Veraguamide L

Details

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Internal ID 5204c338-a19a-4ee2-b2d3-8f2087c274a9
Taxonomy Organic acids and derivatives > Peptidomimetics > Depsipeptides
IUPAC Name ethyl 2-[[1-[2-[2-[[2-[(8-bromo-3-hydroxy-2-methyloct-7-ynoyl)amino]-3-methylbutanoyl]-methylamino]-3-methylbutanoyl]oxy-3-methylbutanoyl]pyrrolidine-2-carbonyl]-methylamino]-3-methylbutanoate
SMILES (Canonical) CCOC(=O)C(C(C)C)N(C)C(=O)C1CCCN1C(=O)C(C(C)C)OC(=O)C(C(C)C)N(C)C(=O)C(C(C)C)NC(=O)C(C)C(CCCC#CBr)O
SMILES (Isomeric) CCOC(=O)C(C(C)C)N(C)C(=O)C1CCCN1C(=O)C(C(C)C)OC(=O)C(C(C)C)N(C)C(=O)C(C(C)C)NC(=O)C(C)C(CCCC#CBr)O
InChI InChI=1S/C38H63BrN4O9/c1-13-51-37(49)30(23(4)5)41(11)34(46)27-18-17-21-43(27)36(48)32(25(8)9)52-38(50)31(24(6)7)42(12)35(47)29(22(2)3)40-33(45)26(10)28(44)19-15-14-16-20-39/h22-32,44H,13-15,17-19,21H2,1-12H3,(H,40,45)
InChI Key XFJWITCKHVUBEG-UHFFFAOYSA-N
Popularity 2 references in papers

Physical and Chemical Properties

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Molecular Formula C38H63BrN4O9
Molecular Weight 799.80 g/mol
Exact Mass 798.37784 g/mol
Topological Polar Surface Area (TPSA) 163.00 Ų
XlogP 6.50
Atomic LogP (AlogP) 3.74
H-Bond Acceptor 9
H-Bond Donor 2
Rotatable Bonds 19

Synonyms

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8-Bromo-N-(1-((1-((1-(2-((1-ethoxy-3-methyl-1-oxobutan-2-yl)(methyl)carbamoyl)pyrrolidin-1-yl)-3-methyl-1-oxobutan-2-yl)oxy)-3-methyl-1-oxobutan-2-yl)(methyl)carbamoyl)-2-methylpropyl)-3-hydroxy-2-methyloct-7-ynimidate
8-Bromo-N-[1-({1-[(1-{2-[(1-ethoxy-3-methyl-1-oxobutan-2-yl)(methyl)carbamoyl]pyrrolidin-1-yl}-3-methyl-1-oxobutan-2-yl)oxy]-3-methyl-1-oxobutan-2-yl}(methyl)carbamoyl)-2-methylpropyl]-3-hydroxy-2-methyloct-7-ynimidate
ethyl 2-((1-(2-(2-((2-((8-bromo-3-hydroxy-2-methyloct-7-ynoyl)amino)-3-methylbutanoyl)-methylamino)-3-methylbutanoyl)oxy-3-methylbutanoyl)pyrrolidine-2-carbonyl)-methylamino)-3-methylbutanoate
ethyl 2-[[1-[2-[2-[[2-[(8-bromo-3-hydroxy-2-methyloct-7-ynoyl)amino]-3-methylbutanoyl]-methylamino]-3-methylbutanoyl]oxy-3-methylbutanoyl]pyrrolidine-2-carbonyl]-methylamino]-3-methylbutanoate
RefChem:193952
DTXSID701304595
1-{2-[(1-Ethoxy-3-methyl-1-oxobutan-2-yl)(methyl)carbamoyl]pyrrolidin-1-yl}-3-methyl-1-oxobutan-2-yl 2-[{2-[(8-bromo-3-hydroxy-2-methyloct-7-ynoyl)amino]-3-methylbutanoyl}(methyl)amino]-3-methylbutanoate

2D Structure

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2D Structure of Veraguamide L

3D Structure

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ADMET Properties (via admetSAR 2)

