10-[6-[[4,5-dihydroxy-3-(3,4,5-trihydroxyoxan-2-yl)oxyoxan-2-yl]oxymethyl]-2,3,4,5-tetrahydroxyoxan-2-yl]oxy-2,2,6a,6b,9,9,12a-heptamethyl-1,3,4,5,6,6a,7,8,8a,10,11,12,13,14b-tetradecahydropicene-4a-carboxylate	163105203	Click to see CC1C(C(C(C(O1)OC2C(C(C(OC2OC(=O)C34CCC(CC3C5=CCC6C7(CCC(C(C7CCC6(C5(CC4)C)C)(C)C)OC8(C(C(C(C(O8)COC9C(C(C(CO9)O)O)OC1C(C(C(CO1)O)O)O)O)O)O)O)C)(C)C)COC(=O)C(=CCCC(C)(C=C)O)CO)O)O)O)O)OC1C(C(C(CO1)O)OC1C(C(C(CO1)O)O)O)O	1653.80	unknown	https://doi.org/10.1021/NP990060M
[3-[5-[3,5-Dihydroxy-4-(3,4,5-trihydroxyoxan-2-yl)oxyoxan-2-yl]oxy-3,4-dihydroxy-6-methyloxan-2-yl]oxy-4,5-dihydroxy-6-[[6-hydroxy-2-(hydroxymethyl)-6-methylocta-2,7-dienoyl]oxymethyl]oxan-2-yl] 10-[6-[[4,5-dihydroxy-3-(3,4,5-trihydroxyoxan-2-yl)oxyoxan-2-yl]oxymethyl]-3,4,5-trihydroxyoxan-2-yl]oxy-2,2,6a,6b,9,9,12a-heptamethyl-1,3,4,5,6,6a,7,8,8a,10,11,12,13,14b-tetradecahydropicene-4a-carboxylate	74966703	Click to see	1637.80	unknown	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10346958/
[3-[5-[3,5-Dihydroxy-4-(3,4,5-trihydroxyoxan-2-yl)oxyoxan-2-yl]oxy-3,4-dihydroxy-6-methyloxan-2-yl]oxy-5-hydroxy-4-(6-hydroxy-2,6-dimethylocta-2,7-dienoyl)oxy-6-(hydroxymethyl)oxan-2-yl] 10-[6-[[4,5-dihydroxy-3-(3,4,5-trihydroxyoxan-2-yl)oxyoxan-2-yl]oxymethyl]-3,4,5-trihydroxyoxan-2-yl]oxy-2,2,6a,6b,9,9,12a-heptamethyl-1,3,4,5,6,6a,7,8,8a,10,11,12,13,14b-tetradecahydropicene-4a-carboxylate	75111124	Click to see CC1C(C(C(C(O1)OC2C(C(C(OC2OC(=O)C34CCC(CC3C5=CCC6C7(CCC(C(C7CCC6(C5(CC4)C)C)(C)C)OC8C(C(C(C(O8)COC9C(C(C(CO9)O)O)OC1C(C(C(CO1)O)O)O)O)O)O)C)(C)C)CO)O)OC(=O)C(=CCCC(C)(C=C)O)C)O)O)OC1C(C(C(CO1)O)OC1C(C(C(CO1)O)O)O)O	1621.80	unknown	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10346958/
[3-[5-[3,5-Dihydroxy-4-(3,4,5-trihydroxyoxan-2-yl)oxyoxan-2-yl]oxy-3,4-dihydroxy-6-methyloxan-2-yl]oxy-5-hydroxy-4-(6-hydroxy-2,6-dimethylocta-2,7-dienoyl)oxy-6-[(6-hydroxy-2,6-dimethylocta-2,7-dienoyl)oxymethyl]oxan-2-yl] 10-[6-[[4,5-dihydroxy-3-(3,4,5-trihydroxyoxan-2-yl)oxyoxan-2-yl]oxymethyl]-3,4,5-trihydroxyoxan-2-yl]oxy-2,2,6a,6b,9,9,12a-heptamethyl-1,3,4,5,6,6a,7,8,8a,10,11,12,13,14b-tetradecahydropicene-4a-carboxylate	73807424	Click to see	1788.00	unknown	https://doi.org/10.1021/NP990060M
