Paenialvin B

Details

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Internal ID 319cbaad-5072-44a7-85f5-c41e79f11a51
Taxonomy Organic acids and derivatives > Peptidomimetics > Depsipeptides > Cyclic depsipeptides
IUPAC Name 6-amino-N-[1-[[(9R,15S)-3,6-bis(4-aminobutyl)-9,16-dimethyl-12-(2-methylpropyl)-2,5,8,11,14-pentaoxo-1-oxa-4,7,10,13-tetrazacyclohexadec-15-yl]amino]-4-methyl-1-oxopentan-2-yl]-2-[[(2R)-2-[[2-[[2-[[(2R)-5-(diaminomethylideneamino)-2-[[(2S)-2-[[2-[[2-[[(2R)-2-[[2-(2,3-dihydroxypropanoylamino)-4-methylpentanoyl]amino]propanoyl]amino]-4-methylpentanoyl]amino]-4-methylpentanoyl]amino]-3-methylpentanoyl]amino]pentanoyl]amino]-4-methylpentanoyl]amino]-4-methylpentanoyl]amino]-3-methylbutanoyl]amino]hexanamide
SMILES (Canonical)
SMILES (Isomeric)
InChI InChI=1S/C90H166N22O20/c1-22-54(18)71(111-83(125)67(43-51(12)13)107-80(122)64(40-48(6)7)103-74(116)56(20)98-78(120)62(38-46(2)3)108-85(127)69(114)45-113)87(129)101-60(33-29-37-96-90(94)95)77(119)104-65(41-49(8)9)81(123)106-66(42-50(10)11)82(124)110-70(53(16)17)86(128)100-59(31-24-27-35-92)76(118)105-68(44-52(14)15)84(126)112-72-57(21)132-89(131)61(32-25-28-36-93)102-75(117)58(30-23-26-34-91)99-73(115)55(19)97-79(121)63(39-47(4)5)109-88(72)130/h46-72,113-114H,22-45,91-93H2,1-21H3,(H,97,121)(H,98,120)(H,99,115)(H,100,128)(H,101,129)(H,102,117)(H,103,116)(H,104,119)(H,105,118)(H,106,123)(H,107,122)(H,108,127)(H,109,130)(H,110,124)(H,111,125)(H,112,126)(H4,94,95,96)/t54?,55-,56-,57?,58?,59?,60-,61?,62?,63?,64?,65?,66?,67?,68?,69?,70-,71+,72+/m1/s1
InChI Key NGHWISNXEIEDJE-GZEKDRQBSA-N
Popularity 2 references in papers

Physical and Chemical Properties

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Molecular Formula C90H166N22O20
Molecular Weight 1876.40 g/mol
Exact Mass 1875.26487577 g/mol
Topological Polar Surface Area (TPSA) 675.00 Ų
XlogP 4.20
Atomic LogP (AlogP) -1.45
H-Bond Acceptor 24
H-Bond Donor 23
Rotatable Bonds 58