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Target Value Probability (raw) Probability (%)
Human Intestinal Absorption - 0.4917 49.17%
Caco-2 - 0.8490 84.90%
Blood Brain Barrier - 0.7250 72.50%
Human oral bioavailability + 0.5429 54.29%
Subcellular localzation Mitochondria 0.5421 54.21%
OATP2B1 inhibitior - 0.7132 71.32%
OATP1B1 inhibitior + 0.8790 87.90%
OATP1B3 inhibitior + 0.9249 92.49%
MATE1 inhibitior - 0.8600 86.00%
OCT2 inhibitior - 0.9250 92.50%
BSEP inhibitior + 0.6374 63.74%
P-glycoprotein inhibitior + 0.7347 73.47%
P-glycoprotein substrate + 0.7465 74.65%
CYP3A4 substrate + 0.7131 71.31%
CYP2C9 substrate - 0.7982 79.82%
CYP2D6 substrate - 0.8407 84.07%
CYP3A4 inhibition - 0.6313 63.13%
CYP2C9 inhibition - 0.8481 84.81%
CYP2C19 inhibition - 0.8021 80.21%
CYP2D6 inhibition - 0.8900 89.00%
CYP1A2 inhibition - 0.8382 83.82%
CYP2C8 inhibition - 0.5786 57.86%
CYP inhibitory promiscuity - 0.8043 80.43%
UGT catelyzed + 0.7000 70.00%
Carcinogenicity (binary) - 0.7961 79.61%
Carcinogenicity (trinary) Non-required 0.5823 58.23%
Eye corrosion - 0.9831 98.31%
Eye irritation - 0.9104 91.04%
Skin irritation - 0.7868 78.68%
Skin corrosion - 0.9200 92.00%
Ames mutagenesis - 0.5800 58.00%
Human Ether-a-go-go-Related Gene inhibition - 0.3980 39.80%
Micronuclear + 0.7000 70.00%
Hepatotoxicity + 0.6941 69.41%
skin sensitisation - 0.8700 87.00%
Respiratory toxicity + 0.6889 68.89%
Reproductive toxicity + 0.7889 78.89%
Mitochondrial toxicity + 0.7750 77.50%
Nephrotoxicity + 0.5911 59.11%
Acute Oral Toxicity (c) III 0.6233 62.33%
Estrogen receptor binding + 0.8195 81.95%
Androgen receptor binding + 0.6466 64.66%
Thyroid receptor binding + 0.5380 53.80%
Glucocorticoid receptor binding + 0.7040 70.40%
Aromatase binding + 0.6454 64.54%
PPAR gamma + 0.7084 70.84%
Honey bee toxicity - 0.7351 73.51%
Biodegradation - 0.8000 80.00%
Crustacea aquatic toxicity - 0.5400 54.00%
Fish aquatic toxicity - 0.5207 52.07%

Targets

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Proven Targets:

CHEMBL ID UniProt ID Name Min activity Assay type Source
No proven targets yet!

Predicted Targets (via Super-PRED):