[3-[5-[3,5-Dihydroxy-4-(3,4,5-trihydroxyoxan-2-yl)oxyoxan-2-yl]oxy-3,4-dihydroxy-6-methyloxan-2-yl]oxy-5-hydroxy-6-[(6-hydroxy-2,6-dimethylocta-2,7-dienoyl)oxymethyl]-4-[6-hydroxy-2-(hydroxymethyl)-6-methylocta-2,7-dienoyl]oxyoxan-2-yl] 10-[6-[[4,5-dihydroxy-3-(3,4,5-trihydroxyoxan-2-yl)oxyoxan-2-yl]oxymethyl]-3,4,5-trihydroxyoxan-2-yl]oxy-2,2,6a,6b,9,9,12a-heptamethyl-1,3,4,5,6,6a,7,8,8a,10,11,12,13,14b-tetradecahydropicene-4a-carboxylate	73807423	Click to see CC1C(C(C(C(O1)OC2C(C(C(OC2OC(=O)C34CCC(CC3C5=CCC6C7(CCC(C(C7CCC6(C5(CC4)C)C)(C)C)OC8C(C(C(C(O8)COC9C(C(C(CO9)O)O)OC1C(C(C(CO1)O)O)O)O)O)O)C)(C)C)COC(=O)C(=CCCC(C)(C=C)O)C)O)OC(=O)C(=CCCC(C)(C=C)O)CO)O)O)OC1C(C(C(CO1)O)OC1C(C(C(CO1)O)O)O)O	1804.00	unknown	https://doi.org/10.1021/NP990060M
[3-[5-[3,5-Dihydroxy-4-(3,4,5-trihydroxyoxan-2-yl)oxyoxan-2-yl]oxy-4-hydroxy-6-methyl-3-[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-4,5-dihydroxy-6-[(6-hydroxy-2,6-dimethylocta-2,7-dienoyl)oxymethyl]oxan-2-yl] 10-[6-[[4,5-dihydroxy-3-(3,4,5-trihydroxyoxan-2-yl)oxyoxan-2-yl]oxymethyl]-3,4,5-trihydroxyoxan-2-yl]oxy-5-hydroxy-2,2,6a,6b,9,9,12a-heptamethyl-1,3,4,5,6,6a,7,8,8a,10,11,12,13,14b-tetradecahydropicene-4a-carboxylate	85263599	Click to see	1799.90	unknown	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10346958/
[3-[5-[3,5-Dihydroxy-4-(3,4,5-trihydroxyoxan-2-yl)oxyoxan-2-yl]oxy-4-hydroxy-6-methyl-3-[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-4,5-dihydroxy-6-[[6-hydroxy-2-(hydroxymethyl)-6-methylocta-2,7-dienoyl]oxymethyl]oxan-2-yl] 10-[6-[[4,5-dihydroxy-3-(3,4,5-trihydroxyoxan-2-yl)oxyoxan-2-yl]oxymethyl]-3,4,5-trihydroxyoxan-2-yl]oxy-5-hydroxy-2,2,6a,6b,9,9,12a-heptamethyl-1,3,4,5,6,6a,7,8,8a,10,11,12,13,14b-tetradecahydropicene-4a-carboxylate	73799230	Click to see CC1C(C(C(C(O1)OC2C(C(C(OC2OC(=O)C34CCC(CC3C5=CCC6C7(CCC(C(C7CCC6(C5(CC4O)C)C)(C)C)OC8C(C(C(C(O8)COC9C(C(C(CO9)O)O)OC1C(C(C(CO1)O)O)O)O)O)O)C)(C)C)COC(=O)C(=CCCC(C)(C=C)O)CO)O)O)OC1C(C(C(C(O1)CO)O)O)O)O)OC1C(C(C(CO1)O)OC1C(C(C(CO1)O)O)O)O	1815.90	unknown	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10346958/
[6-[[6-[4,5-Dihydroxy-3-(6-hydroxy-2,6-dimethylocta-2,7-dienoyl)oxyoxan-2-yl]oxy-2,6-dimethylocta-2,7-dienoyl]oxymethyl]-3-[5-[3,5-dihydroxy-4-(3,4,5-trihydroxyoxan-2-yl)oxyoxan-2-yl]oxy-3,4-dihydroxy-6-methyloxan-2-yl]oxy-5-hydroxy-4-(6-hydroxy-2,6-dimethylocta-2,7-dienoyl)oxyoxan-2-yl] 10-[6-[[4,5-dihydroxy-3-(3,4,5-trihydroxyoxan-2-yl)oxyoxan-2-yl]oxymethyl]-3,4,5-trihydroxyoxan-2-yl]oxy-2,2,6a,6b,9,9,12a-heptamethyl-1,3,4,5,6,6a,7,8,8a,10,11,12,13,14b-tetradecahydropicene-4a-carboxylate	73807425	Click to see	2086.30	unknown	https://doi.org/10.1021/NP990060M