Synonyms

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RefChem:169557
6-Amino-N-(1-(((9R,15S)-3,6-bis(4-aminobutyl)-5,8,11,14-tetrahydroxy-9,16-dimethyl-12-(2-methylpropyl)-2-oxo-1-oxa-4,7,10,13-tetraazacyclohexadeca-4,7,10,13-tetraen-15-yl)-C-hydroxycarbonimidoyl)-3-methylbutyl)-2-(((2R)-2-((2-((2-(((2R)-5-carbamimidamido-1-hydroxy-2-(((2S)-1-hydroxy-2-((1-hydroxy-2-((1-hydroxy-2-(((2R)-1-hydroxy-2-((1-hydroxy-4-methyl-2-((1,2,3-trihydroxypropylidene)amino)pentylidene)amino)propylidene)amino)-4-methylpentylidene)amino)-4-methylpentylidene)amino)-3-methylpentylidene)amino)pentylidene)amino)-1-hydroxy-4-methylpentylidene)amino)-1-hydroxy-4-methylpentylidene)amino)-1-hydroxy-3-methylbutylidene)amino)hexanimidate
6-amino-N-(1-(((9R,15S)-3,6-bis(4-aminobutyl)-9,16-dimethyl-12-(2-methylpropyl)-2,5,8,11,14-pentaoxo-1-oxa-4,7,10,13-tetrazacyclohexadec-15-yl)amino)-4-methyl-1-oxopentan-2-yl)-2-(((2R)-2-((2-((2-(((2R)-5-(diaminomethylideneamino)-2-(((2S)-2-((2-((2-(((2R)-2-((2-(2,3-dihydroxypropanoylamino)-4-methylpentanoyl)amino)propanoyl)amino)-4-methylpentanoyl)amino)-4-methylpentanoyl)amino)-3-methylpentanoyl)amino)pentanoyl)amino)-4-methylpentanoyl)amino)-4-methylpentanoyl)amino)-3-methylbutanoyl)amino)hexanamide
6-Amino-N-(1-{[(9R,15S)-3,6-bis(4-aminobutyl)-5,8,11,14-tetrahydroxy-9,16-dimethyl-12-(2-methylpropyl)-2-oxo-1-oxa-4,7,10,13-tetraazacyclohexadeca-4,7,10,13-tetraen-15-yl]-C-hydroxycarbonimidoyl}-3-methylbutyl)-2-{[(2R)-2-({2-[(2-{[(2R)-5-carbamimidamido-1-hydroxy-2-{[(2S)-1-hydroxy-2-({1-hydroxy-2-[(1-hydroxy-2-{[(2R)-1-hydroxy-2-({1-hydroxy-4-methyl-2-[(1,2,3-trihydroxypropylidene)amino]pentylidene}amino)propylidene]amino}-4-methylpentylidene)amino]-4-methylpentylidene}amino)-3-methylpentylidene]amino}pentylidene]amino}-1-hydroxy-4-methylpentylidene)amino]-1-hydroxy-4-methylpentylidene}amino)-1-hydroxy-3-methylbutylidene]amino}hexanimidate
6-amino-N-[1-[[(9R,15S)-3,6-bis(4-aminobutyl)-9,16-dimethyl-12-(2-methylpropyl)-2,5,8,11,14-pentaoxo-1-oxa-4,7,10,13-tetrazacyclohexadec-15-yl]amino]-4-methyl-1-oxopentan-2-yl]-2-[[(2R)-2-[[2-[[2-[[(2R)-5-(diaminomethylideneamino)-2-[[(2S)-2-[[2-[[2-[[(2R)-2-[[2-(2,3-dihydroxypropanoylamino)-4-methylpentanoyl]amino]propanoyl]amino]-4-methylpentanoyl]amino]-4-methylpentanoyl]amino]-3-methylpentanoyl]amino]pentanoyl]amino]-4-methylpentanoyl]amino]-4-methylpentanoyl]amino]-3-methylbutanoyl]amino]hexanamide
CHEBI:226908

2D Structure

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2D Structure of Paenialvin B

3D Structure

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ADMET Properties (via admetSAR 2)