CHEMBL ID UniProt ID Name Probability Model accuracy
CHEMBL2581 P07339 Cathepsin D 99.10% 98.95%
CHEMBL3251 P19838 Nuclear factor NF-kappa-B p105 subunit 98.94% 96.09%
CHEMBL1795139 Q8IU80 Transmembrane protease serine 6 96.78% 98.33%
CHEMBL3130 O00329 PI3-kinase p110-delta subunit 96.72% 96.47%
CHEMBL4005 P42336 PI3-kinase p110-alpha subunit 96.71% 97.47%
CHEMBL4588 P22894 Matrix metalloproteinase 8 96.35% 94.66%
CHEMBL3145 P42338 PI3-kinase p110-beta subunit 96.12% 98.75%
CHEMBL3837 P07711 Cathepsin L 95.92% 96.61%
CHEMBL3359 P21462 Formyl peptide receptor 1 94.62% 93.56%
CHEMBL4361 Q07820 Induced myeloid leukemia cell differentiation protein Mcl-1 94.53% 95.52%
CHEMBL321 P14780 Matrix metalloproteinase 9 94.15% 92.12%
CHEMBL4685 P14902 Indoleamine 2,3-dioxygenase 93.26% 96.38%
CHEMBL5103 Q969S8 Histone deacetylase 10 92.83% 90.08%
CHEMBL274 P51681 C-C chemokine receptor type 5 92.57% 98.77%
CHEMBL340 P08684 Cytochrome P450 3A4 92.39% 91.19%
CHEMBL2514 O95665 Neurotensin receptor 2 92.13% 100.00%
CHEMBL4072 P07858 Cathepsin B 92.08% 93.67%
CHEMBL4227 P25090 Lipoxin A4 receptor 91.96% 100.00%
CHEMBL3137262 O60341 LSD1/CoREST complex 91.35% 97.09%
CHEMBL1907603 Q05586 Glutamate NMDA receptor; GRIN1/GRIN2B 91.17% 95.89%
CHEMBL5203 P33316 dUTP pyrophosphatase 90.95% 99.18%
CHEMBL2111367 P27986 PI3-kinase p110-alpha/p85-alpha 90.54% 94.33%
CHEMBL3430907 Q96GD4 Aurora kinase B/Inner centromere protein 90.39% 97.50%
CHEMBL333 P08253 Matrix metalloproteinase-2 90.00% 96.31%
CHEMBL1907600 Q00535 Cyclin-dependent kinase 5/CDK5 activator 1 89.64% 93.03%
CHEMBL4979 P13866 Sodium/glucose cotransporter 1 88.91% 98.24%
CHEMBL5845 P23415 Glycine receptor subunit alpha-1 88.39% 90.71%
CHEMBL3880 P07900 Heat shock protein HSP 90-alpha 88.17% 96.21%
CHEMBL332 P03956 Matrix metalloproteinase-1 87.93% 94.50%
CHEMBL4073 P09237 Matrix metalloproteinase 7 87.03% 97.56%
CHEMBL2107 P61073 C-X-C chemokine receptor type 4 86.97% 93.10%
CHEMBL3238 P23786 Carnitine palmitoyltransferase 2 86.58% 94.05%
CHEMBL237 P41145 Kappa opioid receptor 86.37% 98.10%
CHEMBL1744525 P43490 Nicotinamide phosphoribosyltransferase 86.34% 96.25%
CHEMBL283 P08254 Matrix metalloproteinase 3 86.28% 97.29%
CHEMBL4478 Q00975 Voltage-gated N-type calcium channel alpha-1B subunit 85.81% 97.14%
CHEMBL4187 Q99250 Sodium channel protein type II alpha subunit 85.64% 95.50%
CHEMBL2095194 P08709 Coagulation factor VII/tissue factor 85.61% 99.17%
CHEMBL5255 O00206 Toll-like receptor 4 85.60% 92.50%
CHEMBL253 P34972 Cannabinoid CB2 receptor 85.42% 97.25%
CHEMBL1075094 Q16236 Nuclear factor erythroid 2-related factor 2 85.14% 96.00%
CHEMBL5163 Q9NY46 Sodium channel protein type III alpha subunit 85.00% 96.90%
CHEMBL335 P18031 Protein-tyrosine phosphatase 1B 84.94% 95.17%
CHEMBL2534 O15530 3-phosphoinositide dependent protein kinase-1 84.91% 95.36%
CHEMBL2094135 Q96BI3 Gamma-secretase 84.48% 98.05%
CHEMBL3060 Q9Y345 Glycine transporter 2 84.31% 99.17%
CHEMBL221 P23219 Cyclooxygenase-1 84.29% 90.17%
CHEMBL2274 Q9H228 Sphingosine 1-phosphate receptor Edg-8 83.99% 100.00%
CHEMBL4303 P08238 Heat shock protein HSP 90-beta 83.84% 96.77%
CHEMBL1907591 P30926 Neuronal acetylcholine receptor; alpha4/beta4 83.52% 100.00%
CHEMBL1871 P10275 Androgen Receptor 83.35% 96.43%
CHEMBL5028 O14672 ADAM10 83.16% 97.50%
CHEMBL3267 P48736 PI3-kinase p110-gamma subunit 83.15% 95.71%
CHEMBL2781 P19634 Sodium/hydrogen exchanger 1 82.78% 90.24%
CHEMBL4822 P56817 Beta-secretase 1 82.31% 97.35%
CHEMBL5608 Q16288 NT-3 growth factor receptor 81.77% 95.89%
CHEMBL228 P31645 Serotonin transporter 81.58% 95.51%
CHEMBL4835 P00338 L-lactate dehydrogenase A chain 81.31% 95.34%
CHEMBL2955 O95136 Sphingosine 1-phosphate receptor Edg-5 80.47% 92.86%
CHEMBL2782 P35610 Acyl coenzyme A:cholesterol acyltransferase 1 80.41% 91.65%
CHEMBL3691 Q13822 Autotaxin 80.01% 96.39%

Plants that contains it

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Below are displayed all the plants proven (via scientific papers) to contain this compound!
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Cross-Links

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PubChem 53262812
LOTUS LTS0169057
wikiData Q104200928