3beta-[6-O-(2-O-beta-D-Xylopyranosyl-alpha-L-arabinopyranosyl)-beta-D-glucopyranosyloxy]-28-oxooleana-12-ene-28-yl 2-O-[4-O-(3-O-beta-D-xylopyranosyl-beta-D-xylopyranosyl)-alpha-L-rhamnopyranosyl]-6-O-[(6S,2E)-6-hydroxy-2,6-dimethyl-1-oxo-2,7-octadienyl]-beta-D-glucopyranoside	10796625	Click to see CC1C(C(C(C(O1)OC2C(C(C(OC2OC(=O)C34CCC(CC3C5=CCC6C7(CCC(C(C7CCC6(C5(CC4)C)C)(C)C)OC8C(C(C(C(O8)COC9C(C(C(CO9)O)O)OC1C(C(C(CO1)O)O)O)O)O)O)C)(C)C)COC(=O)C(=CCCC(C)(C=C)O)C)O)O)O)O)OC1C(C(C(CO1)O)OC1C(C(C(CO1)O)O)O)O	1621.80	unknown	via CMAUP database
Gleditsia saponin B	100987821	Click to see	1982.20	unknown	https://doi.org/10.1248/CPB.47.388
Gleditsia saponin C	44584163	Click to see CC1C(C(C(C(O1)OCC2C(C(C(C(O2)OC(=O)C34CCC(CC3C5=CCC6C7(CCC(C(C7CCC6(C5(CC4O)C)C)(C)C)OC8C(C(C(C(O8)COC9C(C(C(CO9)O)O)OC1C(C(C(CO1)O)O)O)O)O)O)C)(C)C)OC1C(C(C(C(O1)C)OC1C(C(C(CO1)O)OC1C(C(C(CO1)O)O)O)O)O)O)O)O)OC(=O)C(=CCCC(C)(C=C)O)C)OC(=O)C(=CCCC(C)(C=C)O)CO)O	1966.20	unknown	via CMAUP database
Gleditsia saponin C'	100945174	Click to see	1617.70	unknown	via CMAUP database
Gleditsioside B	10701743	Click to see	1637.80	unknown	via CMAUP database
Gleditsioside C	162826485	Click to see CC1C(C(C(C(O1)OC2C(C(C(OC2OC(=O)C34CCC(CC3C5=CCC6C7(CCC(C(C7CCC6(C5(CC4O)C)C)(C)C)OC8C(C(C(C(O8)COC9C(C(C(CO9)O)O)OC1C(C(C(CO1)O)O)O)O)O)O)C)(C)C)COC(=O)C(=CCCC(C)(C=C)O)CO)O)O)OC1C(C(C(C(O1)CO)O)O)O)O)OC1C(C(C(CO1)O)OC1C(C(C(CO1)O)O)O)O	1815.90	unknown	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10346958/
Gleditsioside D	162826519	Click to see CC1C(C(C(C(O1)OC2C(C(C(OC2OC(=O)C34CCC(CC3C5=CCC6C7(CCC(C(C7CCC6(C5(CC4O)C)C)(C)C)OC8C(C(C(C(O8)COC9C(C(C(CO9)O)O)OC1C(C(C(CO1)O)O)O)O)O)O)C)(C)C)COC(=O)C(=CCCC(C)(C=C)O)C)O)O)OC1C(C(C(C(O1)CO)O)O)O)O)OC1C(C(C(CO1)O)OC1C(C(C(CO1)O)O)O)O	1799.90	unknown	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10346958/
Gleditsioside E	10844213	Click to see	1966.20	unknown	https://doi.org/10.1055/S-2003-40645 https://doi.org/10.1248/CPB.47.388
Gleditsioside H	100945173	Click to see CC1C(C(C(C(O1)OCC2C(C(C(C(O2)OC(=O)C34CCC(CC3C5=CCC6C7(CCC(C(C7CCC6(C5(CC4)C)C)(C)C)OC8C(C(C(C(O8)COC9C(C(C(CO9)O)O)OC1C(C(C(CO1)O)O)O)O)O)O)C)(C)C)OC1C(C(C(C(O1)C)OC1C(C(C(CO1)O)OC1C(C(C(CO1)O)O)O)O)O)O)O)O)O)O)O	1601.70	unknown	https://doi.org/10.1016/S0031-9422(99)00238-1
Gleditsioside N	163064877	Click to see CC1C(C(C(C(O1)OC2C(C(C(OC2OC(=O)C34CCC(CC3C5=CCC6C7(CCC(C(C7CCC6(C5(CC4)C)C)(C)C)OC8C(C(C(C(O8)COC9C(C(C(CO9)O)O)OC1C(C(C(CO1)O)O)O)O)O)O)C)(C)C)COC(=O)C(=CCCC(C)(C=C)O)C)O)OC(=O)C(=CCCC(C)(C=C)O)CO)O)O)OC1C(C(C(CO1)O)OC1C(C(C(CO1)O)O)O)O	1804.00	unknown	https://doi.org/10.1021/NP990060M