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Target Value Probability (raw) Probability (%)
Human Intestinal Absorption - 0.5906 59.06%
Caco-2 - 0.8589 85.89%
Blood Brain Barrier - 0.8500 85.00%
Human oral bioavailability - 0.6000 60.00%
Subcellular localzation Mitochondria 0.4288 42.88%
OATP2B1 inhibitior - 1.0000 100.00%
OATP1B1 inhibitior + 0.8252 82.52%
OATP1B3 inhibitior + 0.9338 93.38%
MATE1 inhibitior - 0.8800 88.00%
OCT2 inhibitior - 0.7750 77.50%
BSEP inhibitior + 0.9501 95.01%
P-glycoprotein inhibitior + 0.7418 74.18%
P-glycoprotein substrate + 0.9009 90.09%
CYP3A4 substrate + 0.7226 72.26%
CYP2C9 substrate - 1.0000 100.00%
CYP2D6 substrate - 0.8163 81.63%
CYP3A4 inhibition - 0.9416 94.16%
CYP2C9 inhibition - 0.9073 90.73%
CYP2C19 inhibition - 0.8825 88.25%
CYP2D6 inhibition - 0.9188 91.88%
CYP1A2 inhibition - 0.8898 88.98%
CYP2C8 inhibition + 0.6962 69.62%
CYP inhibitory promiscuity - 0.9947 99.47%
UGT catelyzed + 0.6000 60.00%
Carcinogenicity (binary) - 0.8600 86.00%
Carcinogenicity (trinary) Non-required 0.5880 58.80%
Eye corrosion - 0.9836 98.36%
Eye irritation - 0.8954 89.54%
Skin irritation - 0.7671 76.71%
Skin corrosion - 0.9215 92.15%
Ames mutagenesis - 0.5900 59.00%
Human Ether-a-go-go-Related Gene inhibition + 0.7014 70.14%
Micronuclear + 0.7400 74.00%
Hepatotoxicity - 0.5269 52.69%
skin sensitisation - 0.8224 82.24%
Respiratory toxicity + 0.7222 72.22%
Reproductive toxicity + 0.8556 85.56%
Mitochondrial toxicity + 0.7750 77.50%
Nephrotoxicity + 0.8616 86.16%
Acute Oral Toxicity (c) III 0.6199 61.99%
Estrogen receptor binding + 0.5597 55.97%
Androgen receptor binding + 0.7418 74.18%
Thyroid receptor binding + 0.7029 70.29%
Glucocorticoid receptor binding + 0.7917 79.17%
Aromatase binding + 0.7962 79.62%
PPAR gamma + 0.7873 78.73%
Honey bee toxicity - 0.7057 70.57%
Biodegradation - 0.8750 87.50%
Crustacea aquatic toxicity - 0.5200 52.00%
Fish aquatic toxicity - 0.8552 85.52%

Targets

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Proven Targets:

CHEMBL ID UniProt ID Name Min activity Assay type Source
No proven targets yet!

Predicted Targets (via Super-PRED):