Gleditsioside P	162983551	Click to see	2086.30	unknown	https://doi.org/10.1021/NP990060M
> Lipids and lipid-like molecules / Prenol lipids / Triterpenoids
(3beta,16alpha)-3,16-Dihydroxyolean-13(18)-en-28-oic acid	101596822	Click to see CC1(CCC2(C(CC3(C(=C2C1)CCC4C3(CCC5C4(CCC(C5(C)C)O)C)C)C)O)C(=O)O)C	472.70	unknown	via CMAUP database
(4aR,5R,6aS,6bR,10S,12aR)-5,10-dihydroxy-2,2,6a,6b,9,9,12a-heptamethyl-1,3,4,5,6,6a,7,8,8a,10,11,12,13,14b-tetradecahydropicene-4a-carboxylic acid	23983726	Click to see	472.70	unknown	via CMAUP database
(4aR,6aR,6aS,6bR,8aR,10S,12aR,14bS)-10-hydroxy-2,2,6a,6b,9,9,12a-heptamethyl-1,3,4,5,6,6a,7,8,8a,10,11,12,13,14b-tetradecahydropicene-4a-carboxylic acid	45483610	Click to see CC1(CCC2(CCC3(C(=CCC4C3(CCC5C4(CCC(C5(C)C)O)C)C)C2C1)C)C(=O)O)C	456.70	unknown	via CMAUP database
(4aR,6aS,6bS,8aR,11R,12S,12aR,14aR,14bR)-4,4,6a,6b,8a,11,12,14b-octamethyl-1,2,4a,5,7,8,9,10,11,12,12a,13,14,14a-tetradecahydropicen-3-one	101289675	Click to see	424.70	unknown	https://doi.org/10.1248/CPB.53.561
(5R,6aS)-5,10-dihydroxy-2,2,6a,6b,9,9,12a-heptamethyl-1,3,4,5,6,6a,7,8,8a,10,11,12,13,14b-tetradecahydropicene-4a-carboxylic acid	45358126	Click to see CC1(CCC2(C(C1)C3=CCC4C5(CCC(C(C5CCC4(C3(CC2O)C)C)(C)C)O)C)C(=O)O)C	472.70	unknown	via CMAUP database
5,10-Dihydroxy-2,2,6a,6b,9,9,12a-heptamethyl-1,3,4,5,6,6a,7,8,8a,10,11,12,13,14b-tetradecahydropicene-4a-carboxylic acid	3939968	Click to see CC1(CCC2(C(C1)C3=CCC4C5(CCC(C(C5CCC4(C3(CC2O)C)C)(C)C)O)C)C(=O)O)C	472.70	unknown	https://doi.org/10.1016/J.FITOTE.2009.06.015
Bauer-7-en-3-one	618607	Click to see	424.70	unknown	https://doi.org/10.1248/CPB.53.561
Echinocystic Acid	73309	Click to see	472.70	unknown	https://doi.org/10.1016/J.FITOTE.2009.06.015
Oleanolic Acid	10494	Click to see	456.70	unknown	via CMAUP database
> Lipids and lipid-like molecules / Steroids and steroid derivatives / Stigmastanes and derivatives
(-)-beta-Sitosterol	222284	Click to see	414.70	unknown	https://doi.org/10.1248/CPB.53.561
(2R,15R)-14-[(2R,5R)-5-ethyl-6-methylheptan-2-yl]-2,15-dimethyltetracyclo[8.7.0.0^{2,7}.0^{11,15}]heptadec-6-ene-5,8-dione	11743229	Click to see CCC(CCC(C)C1CCC2C1(CCC3C2CC(=O)C4=CC(=O)CCC34C)C)C(C)C	426.70	unknown	via CMAUP database