CHEMBL ID UniProt ID Name Probability Model accuracy
CHEMBL3837 P07711 Cathepsin L 99.99% 96.61%
CHEMBL2094135 Q96BI3 Gamma-secretase 99.53% 98.05%
CHEMBL4072 P07858 Cathepsin B 99.51% 93.67%
CHEMBL2581 P07339 Cathepsin D 99.38% 98.95%
CHEMBL4040 P28482 MAP kinase ERK2 98.50% 83.82%
CHEMBL3359 P21462 Formyl peptide receptor 1 98.20% 93.56%
CHEMBL3251 P19838 Nuclear factor NF-kappa-B p105 subunit 97.31% 96.09%
CHEMBL3130 O00329 PI3-kinase p110-delta subunit 97.08% 96.47%
CHEMBL2514 O95665 Neurotensin receptor 2 96.93% 100.00%
CHEMBL2492 P36544 Neuronal acetylcholine receptor protein alpha-7 subunit 96.28% 88.42%
CHEMBL3060 Q9Y345 Glycine transporter 2 95.93% 99.17%
CHEMBL1795139 Q8IU80 Transmembrane protease serine 6 95.80% 98.33%
CHEMBL1907594 P30926 Neuronal acetylcholine receptor; alpha3/beta4 95.70% 97.23%
CHEMBL2107 P61073 C-X-C chemokine receptor type 4 95.27% 93.10%
CHEMBL5619 P27695 DNA-(apurinic or apyrimidinic site) lyase 95.18% 91.11%
CHEMBL4018 P49146 Neuropeptide Y receptor type 2 95.08% 98.94%
CHEMBL230 P35354 Cyclooxygenase-2 94.77% 89.63%
CHEMBL2072 P35499 Sodium channel protein type IV alpha subunit 94.52% 92.32%
CHEMBL4296 Q15858 Sodium channel protein type IX alpha subunit 94.24% 96.11%
CHEMBL1907605 P24864 Cyclin-dependent kinase 2/cyclin E1 93.89% 92.88%
CHEMBL3776 Q14790 Caspase-8 93.55% 97.06%
CHEMBL1907591 P30926 Neuronal acetylcholine receptor; alpha4/beta4 93.14% 100.00%
CHEMBL4801 P29466 Caspase-1 92.70% 96.85%
CHEMBL259 P32245 Melanocortin receptor 4 92.57% 95.38%
CHEMBL4227 P25090 Lipoxin A4 receptor 92.46% 100.00%
CHEMBL3137262 O60341 LSD1/CoREST complex 92.33% 97.09%
CHEMBL2208 P49137 MAP kinase-activated protein kinase 2 92.28% 95.20%
CHEMBL299 P17252 Protein kinase C alpha 92.06% 98.03%
CHEMBL6136 O60341 Lysine-specific histone demethylase 1 91.84% 95.58%
CHEMBL5163 Q9NY46 Sodium channel protein type III alpha subunit 91.80% 96.90%
CHEMBL3392948 Q9NP59 Solute carrier family 40 member 1 90.88% 95.00%
CHEMBL4581 P52732 Kinesin-like protein 1 90.64% 93.18%
CHEMBL4588 P22894 Matrix metalloproteinase 8 90.48% 94.66%
CHEMBL1075094 Q16236 Nuclear factor erythroid 2-related factor 2 89.84% 96.00%
CHEMBL3267 P48736 PI3-kinase p110-gamma subunit 89.51% 95.71%
CHEMBL3892 Q99500 Sphingosine 1-phosphate receptor Edg-3 88.59% 97.29%
CHEMBL5845 P23415 Glycine receptor subunit alpha-1 88.51% 90.71%
CHEMBL204 P00734 Thrombin 87.17% 96.01%
CHEMBL3108638 O15164 Transcription intermediary factor 1-alpha 86.87% 95.56%
CHEMBL2413 P32246 C-C chemokine receptor type 1 85.99% 89.50%
CHEMBL340 P08684 Cytochrome P450 3A4 85.51% 91.19%
CHEMBL3308 P55212 Caspase-6 85.36% 97.56%
CHEMBL4777 P25929 Neuropeptide Y receptor type 1 84.80% 96.67%
CHEMBL237 P41145 Kappa opioid receptor 84.00% 98.10%
CHEMBL4462 Q8IXJ6 NAD-dependent deacetylase sirtuin 2 83.91% 90.24%
CHEMBL1075317 P61964 WD repeat-containing protein 5 83.80% 96.33%
CHEMBL3468 P55210 Caspase-7 83.63% 95.68%
CHEMBL4478 Q00975 Voltage-gated N-type calcium channel alpha-1B subunit 83.46% 97.14%
CHEMBL253 P34972 Cannabinoid CB2 receptor 82.97% 97.25%
CHEMBL3038469 P24941 CDK2/Cyclin A 82.81% 91.38%
CHEMBL5966 P55899 IgG receptor FcRn large subunit p51 82.23% 90.93%
CHEMBL3004 P33527 Multidrug resistance-associated protein 1 82.14% 96.37%
CHEMBL236 P41143 Delta opioid receptor 81.50% 99.35%
CHEMBL4187 Q99250 Sodium channel protein type II alpha subunit 80.89% 95.50%
CHEMBL4816 Q9Y243 Serine/threonine-protein kinase AKT3 80.79% 96.28%
CHEMBL1907603 Q05586 Glutamate NMDA receptor; GRIN1/GRIN2B 80.66% 95.89%
CHEMBL5103 Q969S8 Histone deacetylase 10 80.36% 90.08%

Plants that contains it

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Below are displayed all the plants proven (via scientific papers) to contain this compound!
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Cross-Links

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PubChem 139589553
LOTUS LTS0172635
wikiData Q105178937