(3S,8S,9S,10R,13R,14S,17R)-17-[(E,2S,5S)-5-Ethyl-6-methylhept-3-en-2-yl]-10,13-dimethyl-2,3,4,7,8,9,11,12,14,15,16,17-dodecahydro-1H-cyclopenta[a]phenanthren-3-ol	12314479	Click to see CCC(C=CC(C)C1CCC2C1(CCC3C2CC=C4C3(CCC(C4)O)C)C)C(C)C	412.70	unknown	https://doi.org/10.1248/CPB.53.561
(5R,8R,9S,10S,13R,14S,17R)-17-[(2R,5R)-5-ethyl-6-methylheptan-2-yl]-10,13-dimethyl-2,4,5,7,8,9,11,12,14,15,16,17-dodecahydro-1H-cyclopenta[a]phenanthrene-3,6-dione	154497525	Click to see	428.70	unknown	https://doi.org/10.1248/CPB.53.561
14-(5-Ethyl-6-methylheptan-2-yl)-2,15-dimethyltetracyclo[8.7.0.0^{2,7}.0^{11,15}]heptadecane-5,8-dione	543599	Click to see	428.70	unknown	https://doi.org/10.1248/CPB.53.561
17-(5-ethyl-6-methylhept-3-en-2-yl)-10,13-dimethyl-2,3,4,7,8,9,11,12,14,15,16,17-dodecahydro-1H-cyclopenta[a]phenanthren-3-ol	122544	Click to see	412.70	unknown	https://doi.org/10.1248/CPB.53.561
17-(5-ethyl-6-methylheptan-2-yl)-10,13-dimethyl-2,3,4,7,8,9,11,12,14,15,16,17-dodecahydro-1H-cyclopenta[a]phenanthren-3-ol	86821	Click to see CCC(CCC(C)C1CCC2C1(CCC3C2CC=C4C3(CCC(C4)O)C)C)C(C)C	414.70	unknown	https://doi.org/10.1248/CPB.53.561
Npc196776	50930798	Click to see	410.70	unknown	via CMAUP database
Stigmast-4-ee-3,6-dione	14308881	Click to see	426.70	unknown	https://doi.org/10.1248/CPB.53.561
Stigmast-4-ene-3,6-dione	5490007	Click to see CCC(CCC(C)C1CCC2C1(CCC3C2CC(=O)C4=CC(=O)CCC34C)C)C(C)C	426.70	unknown	https://doi.org/10.1248/CPB.53.561
Stigmast-5-en-3-ol	22012	Click to see	414.70	unknown	https://doi.org/10.1248/CPB.53.561
Stigmastane-3,6-dione	13992092	Click to see	428.70	unknown	https://doi.org/10.1248/CPB.53.561
Stigmasterol	5280794	Click to see	412.70	unknown	https://doi.org/10.1248/CPB.53.561
> Organic acids and derivatives / Carboxylic acids and derivatives / Pentacarboxylic acids and derivatives
[(2S,6S,7S)-5,12-diacetyloxy-6-(acetyloxymethyl)-8-benzoyloxy-2-hydroxy-2,10,10-trimethyl-11-oxatricyclo[7.2.1.01,6]dodecan-7-yl] pyridine-3-carboxylate	5321999	Click to see	653.70	unknown	via CMAUP database
> Organoheterocyclic compounds / Imidazopyrimidines / Purines and purine derivatives / 6-aminopurines
3-(3-methylbut-2-enyl)purin-6-amine	45070	Click to see	203.24	unknown	via CMAUP database
> Organoheterocyclic compounds / Isoindoles and derivatives / Isoindoles
Cytochalasin H from Phomopsis sp.	16211932	Click to see	493.60	unknown	via CMAUP database
> Phenylpropanoids and polyketides / Cinnamic acids and derivatives / Hydroxycinnamic acids and derivatives / Hydroxycinnamic acids
Caffeic Acid	689043	Click to see	180.16	unknown	via CMAUP database
cis-Caffeic acid	1549111	Click to see C1=CC(=C(C=C1C=CC(=O)O)O)O	180.16	unknown	via CMAUP database
> Phenylpropanoids and polyketides / Flavonoids / Flavans / Catechins
(+)-Epicatechin	182232	Click to see	290.27	unknown	via CMAUP database
2-(3,4-dihydroxyphenyl)-3,4-dihydro-2H-1-benzopyran-3,5,7-triol	1203	Click to see	290.27	unknown	via CMAUP database
Catechin	9064	Click to see	290.27	unknown	via CMAUP database
Epicatechin	72276	Click to see	290.27	unknown	via CMAUP database
> Phenylpropanoids and polyketides / Flavonoids / Flavans / Flavanones
Eriodictyol	440735	Click to see C1C(OC2=CC(=CC(=C2C1=O)O)O)C3=CC(=C(C=C3)O)O	288.25	unknown	via CMAUP database
> Phenylpropanoids and polyketides / Flavonoids / Flavans / Flavanones / Flavanonols
Aromadendrin	122850	Click to see C1=CC(=CC=C1C2C(C(=O)C3=C(C=C(C=C3O2)O)O)O)O	288.25	unknown	via CMAUP database
Ddd01025617	9838882	Click to see	288.25	unknown	via CMAUP database
> Phenylpropanoids and polyketides / Flavonoids / Flavones / Flavonols
Quercetin	5280343	Click to see	302.23	unknown	via CMAUP database
> Phenylpropanoids and polyketides / Flavonoids / Flavonoid glycosides / Flavonoid C-glycosides
6-beta-D-Glucopyranosyl-4',5,7-trihydroxyflavone	44257794	Click to see C1=CC(=CC=C1C2=CC(=O)C3=C(O2)C=C(C(=C3O)C4C(C(C(C(O4)CO)O)O)O)O)O	432.40	unknown	via CMAUP database
> Phenylpropanoids and polyketides / Flavonoids / Flavonoid glycosides / Flavonoid C-glycosides / Flavonoid 8-C-glycosides
2-(3,4-dihydroxyphenyl)-5,7-dihydroxy-8-[(2S,3R,4R,5S,6S)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]chromen-4-one	154497137	Click to see C1=CC(=C(C=C1C2=CC(=O)C3=C(O2)C(=C(C=C3O)O)C4C(C(C(C(O4)CO)O)O)O)O)O	448.40	unknown	https://doi.org/10.1248/CPB.25.3408
> Phenylpropanoids and polyketides / Flavonoids / Flavonoid glycosides / Flavonoid O-glycosides / Flavonoid-3-O-glycosides
Quercetin 3-alloside	12304327	Click to see	464.40	unknown	https://doi.org/10.1248/CPB.25.3408
> Phenylpropanoids and polyketides / Tannins / Hydrolyzable tannins
Liquidambar styraciflua	16133892	Click to see C1=C(C=C(C(=C1O)O)O)C(=O)OC2=CC(=CC(=C2O)O)C(=O)OCC3C(C(C(C(O3)OC(=O)C4=CC(=C(C(=C4)OC(=O)C5=CC(=C(C(=C5)O)O)O)O)O)OC(=O)C6=CC(=C(C(=C6)OC(=O)C7=CC(=C(C(=C7)O)O)O)O)O)OC(=O)C8=CC(=C(C(=C8)OC(=O)C9=CC(=C(C(=C9)O)O)O)O)O)OC(=O)C1=CC(=C(C(=C1)OC(=O)C1=CC(=C(C(=C1)O)O)O)O)O	1701.20	unknown	via CMAUP database

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Gleditsia sinensis

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